Polyimide Film
A technology of polyimide film and gel film, which is applied in the direction of film/sheet adhesives, layered products, metal layered products, etc., and can solve the problem of dimensional changes in the diagonal direction of flexible metal laminates Insufficient improvement, poor connection between components and substrates, and failure to take film strain into consideration, achieve the effect of small dimensional change rate, stable dimensional change rate, and improved positional deviation
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[0105] Hereinafter, the present invention will be described in more detail by citing examples, but the present invention is not limited by these examples, and many modifications made within the technical idea of the present invention can also be utilized by those skilled in the art.
[0106] Hereinafter, methods for measuring various characteristics of the present invention will be described.
[0107] (1) AI (45, 135)
[0108]The propagation velocity V of the ultrasonic pulse in the present invention was measured using SST-2500 (Sonic Sheet Tester) manufactured by Nomura Corporation. Using SST-2500, ultrasonic velocities in 16 directions every 11.25° in the surface direction of the film from 0 to 180° (0° is parallel to the MD direction) were automatically measured. Among the obtained velocities in each direction, the anisotropy index (AI) shown in Formula 1 was obtained from ultrasonic velocities V45 and V135 at 45° and 135° based on the MD direction. Using the films obta...
Synthetic example 2
[0119] Prepare pyromellitic dianhydride (molecular weight 218.12) / 3,3',4,4'-biphenyltetracarboxylic dianhydride (molecular weight 294.22) / 4 according to the molar ratio of 65 / 35 / 80 / 20, 4'-diaminodiphenyl ether (molecular weight 200.24) / p-phenylenediamine (molecular weight 108.14), in DMAc (N,N-dimethylacetamide), make 20% by weight solution and polymerize to obtain 3500 poise poly Amic acid solution.
Synthetic example A
[0121] Add 1,3-bis(4-aminophenoxy)benzene into the solvent dimethylacetamide and stir until it dissolves. Thereafter, 4,4'-dioxydiphthalic anhydride was added and stirred to obtain a polyamic acid solution. The solid content in dimethylacetamide was 15%, and Tg was 217°C.
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