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61results about How to "Good initial colorability" patented technology

High-efficiency environment-friendly stabilizing agent used for PVC section bars

The invention relates to a high-efficiency environment-friendly stabilizing agent used for PVC section bars, which belongs to the technical field of PVC processing aids. The stabilizing agent comprises the following raw materials by weight: 20 to 30 of calcium stearate, 20 to 30 of zinc stearate, 10 to 15 of polyol ester, 1 to 3 of an anti-oxidant, 0.5 of an ultraviolet ray absorber, 10 to 30 of hydrotalcite, 3.5 of beta-diketone, 5 to 15 of alpha-phenylindole and 8 to 15 of epoxy compounds. The invention enables the problem of thermal decomposition of PVC section bars during processing to beovercome and the problem of discoloring because of long-term illumination and exposure in air during daily usage of PVC section bars to be solved, meeting developmental needs of section bars in China.
Owner:SHANDONG RUIFENG CHEM

Environmental-friendly high-efficiency composite heat stabilizer for tribasic zinc PVC (polyvinyl chloride) and preparation method of environmental-friendly high-efficiency composite heat stabilizer

The invention belongs to the field of a heat stabilizer for PVC (polyvinyl chloride) and relates to an environmental-friendly high-efficiency composite heat stabilizer for tribasic zinc PVC (polyvinyl chloride) and a preparation method of the environmental-friendly high-efficiency composite heat stabilizer. The environmental-friendly high-efficiency composite heat stabilizer for the tribasic zinc PVC (polyvinyl chloride) is prepared by performing a reaction of tribasic zinc, calcium stearate, a lubricant and an auxiliary heat stabilizer, wherein the tribasic zinc is prepared by mixing pentaerythritol and zinc oxide according to a weight ratio of 6-8:3 and performing a reaction for 4 to 6 hours at a temperature of 140 to 180 DEG C. The preparation method comprises the following steps of: adding the tribasic zinc and the calcium stearate into a reaction kettle for sufficiently mixing; adding the mixed materials into a kneading machine to knead for 15 to 25 minutes at a temperature of 100 to 120 DEG C; adding a lubricating agent and the auxiliary heat stabilizer in the kneading machine to knead and stir for 25-35min; and carrying out discharging, tabletting, sieving and packaging to obtain the finished product. The prepared environmental-friendly high-efficiency composite heat stabilizer for the tribasic zinc PVC (polyvinyl chloride) has the characteristics that the environmental-friendly high-efficiency composite heat stabilizer is difficult to separate out and has good stabilizing effect; the balancing torque can be reduced; and the processing property is improved. Moreover, the environmental-friendly high-efficiency composite heat stabilizer for the tribasic zinc PVC (polyvinyl chloride) has the advantages of high efficiency and environment protection.
Owner:慧科高新科技股份有限公司

Zinc-based heat stabilizer for polyvinyl chloride, composition with same and application of zinc-based heat stabilizer for polyvinyl chloride

ActiveCN105086293AGood resistance to initial colorationDelay "zinc burnUreaPhosphite ester
The invention relates to zinc-based heat stabilizer for polyvinyl chloride, a composition with the same and an application of the zinc-based heat stabilizer for polyvinyl chloride. The zinc-based heat stabilizer is prepared from urea organic matter and zinc salt through a liquid phase reaction. According to the composition independently prepared from the zinc-based heat stabilizer or prepared by mixing the zinc-based heat stabilizer, calcium carboxylate, beta-diketone, phosphite ester and polyhydric alcohols raw materials, the thermal stability of PVC can be effectively improved. The raw materials of the zinc-based heat stabilizer are easy to obtain, the synthetic process is simple, industrial application prospects are achieved, and the zinc-based heat stabilizer has the important guiding function on research and development of novel urea heat stabilizer.
Owner:SHENZHEN GRADUATE SCHOOL TSINGHUA UNIV

Application of bipyridine ester phosphite to PVC heat stabilizer

ActiveCN106046618AExcellent resistance to precipitationAuxiliary Stabilization ImprovementNitrogen atomEther
The invention relates to the application of bipyridine ester phosphite to a PVC heat stabilizer. bipyridine ester phosphite can be applied to preparation of a liquid barium-zinc stabilizer, a liquid barium-cadmium-zinc stabilizer and a liquid calcium-zinc stabilizer. The liquid barium-zinc stabilizer is prepared from, by weight, 40-50 parts of barium isotanoate, 10-15 parts of zinc-based complex, 5-10 parts of bipyridine ester phosphite, 2-7 parts of 2-ethyl acetyl benzoyl methane, 1-10 parts of thiodipropionicacid dilauryl ester and 10-20 parts of tripropylene glycol n-butyl ether. The bipyridine ester phosphite compound has a higher anti-precipitation property than aliphatic or aromatic phosphite ester by means of a novel heterocyclic perssad replacing the aliphatic or aromatic perssad during preparation of the liquid barium-zinc stabilizer, the liquid barium-cadmium-zinc stabilizer and the liquid calcium-zinc stabilizer. By introducing nitrogen atoms to the heterocyclic ring, the auxiliary stabilization effect on phosphite ester is improved remarkably, and then the printing performance and stability of a modified PVC product are improved.
Owner:ZHEJIANG HIMPTON NEW MATERIAL

