81results about How to "Excellent oxygen absorption performance" patented technology

An oxygen absorption resin composition is provided that comprises a thermoplastic resin (A) having carbon-carbon double bonds substantially in its main chain and a transition metal salt (B). If necessary, the composition further comprises a gas barrier resin (C), a compatibilizer (D) and the like. The composition has excellent oxygen absorption properties, and when the composition is employed, generation of odorous substances derived from the decomposition of resins as a result of oxygen absorption can be suppressed.

[Problem to be Solved] To provide an oxygen-absorbable resin composition that does not require any metal incorporated thereinto and has excellent oxygen absorbability even at room temperature, an oxygen-absorbable barrier resin composition also exhibiting excellent gas-barrier property, oxygen-absorbable molded article comprised of the resin composition, an oxygen-absorbable packaging material comprised of the molded article, and an oxygen-absorbable packaging container.[Means for Solving Problems] THE oxygen-absorbable resin composition comprises an oxygen-absorbable resin (A) having a cycloene structure in the molecule and a softener (B) and has a glass transition temperature of not higher than 30° C. The oxygen-absorbable barrier resin composition comprises a barrier resin (C) in addition to (A) and (B). The oxygen-absorbable resin (A) having a cycloene structure in the molecule is preferably a cyclized product of a conjugated diene polymer having an unsaturated bond reduction ratio of at least 60%. The softener (B) is preferably liquid paraffin or polybutene.

An oxygen absorption resin composition is provided that comprises a thermoplastic resin (A) having carbon-carbon double bonds substantially in its main chain and a transition metal salt (B). If necessary, the composition further comprises a gas barrier resin (C), a compatibilizer (D) and the like. The composition has excellent oxygen absorption properties, and when the composition is employed, generation of odorous substances derived from the decomposition of resins as a result of oxygen absorption can be suppressed.

The invention aims at providing an oxygen-absorbing resin which has excellent oxygen absorption performance and which can dispense with the addition of a transition metal catalyst or the irradiation with a radiation. The invention provides an oxygen-absorbing resin which is obtained by polymerizing a raw material containing a monomer (A) having an unsaturated alicyclic structure bearing a carbon-carbon double bond wherein one carbon atom adjacent to the carbon-carbon double bond is bonded to an electron-donating substituent and a hydrogen atom and another carbon atom adjacent to the carbon atom is bonded to a heteroatom-containing functional group or a bonding group derived from the functional group with the electron-donating substituent and the functional or bonding group taking cis-configuration and which contains the unsaturated alicyclic structure in an amount of 0.5 to 10 meq / g; oxygen-absorbing resin compositions containing the above oxygen-absorbing resin; and oxygen-absorbing containers, characterized by having an oxygen-absorbing layer made from the resin or the compositions.

The present invention herein provides an oxygen-absorbing resin composition which is excellent in the oxygen-absorbability and which can inhibit any deterioration through oxidation during the molding operations of the composition and does not accordingly undergo any coloration during the molding operations. The present invention thus provides an oxygen-absorbing resin composition characterized in that it comprises (A) a hydrogenated styrene-diene copolymer; (B) a thermoplastic resin including ethylenic structural units in its molecular structure; and (C) a transition metal catalyst, wherein the oxidation of the thermoplastic resin (B) proceeds while the copolymer (A) serves as a trigger and the composition thus absorbs oxygen. In this respect, the copolymer (A) comprises carbon-carbon double bonds derived from the diene in an amount ranging from 1×10−5 to 1×10−2 eq / g.

The present invention provides an oxygen-absorbing resin composition containing a thermoplastic resin (A) having carbon-carbon double bonds substantially only in the main chain and a transition metal salt (B), and the oxygen absorption amount of 1 mol of carbon-carbon double bond of the thermoplastic resin (A) being 1.6 mols or more.

The present invention provides an oxygen-absorbing resin composition containing a thermoplastic resin (A) having carbon-carbon double bonds substantially only in the main chain and a transition metal salt (B), and the oxygen absorption amount of 1 mol of carbon-carbon double bond of the thermoplastic resin (A) being 1.6 mols or more.

A polyamide compound containing from 25 to 50 mol % of a diamine unit that contains at least 50 mol % of an alicyclic diamine unit represented by the following general formula (I); from 25 to 50 mol % of a dicarboxylic acid unit that contains a linear aliphatic dicarboxylic acid unit represented by the following general formula (II-1) and / or an aromatic dicarboxylic acid unit represented by the following general formula (II-2) in an amount of at least 50 mol % in total; and from 0.1 to 50 mol % of a constituent unit represented by the following general formula (III):wherein, in the formulae, n indicates an integer of from 2 to 18; Ar represents an arylene group; and R represents a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group.

