The invention discloses an X-
ray fluorescence spectrometry method for simultaneously analyzing fluorspar, barite and celestite in ores quantitatively. The X-
ray fluorescence spectrometry method comprises the following specific processes: preparing an artificial standard substance by mixing a barite standard substance, a
fluorite standard substance,
rare earth ore standard substance,
strontium sulfate and
strontium carbonate, fusing the artificial standard substance by using a mixed fusing agent (the ratio of
lithium tetraborate to
lithium metaborate is 12:22), scanning obtained
standard samples to determine an instrument condition, correcting a matrix effect, and then establishing a
standard curve; treating a sample to be tested by using a
strontium-containing
acetic acid solution, filtering, separating an interferent,
ashing a precipitate and
filter paper, then adding the mixed fusing agent (the ratio of
lithium tetraborate to
lithium metaborate is 12:22) for fusing, and analyzing according to the
standard curve. An X-
ray fluorescence spectrometer is selected as an analytical instrument, pretreatment operation is simplified, and simultaneous quantitative analysis of three components, namely the
fluorite, the barite and the celestite, in the ore is achieved; the X-ray
fluorescence spectrometry method is suitable for analyzing the single ore or the ore containing the
fluorite, the barite and the celestite.