A Diesel engine anti-wear lubricant oil additive composition that includes organo-metallic compounds of Cu, Ce, etc., is used to catalytically burn-off diesel particulate matter (PM) collected by diesel particulate filter (DPF). A fuel borne catalyst (FBC) of Cu,Ce,Fe etc., required for regenerating the DPF is made by blending a predetermined quantity of used engine oil, removed from the engine crankcase oil system, with fuel in the fuel tank of a diesel engine equipped with DPF and EGR systems. A method of fumigating water and catalytic compounds of Cu, Fe, Ce, etc., into the air-intake system of a diesel engine in the EGR gases from the DPF or air, to reduce both PM and NOx emissions from a diesel engine, with improved engine lubrication performance, is also disclosed.