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148 results about "Titanium nickel alloy" patented technology

4D printing method and application of titanium-nickel shape memory alloy

The invention belongs to the technical field of preparation of shape memory alloys, and discloses a 4D printing method and application of a titanium-nickel shape memory alloy. Pure titanium and pure nickel are matched and smelted, and titanium-nickel alloy bars are obtained; then alloy powder is prepared through a rotating electrode atomization method, the powder is screened, and titanium-nickel alloy powder with the grain size of 15 micrometers to 53 micrometers is obtained; and the obtained titanium-nickel alloy powder is placed in a discharge plasma assisted ball mill to be subjected to discharge treatment, the powder is subjected to surface modification, and finally the titanium-nickel shape memory alloy is formed by means of SLM forming. The phase composition of the obtained titanium-nickel shape memory alloy is composed of a B2 austenite phase of a CsC1 type structure, a B19' Martensite phase of a monocline structure and a Ti2Ni precipitated phase. The microstructure comprises nano-sized afterbirth-like crystals and micro dendrite, and the afterbirth-like crystals and the dendrite are alternately distributed in a layered manner. The advantages of being unique in organizationstructure, nearly fully dense and ultrahigh in performance are achieved.
Owner:SOUTH CHINA UNIV OF TECH

Method for ultrasonic-assistance laser near-net shape forming of titanium-nickel alloy gradient material

The invention discloses a method for ultrasonic-assistance laser near-net shape forming of a titanium-nickel alloy gradient material and belongs to the technical field of additive manufacturing. The titanium-nickel based alloy gradient material is manufactured through an ultrasonic-assistance laser near-net shape forming system in an additive manufacturing mode. The method includes the steps thatan ultrasonic generator is fixed to a machine tool working table, a pre-heater is fixed to the ultrasonic generator, and a base plate is fixed to the pre-heater. During forming, the ratio of two typesof powder is changed constantly with the volume fraction of 10% as the step length, and gradient transition from a titanium alloy to a nickel-based alloy is achieved step by step. Through ultrasonicassistance and pre-heating, the defects such as air holes and shrinking holes in a sample can be reduced, and the brittle phase is uniformly distributed on a substrate,; and meanwhile the hardness, the abrasion resistance and other properties of the substrate can be improved, the temperature gradient can be reduced during forming through assistant pre-heating, and the possibility of cracks is greatly lowered. The gradient material prepared through the method is not limited by the shape and the size, and the production efficiency is improved while the cost is reduced.
Owner:DALIAN UNIV OF TECH

Powder material for boiler tube high temperature resistance and wear resistance protecting and preparation method thereof

The invention relates to powder material for boiler tube high temperature resistance and wear resistance protecting and a preparation method thereof, and belongs to the technical field of surface engineering. The power material comprises the following components, by weight percentage, 10-20% of titanium-nickel alloy powder, 1.5-3.5% of graphite powder, 0.5-1% of silica powder, 8-25% of nickel-chromium alloy powder Ni80Cr20, 5-10% of iron boride powder and the balance of tri-chromium dicarbide powder. The preparation method comprises the following steps that power material is prepared, mix powder is formed, liquid-containing binders are prepared, sizing agents are prepared from the mix powder, prilling is completed through spray drying, and finished product powder is prepared from screening the prilling powder and is used for preparing a cladding layer. The metal cladding layer with high wear resistant duplex ceramic is formed through laser cladding, and the hardness ranges from 1100 HV to 1600 HV, so that the powder material for boiler tube high temperature resistance and wear resistance protecting and the preparation method thereof has the advantages that efficiency of the laser cladding is higher, loss of powder spattering is low, grain of the cladding layer is tiny, wear resistance of the cladding layer is high and the like.
Owner:NORTH CHINA ELECTRIC POWER UNIV (BAODING)

Method for preparing vacuum hotpressing sintered wear-resistant coating on surface of metallic titanium and titanium alloy base material

