The invention provides a composite film having gas barrier, heat insulation and fire resistance properties. The composite film is characterized in that the composite film is sequentially formed by an inorganic fiber cloth layer 10, an aluminum-plastic composite layer 20 and a plastic composite layer 30 from outside to inside, and a binder is bonded between each two adjacent layers. The invention also provides a making method of the composite film having gas barrier, heat insulation and fire resistance properties. The barrier film has the characteristics of low gas and water transmittance, good alkali resistance, good weather resistance, good fire resistance, good puncture resistance, and no generation of a chemical reaction with an alkaline cement mortar, and can be widely used in the fields of machines, electronics, buildings, aviations, spaceflights, automobiles and ships needing heat insulation in the cold, hot and wet environments.