Preparation method of rare earth heat stabilizer used for PVC

The invention discloses a preparation method of a rare earth heat stabilizer used for PVC, and belongs to the technical field of plastic assistants. The preparation method comprises the following steps: protecting the hydroxyl group of 3-hydroxypropionic acid used as a raw material with trimethylchlorosilane, reacting the hydroxyl group protected 3-hydroxypropionic acid with thionyl chloride to generate acyl chloride, reacting the acyl chloride with glutamic acid to generate an amine substance, oxidizing the amine substsance to obtain a substance containing an amino group and a carboxyl group, saponifying the substance containing an amino group and a carboxyl group, reacting the saponified substance with an inorganic rare earth salt to generate organic rare earth with generated HCl neutralized by the amino group in order to prevent automatic oxidation, mixing the organic rare earth with a heat stabilization assistant, and drying the obtained mixture to obtain the rare earth heat stabilizer used for PVC. The rare earth heat stabilizer used for PVC overcomes the disadvantages of large toxicity, poor initial heat stability and slow speed of existing heat stabilizers, and has the advantages of improvement of the long-term stability and the initial coloring property of the PVC, non-toxicity, environmental protection, low energy consumption, low dosage, low price and broad industrial application prospect.
Owner:CHANGZHOU UNIV

Method for preparing magnesium-aluminum-zinc hydrotalcite from aluminum-air battery electrolytic waste liquid, and application thereof

The invention discloses a method for preparing magnesium-aluminum-zinc hydrotalcite from aluminum-air battery electrolytic waste liquid, and application thereof. The preparation method comprises a scheme 1 or a scheme 2, and the scheme 1 comprises the following steps: filtering the aluminum-air battery electrolytic waste liquid in advance, reacting filtrate with a magnesium source and a zinc source, carrying out solid-liquid separation to obtain hydroxyl type magnesium-aluminum-zinc hydrotalcite, reacting the hydroxyl type magnesium-aluminum-zinc hydrotalcite with a carbon source, and filtering to obtain magnesium-aluminum-zinc hydrotalcite; and the scheme 2 comprises the following steps: directly reacting filtrate obtained by filtering the aluminum-air battery electrolytic waste liquid with the magnesium source, the zinc source and the carbon source, and performing solid-liquid separation to obtain magnesium-aluminum-zinc hydrotalcite. By adopting the method, resource utilization of the aluminum-air battery electrolytic waste liquid can be realized, the magnesium-aluminum-zinc hydrotalcite with a relatively high additional value can be obtained, the production cost of the hydrotalcite can be reduced, and the prepared magnesium-aluminum-zinc hydrotalcite is relatively low in impurity content, easy in crystal form control, simple in equipment operation, relatively low in production cost, energy-saving and environment-friendly, and is easy to realize industrial production.
Owner:云南创能斐源金属燃料电池有限公司

Novel preparation method of orotic acid hydrate zinc PVC stabilizer by heterogeneous system

By the technology of a heterogeneous system, orotic acid hydrate zinc is prepared to enhance stability of PVC. The preparation method comprises the following steps: adding proper amounts of uracil and deionized water into a four-mouth flask, heating and fully stirring, adding proper amounts of ammonia water and a phase-transfer catalyst, letting the phase-transfer catalyst be uniformly dispersed in the solution, and cooling the solution to room temperature; adding zinc pyrrolidone carboxylate and glycerol while stirring, stirring at constant temperature at room temperature for several hours, pouring the reaction solution into lots of ethanol to obtain white precipitate, separating with cold water, and washing and drying. The orotic acid hydrate zinc is used as a PVC heat stabilizer and can reduce initial coloration of PVC and prolong later zinc burning. According to the technology, cold water is used for separation and purification of the product. Thus, traditional technological flow is greatly simplified, and resource waste and environmental pollution are avoided. The raw materials are easily available, and the preparation technology is simple. Therefore, the technology has a good industrial application prospect.
Owner:SHENZHEN AIMSEA IND

Preparation method of environment-friendly thermal stabilizing agent

The invention relates to preparation of an environment-friendly thermal stabilizing agent, and belongs to the technical field of plastic industry. Castor oil and soybean oil are taken and are added into a four-opening flask; the flask is put into a water bath pot; preheating is performed; maleic anhydride is taken and is poured into methyl ethyl ketone; the obtained mixed liquid is dripped into the flask; after the dripping is completed, the temperature is controlled; stirring is performed; solvents are removed in a vacuum way; modified mixed oil is obtained; the modified mixed oil is poured into a three-opening flask; formic acid, dibenzoyl methane and pentaerythritol are poured; a hydrogen peroxide solution is dripped into the flask; the temperature is regulated; the rotating speed is regulated; after the reaction, still standing and cooling are performed to the room temperature; layering is performed; upper layer oily materials are obtained; sodium hydroxide solution is heated; the upper layer oily materials are dripped into the sodium hydroxide solution; stirring is performed; emulsion is obtained; a zinc oxide solution is added into the emulsion; stirring is performed; products are filtered; filter slag is washed by distilled water and is then put into a baking oven to be baked; the environment-friendly thermal stabilizing agent is obtained.
Owner:戴琪
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