The invention discloses an environmentally-friendly process with a complete reaction in an
ammonia desulfurization device. The process comprises the following steps: when the
ammonia desulfurization device is used, boiler
flue gas with a temperature of 120-150 DEG C is subjected to gas-
solid separation by a first
cyclone separator, a part of
flue gas after gas-
solid separation is subjected to desulfurization and oxidation treatment,
after treatment is performed by a second
cyclone separator, the treated gas flows into an evaporative dryer through a second circulation pump, the other part of the boiler
flue gas with the temperature of 120-150 DEG C treated by the first
cyclone separator is introduced into the evaporative dryer, the dried particulate matter obtained by the evaporative dryer enters an
ammonium sulfate bin, and packaging treatment is performed by using an automatic
packaging machine. According to the process provided by the invention, the first cyclone separator is arranged to separate dust in the boiler
flue gas to prevent desulfurization efficiency for
sulfur dioxide in the
flue gas from being reduced, an
ammonia concentration in ammonia water is controlled at 10%-20% to prevent the ammonia
water concentration from being too high, if the ammonia
water concentration is high, ammonia escapes, and if the ammonia
water concentration is too low, desulfurization is incomplete, so that under the ammonia concentration condition, the desulfurization effect is good, and an ammonia escape phenomenon is inhibited; and the process has a novel structure and is convenient to operate.