The invention provides a method for preparing vacuum hot-pressed sintered wear-resistant coatings on the surfaces of metallic titanium and titanium alloy substrates. The method comprises the following steps of well mixing and then smearing titanium powder, nickel powder and titanium diboride powder on block metallic titanium or titanium alloy, putting the block metallic titanium or the titanium alloy in a graphite mold, placing the graphite mold in a vacuum hot-pressing furnace, applying axial pressure to the block metallic titanium or the titanium alloy in thegraphite mold, heating the graphite mold together with the block metallic titanium or the titanium alloy and mixed powder to 899.85 to 999.85 DEG C, unloading after preserving heat for 30 minutes, cooling to lower than 399.85 DEG C under a vacuum condition, opening the vacuum hot-pressing furnace, taking out and cooling the graphite mold to a room temperature, taking out the metallic titaniumor the titanium alloy from the graphite mold, and forming a complex wear-resistant coating of titanium-nickel alloy and titanium diboride on the surface of the metallic titanium or the titanium alloy. The wear-resistant coating of the invention is characterized in that the coating has high wear properties of wear-resistant materials, has a TiNi (beta) phase matrix with stable superelasticity performance, and can effectively improve the fatigue properties of the metallic titanium and the titanium alloy.
Owner:SHENYANG UNIV

Preparation method of novel titanium-nickel medical implantation material

The invention relates to a preparation method of a novel titanium-nickel medical implantation material, particularly a composite treatment method for preparing a titanium dioxide/aluminum oxide mixture by depositing titanium on a titanium-nickel surface and performing micro-arc oxidation. The method comprises the following steps: firstly, by using a titanium-nickel alloy base as a workpiece, eliminating the oxide film on the workpiece surface by a mechanical-chemical mixed method; secondly, depositing titanium on the workpiece surface by a plasma surface alloying technique; thirdly, carrying out micro-arc oxidation on the workpiece in a micro-arc oxidation device; and finally, carrying out ultrasonic cleaning on the workpiece, and drying to obtain the finished product. The material can effectively isolate the precipitation of the nickel element in the titanium-nickel alloy, and the ceramic film layer of the titanium base surface subjected to micro-arc oxidation has the advantages of fewer surface voids, high hardness, high corrosion resistance, favorable insulativity and high binding force with the base metal. The method has the characteristics of favorable technical repetitiveness, controllable quality and the like, is simple to operate, can be widely used for surface modification treatment of titanium-nickel alloys, and effectively improves the application range and level.
Owner:TAIYUAN UNIV OF TECH

Preparation method of ZTA particle enhanced steel-based composite liner plate based on chemical activation treatment

The invention discloses a preparation method of a ZTA particle enhanced steel-based composite liner plate based on chemical activation treatment. The preparation method comprises the following steps: (1) carrying out high temperature salt-bath plating on ZTA particles, and obtaining uniform titanium plated layers on the surfaces of the ZTA particles; (2) forming nickel layers at the peripheries of the titanium plated layers; (3) sintering the plated ZTA particles, and mutually connecting the ZTA particles to form a porous prefabricated part; and (4) fixing the prefabricated part on the end surface or the working surface of a cast, pouring a steel base material metal solution through a casting-penetrating process, and carrying out cooling to obtain the ZTA particle enhanced steel-based composite liner plate. During the salt-bath titanium plating, titanium and the surfaces of the ZTA ceramic particles form metallurgical bonding, so that the interfacial bonding property between the titanium layers and the ZTA ceramic particles is enhanced. The ZTA ceramic particles subjected to the salt-bath titanium plating is then subjected to chemical nickel plating, and a titanium-nickel alloy can be generated at a titanium-nickel bonding part; and the titanium-nickel alloy layers achieve the effect of a flexible transitional layer between a metal base body and the ZTA particles, so that the bonding strength of the interface is greatly enhanced.
Owner:陕西明熙康普科技有限公司

