The invention discloses a PVC hydrotalcite- rare earth- calcium zinc stabilizing agent and the method for preparing the same, which in detail erlates to plastic composite stabilizing agent and the preaparing method, belonging to chemical field. The main component for stabilizing comprises column- supported hydrotalcite, unsaturated rare earth, and epoxy aliphatic acid calcium zinc, and it is prepared through chemical synthesis, reformed treatment and optimization compound. The product is characterized by outstanding thermal stabilizing effect, good first stage coloring property, sound plasticizing property, good transparenty, weatherability, improved quality, high effeciciency, no toxicity, no pollution, low cost. It can replace expensive organotin thermal stabilizing agent and is widely used in PVC product preparation, such as water- supply pipes, section bar, transparent granulate, film, medical apparatus, toy, fridge stamp and box sheet material.