Laminate optical body, optical film, liquid crystal display device using said optical film, and method for manufacturing laminate optical body
An optical body and layering technology, applied in chemical instruments and methods, optics, optical components, etc., can solve problems such as O-plate deformation, difficult to achieve optical compensation, tilt alignment angle offset, etc., and achieve the effect of excellent manufacturing efficiency
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[0175] Hereinafter, although an Example demonstrates this invention concretely, this invention is not limited to these Examples. In addition, the measurement methods in the examples are as follows. In addition, in an Example, when showing the angle other than an inclination angle, let the longitudinal direction of a film be 0 degree, and let the direction which rotated counterclockwise from the longitudinal direction be positive.
[0176] (1) Dimensional change rate
[0177] The laminated optical bodies obtained in Examples and Comparative Examples were cut into 10 cm×10 cm and used as test pieces. Specific positions on the test piece are marked at specific intervals. The marked test piece was placed in an oven (manufactured by ESPEC, product name PH-201), left at 80°C for 500 hours, and then taken out. Measure the marking interval of the taken-out test piece, and calculate the dimensional change rate according to the following formula:
[0178] Dimensional change rate (%)...
reference example 1
[0202] [Production of Polarizing Film]
[0203] Polyvinyl alcohol resin (manufactured by Nippon Synthetic Chemical Industry Co., Ltd., product name "Gohsenol NH-18", saponification degree: 98-99%) was dissolved in hot water and cooled to prepare 7 % by weight polyvinyl alcohol aqueous solution. On the other hand, a norbornene-based resin film (manufactured by JSR Corporation, product name "ARTON", thickness: 100 µm) was prepared as a base material. The above-mentioned aqueous solution was applied to the surface of the substrate, and dried at 100° C. for 10 minutes to form a polyvinyl alcohol film with a thickness of 7 μm on the substrate. The obtained substrate / film laminate was stretched in the short side direction at a stretching temperature of 140° C. and a stretching ratio of 4.5 times. The overall thickness of the stretched laminate was 60 μm, and the thickness of the polyvinyl alcohol film was 3 μm. The thus stretched laminate was immersed in an iodine aqueous solutio...
reference example 2
[0205] [Production of Polarizing Film]
[0206]A polyvinyl alcohol resin (manufactured by Nippon Synthetic Chemicals Co., Ltd., product name "Gohsenol NH-18", degree of saponification: 98 to 99%) was dissolved in hot water and cooled to prepare a 7% by weight aqueous solution of polyvinyl alcohol. On the other hand, a norbornene-based resin film (manufactured by JSR Co., Ltd., product name "ARTON", thickness: 100 μm) was prepared as a base material. The above-mentioned aqueous solution was applied to the surface of the substrate, and dried at 100° C. for 10 minutes to form a polyvinyl alcohol film with a thickness of 7 μm on the substrate. The obtained substrate / film laminate was stretched in the short side direction at a stretching temperature of 140° C. and a stretching ratio of 4.5 times. The overall thickness of the stretched laminate was 60 μm, and the thickness of the polyvinyl alcohol film was 3 μm. The laminate stretched in this way was immersed in an iodine aqueous ...
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