The present invention provides an oxygen-absorbing resin composition, which is superior in oxygen absorbability, absorbs oxygen remaining in the container after sealing, keeps the contents in the container in good preservation, and improves moldability, dispersibility of the oxygen absorbent, stability of the oxygen absorbing performance, performance of preventing peeling and separation of the oxygen absorbent from the base resin, rigidity of the sealing part, and the like, which become problems in the case of including an oxygen absorbent having high oxygen absorbability and low compatibility with the base resin, as well as provides an oxygen-absorbing container cap and an oxygen-absorbing container plug using the same.The present invention provides an oxygen-absorbing resin composition characterized by being obtained by dispersing and blending an oxygen absorbent containing 20% or more of particles having a particle diameter of 1000 μm or less at a ratio of 20% or less to a base resin.

A polyamide resin composition containing a polyamide resin (A); and a metal compound (C) containing at least one metal atom selected from iron, manganese, copper, and zinc; or a colorant (D) containing at least one metal atom selected from iron, manganese, copper, and zinc; wherein the polyamide resin (A) contains 25 to 50% by mol of a diamine unit containing a specific diamine unit in an amount of 50% by mol or more, 25 to 50% by mol of a dicarboxylic acid unit containing a specific dicarboxylic acid unit in an amount of 50% by mol or more, and 0.1 to 50% by mol of a specific constitutional unit.

A polyamide compound containing: from 25 to 50 mol % of a diamine unit, which contains an aromatic diamine unit represented by the following formula (I), in an amount of 50 mol % or more; from 25 to 50 mol % of a dicarboxylic acid unit, which contains a linear aliphatic dicarboxylic acid unit represented by the following formula (II-1) and / or an aromatic dicarboxylic acid unit represented by the following formula (II-2), in an amount in total of 50 mol % or more; and from 0.1 to 50 mol % of a constitutional unit represented by the following formula (III):wherein n represents an integer of from 2 to 18, Ar represents an arylene group, and R represents a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group.

The invention provides oxygen-absorbing resin compositions which are reduced in the quantity of by-product oxides and are excellent in oxygen-absorbing capacity, more specifically, an oxygen-absorbing resin composition which comprises a styrene resin, a thermoplastic resin having ethylene structure in the molecular structure, and a transition metal catalyst and in which the oxidation of the thermoplastic resin proceeds by the action of the styrene resin as a trigger to attain oxygen absorption, wherein the styrene resin comprises two kinds of styrene resins (A) and (B) different in styrene content and the styrene content of the resin (A) is higher than that of the resin (B); and an oxygen-absorbing resin composition comprising polyethylene, a resin other than polyethylene which is capable of acting as a trigger in the oxidation of polyethylene, and a transition metal catalyst, wherein the polyethylene comprises two or more kinds of polyethylenes and at least one of them is a linear low-density polyethylene obtained by copolymerizing ethylene with at least 4 wt % of a 1-alkene having 3 to 6 carbon atoms.

To provide an oxygen-absorbing polyester resin composition which exhibits excellent oxygen-absorbing capability even in the absence of transition metal catalyst without affected by the glass transition temperature of a polyester resin that is contained as a base resin.The oxygen-absorbing polyester resin composition including a base resin (A) which is a polyester resin, an oxygen-absorbing component (B) which is a compound having an unsaturated alicyclic structure, and an oxidation promotion component (C) for promoting the oxidation of the oxygen-absorbing component (B), said oxidation promotion component (C) being a compound having a benzyl hydrogen.

The invention aims at providing an oxygen-absorbing resin which has excellent oxygen absorption performance and which can dispense with the addition of a transition metal catalyst or the irradiation with a radiation. The invention provides an oxygen-absorbing resin which is obtained by polymerizing a raw material containing a monomer (A) having an unsaturated alicyclic structure bearing a carbon-carbon double bond wherein one carbon atom adjacent to the carbon-carbon double bond is bonded to an electron-donating substituent and a hydrogen atom and another carbon atom adjacent to the carbon atom is bonded to a heteroatom-containing functional group or a bonding group derived from the functional group with the electron-donating substituent and the functional or bonding group taking cis-configuration and which contains the unsaturated alicyclic structure in an amount of 0.5 to 10 meq / g; oxygen-absorbing resin compositions containing the above oxygen-absorbing resin; and oxygen-absorbing containers, characterized by having an oxygen-absorbing layer made from the resin or the compositions.

The present invention provides a novel oxygen absorbent composition being capable of realizing an oxygen absorbent not responding to a metal detector, being suppressed in the increase of the odor intensity after the absorption of oxygen and having an excellent oxygen absorption performance over a wide range of humidity conditions from low humidity to high humidity, and provides an oxygen absorbent package using the oxygen absorbent composition. The oxygen absorbent composition of the present invention includes at least one compound having a tetralin ring represented by the following general formula (1) and a transition metal catalyst: