The invention discloses a GC-MS method for measuring volatile characteristic organic matters in water based on multifunctional on-line sample introduction. According to the method, two kinds of onlinepretreatment methods of headspace and dynamic headspace of benzene series (benzene, methylbenzene, ethylbenzene, p-xylene, m-xylene, o-xylene, isopropyl benzene, chlorobenzene and styrene) are established; two kinds of online pretreatment methods of a solid-phase micro-extraction method and a magnetic stirring adsorption extraction method of two kinds of odor substances (geosmin and dimethyl isocamphitol), and four kinds of a formula which is as shown in the specification are established; and then online sample introduction GC-MS detection is carried out. The detection result shows that the detection limit, the recovery rate, the precision and the like of the on-line method for detecting the volatile organic matters in the three categories can meet the measurement requirements; the onlinedetermination efficiency is improved by one half to two thirds, and the method is simple, convenient, environment-friendly and efficient. According to the method, the sample detection sensitivity iseffectively improved by adding the aid and a secondary adsorption mode, and meanwhile, the traditional thermal desorption sample introduction mode is changed, and the accuracy and operability of sample detection are both optimized.