Preparation method for large titanium-nickel alloy ingots

The invention discloses a preparation method for large titanium-nickel alloy ingots. According to the method, a mold cavity is used, and a detachable auxiliary support is placed in the mold cavity and is used for dividing the inner space of the mold cavity into N grids which are horizontally arranged; 3-12.7 mm sponge titanium and square blocky electrolytic nickel are used as raw materials and are proportioned according to the composition proportion of titanium-nickel alloy to be prepared so as to obtain N parts of mixed raw materials; and each part of the mixed raw materials is poured into the corresponding grid; the auxiliary support is taken out from the mold cavity; electrode blocks for smelting the titanium-nickel alloy is formed by one-time vertical pressing; and the above steps are repeated to obtain a plurality of electrode blocks for smelting the titanium-nickel alloy, the electrode blocks are assembled and welded to form consumable electrodes, and then the consumable electrodes undergo vacuum smelting to obtain the large titanium-nickel alloy ingots. According to the method, the large titanium-nickel alloy ingots with equal atomic ratios, uniform alloy components and low impurity content can be produced.
Owner:西安赛特思迈钛业有限公司

Forging method for equal-atomic-ratio titanium-nickel alloy large cast ingot

The invention discloses a forging method for an equal-atomic-ratio titanium-nickel alloy large cast ingot. The titanium-nickel alloy large cast ingot is subjected to homogenization treatment, the technological parameter is 930-980 DEG C, and heat preservation time is 10-12 h, and air cooling is conducted; the air-cooled titanium-nickel alloy large cast ingot is subjected to the first heating number of forging, the heating temperature is 900-920 DEG C, heat preservation is conducted for 4-5 h, deformation is phi460-phi320, the strain rate is (0.05-0.10) s<1>, and a forging blank is obtained after the first heating number in a breaking mode; the forging blank is subjected to the second heating number of forging, the heating temperature is 880-900 DEG C, heat preservation is conducted for 3-3.5 h, deformation is phi320-phi200, the strain rate is (0.10-0.25) s<1>, and the forging blank is obtained after the second heating number in a breaking mode; and the forging blank is subjected to the third heating number of forging, the heating temperature is 850-880 DEG C, heat preservation is conducted for 2-2.5 h, deformation is phi200-phi110, the strain rate is (0.05-0.20) s<1>, and a titanium-nickel alloy square billet is obtained in a breaking mode. The method of the low strain rates, the multiple heating numbers and increasing deformation is adopted, forging of the titanium-nickel alloy large cast ingot is achieved, the cracking phenomenon in forging is eliminated, and the good structure and performance of materials are achieved.
Owner:西安赛特思迈钛业有限公司

Preparation method of ZTA particle enhanced steel-based composite grinding roller based on chemical activation treatment

The invention discloses a preparation method of a ZTA particle enhanced steel-based composite grinding roller based on chemical activation treatment. The preparation method comprises the following steps: (1) carrying out high temperature salt-bath plating on ZTA particles, and obtaining uniform titanium plated layers on the surfaces of the ZTA particles; (2) forming nickel layers at the peripheries of the titanium plated layers; (3) sintering the plated ZTA particles, and mutually connecting the ZTA particles to form a porous prefabricated part; and (4) fixing the prefabricated part on the end surface or the working surface of a cast, pouring a steel base material metal solution through a casting-penetrating process, and carrying out cooling to obtain the ZTA particle enhanced steel-based composite grinding roller. During the salt-bath titanium plating, titanium and the surfaces of the ZTA ceramic particles form metallurgical bonding, so that the interfacial bonding property between the titanium layers and the ZTA ceramic particles is enhanced. The ZTA ceramic particles subjected to the salt-bath titanium plating is then subjected to chemical nickel plating, and a titanium-nickel alloy can be generated at a titanium-nickel bonding part; and the titanium-nickel alloy layers achieve the effect of a flexible transitional layer between a metal base body and the ZTA particles, so that the bonding strength of the interface is greatly enhanced.
Owner:XI AN JIAOTONG UNIV

Method of preparing carbon nano tube reinforced composite ceramic layer on surface of titanium-nickel alloy

