The invention provides a vinylon pure spinning fiber oil and its preparation method, which is composed of non-polar smoothing agent, surfactant, auxiliary agent and water, wherein the content of each component is: non-polar smoothing agent: 8-25%; in surfactants: 5-28% sulfate esters, 5-28% phosphate esters, 5-20% polyol fatty acid esters, 10-30% fatty alcohol ethers; in additives: neutralizer 2 ~11%, high molecular silicone polymer 0.5~5.0%, preservative 0.1%; the balance is water; all are calculated by weight percentage. Since the oil agent of the invention does not contain alkylphenol surfactants, environmental pollution is reduced. The fiber product treated with the oil agent of the present invention has good smoothness, softness, suitable cohesion (or clustering property), antistatic property, etc., so that the fiber can pass through various post-processing procedures smoothly, and has good spinnability; Moreover, it can be widely adapted to the process conditions of fiber production, such as heat resistance, oxidation resistance, corrosion resistance, and prevention of oily odor and deterioration caused by bacterial reproduction. The preparation method in the present invention is simple and does not need heating during preparation.