Belonging to the technical field of polyether
polyol synthesis, the invention particularly relates to a preparation method of novel hard foam polyether
polyol. The preparation method includes the steps of: (1) adding a high-functionality initiator, a small molecular initiator, water, an amine catalyst and
polyethylene polyamine into a reaction kettle, conducting
nitrogen displacement, then controlling the temperature at 70-90DEG C, adding alkylene
oxide for reaction, and conducting curing; (2) performing
dehydration under a vacuum condition; (3) adding an amine catalyst, controlling the temperature at 105-130DEG C, adding alkylene
oxide for reaction, and conducting curing; (4) adding an amine catalyst and alkylene
oxide, and performing curing; and (5) carrying out
vacuum pumping to removeunreacted
polymerization monomers, thereby obtaining the product. The method provided by the invention has the characteristics of high production efficiency, good reaction activity and small residualamount of later
polymerization monomers, and the compound amine catalyst and olefin oxide are subjected to
polymerization reaction and retained in a polyether
system, thus ensuring shortening of the
curing time in the polyether foaming process, and meeting the foam application requirements for high strength and low dimensional change rate.