ActiveCN105039982ASolve the problem that it is difficult to prepare bioactive coatings by micro-arc oxidation technologyAddressing performance mismatchesSurface reaction electrolytic coatingSolid state diffusion coatingPlasma electrolytic oxidationMicro arc oxidation
The invention belongs to the technical field of metal material surface modification, and particularly relates to a method of preparing a carbon nano tube reinforced composite ceramic layer on the surface of a titanium-nickel alloy. The method of preparing the carbon nano tube reinforced composite ceramic layer on the surface of the titanium-nickel alloy comprises the steps that the surface of the titanium-nickel alloy is carburized by adopting a double glow discharge plasma surface alloying technique to form a titanium carbide modification layer; the surface of the titanium-nickel alloy is carburized by adopting the double glow discharge plasma surface alloying technique to form a titanium carbide/titanium gradient modification layer; and by taking the titanium carbide/titanium gradient modification layer as an anode, adopting a micro-arc oxidation technique, and adding a carbon nano tube to a micro-arc oxidation electrolyte, the carbon nano tube reinforced composite ceramic layer is obtained. The bonding strength of the carbon nano tube reinforced composite ceramic layer to a matrix is high, and the hardness, the abrasive resistance, the corrosion resistance and the biocompatibility of the modification layers are improved effectively.
Owner:TAIYUAN UNIV OF TECH

Hot rolling cogging process of Ti-Ni alloy ingot

The present invention relates to high efficiency and low power consumption hot rolling cogging process of Ti-Ni alloy ingot, and features that the technological process includes the steps of: heat treatment of the Ti-Ni alloy ingot, cogging and rolling Ti-Ni alloy rod. The heat treatment before cogging has temperature of 750-950 deg.c, and during the cogging, the deformation region of the Ti-Ni alloy ingot is applied with circumferential symmetrical rolling force and longitudinal continuous gradient rolling force. The rolling process has short period, great rolling deformation rate and high efficiency, and is suitable for industrial production, and the rolled Ti-Ni alloy rod has high sized precision and high finished product rate.
Owner:西安赛特金属材料开发有限公司

Preparation method of multilayer titanium-nickel alloy filter film

The invention provides a preparation method of a multilayer titanium-nickel alloy filter film. The method is characterized by including the steps of: (1) mixing high purity titanium hydride powder and high purity nickel carbonyl powder according to certain proportion; (2) preparing the high purity titanium hydride and nickel carbonyl mixed powder and a polyvinyl butyral liquid into a mixed slurry according to certain mass ratio, covering a smooth quartz surface with a film by a film formation apparatus, and performing standing drying in nitrogen; (3) using thin-layer zinc stearate for spacing on a dried prefabricated film layer, using the mixed slurry for film covering successively, and performing standing drying; and (4) removing the product from the quartz panel surface to form a multilayer titanium-nickel green film, controlling the temperature raising program, and carrying out vacuum sintering, thus obtaining the multilayer titanium-nickel alloy filter film. The method provided by the invention has a simple process, and the obtained material has stable performance, therefore the method is suitable for industrial production.
Owner:CHANGSHA UNIVERSITY OF SCIENCE AND TECHNOLOGY

Titanium/nickel alloy component based on explosion welding and laser additive manufacturing and preparation method

ActiveCN111215855AOvercoming the problem of interface crackingFast formingAdditive manufacturing apparatusGrinding machinesNickel alloyTitanium
The invention discloses a titanium / nickel alloy component based on explosion welding and laser additive manufacturing and a preparation method, and belongs to the technical field of connection of thermometal components. The titanium / nickel alloy component comprises an explosion welding component and a laser additive manufacturing component which are connected. The explosion welding component is atitanium / steel composite plate or titanium / nickel composite plate, and the laser additive manufacturing component is made from a titanium alloy or a nickel-based alloy. According to the titanium / nickel alloy component based on explosion welding and laser additive manufacturing, a middle transition layer is connected through an explosion welding method, and the problem that due to the fact that a titanium / nickel alloy is in direct contact with a generated brittle intermetallic compound, an interface cracks is solved; and the titanium / nickel alloy component is prepared based on the explosion welding component through a laser additive manufacturing process, the forming speed is high, the flexibility is good, and the efficiency is high.
Owner:有研金属复材技术有限公司
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