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1290 results about "Lignosulfonates" patented technology

Lignosulfonates, or sulfonated lignin, (CAS number 8062-15-5) are water-soluble anionic polyelectrolyte polymers: they are byproducts from the production of wood pulp using sulfite pulping. Most delignification in sulfite pulping involves acidic cleavage of ether bonds, which connect many of the constituents of lignin. The electrophilic carbocations produced during ether cleavage react with bisulfite ions (HSO₃⁻) to give sulfonates.

Application of tungsten-based catalyst in lignin catalytic hydrogenation for producing aromatic compound

The invention relates to hydrocracking of lignin, and specifically relates to a method for applying a tungsten-based catalyst to catalyze lignin hydrocracking for producing an aromatic compound. The catalyst comprises a main active component of non-zero-valent tungsten, and a second metal component of a small amount of one or more transition metals selected from zero-valent nickel, cobalt, ruthenium, iridium, palladium, platinum, iron, and copper. According to the method, raw materials such as lignin, biomass hydrolysis residue, lignosulfonate, and alkaline lignin are subject to catalytic hydrogenation under a hydrothermal condition with a temperature of 120 to 450 DEG C and a hydrogen pressure of 1 to 20MPa; the raw materials are cracked into C6-C9 phenolic compounds with high selectivity. A maximal phenol yield reaches 55.6%. Compared to existing technologies, according to the invention, renewable natural biomasses are adopted as raw materials, such that the raw materials are cheap, and have wide sources; inorganic acid and alkali are not required, such the production of a large amount of alkaline solution in traditional lignin catalysis is avoided; the tungsten-based catalyst is cheap; the reaction process is green, and has atom economical characteristics.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Modified aliphatic high-efficiency water-reducing agent by utilizing lignosulfonate and preparation method thereof

The invention relates to a method for preparing a modified aliphatic high-efficiency water-reducing agent by utilizing lignosulfonate, belonging to the field of concrete water-reducing agents. The invention adopts acetone and formaldehyde as condensation monomers and lignosulfonate as a modifying agent and carries out sulfonating and condensation reactions under an alkaline condition to produce anovel high-efficiency concrete water-reducing agent. The preparation method of the novel high-efficiency concrete water-reducing agent comprises the following steps: (1) adding a sulfonating agent, acetone and water to a reactor, increasing the temperature to 25-65 DEG C and reacting for 0.1-1.5 hours; (2) dipping part of formaldehyde solution for 0.25-2.5 hours, increasing the temperature to 70-95 DEG C and reacting for 1-6 hours; and (3) decreasing the temperature to below 60 DEG C, adding the lignosulfonate and the rest of the formaldehyde solution to the reactor, using an alkaline regulator to regulate a pH value of the system to be 8.0-14.0, increasing the temperature to 70-98 DEG C, reacting for 1-5 hours and decreasing the temperature before discharging. The modified aliphatic high-efficiency water-reducing agent is suitable for producing commercial concrete which has similar color as normal concrete and has smaller collapsed slump loss. By adjusting the process, such as proportioning raw materials, and the like and effectively utilizing the lignosulfonate, the invention not only decreases the product cost, but also lessens environmental pollutants and has favorable industrialized prospects.
Owner:NANJING FORESTRY UNIV

Composition board binding material

This invention features a graft copolymer of lignosulfonates reacted with an unsaturated carbonyl compound and an aldehyde, in two separate reaction steps. The resin can be used as a substitute for a majority of pure urea formaldehyde resin in the manufacture of composite board products. The resin can also be introduced directly into the urea formaldehyde resin production process.
Owner:CELLUTECH

Water-coal-slurry additive and preparation method thereof

The invention provides a water-coal-slurry additive and a preparation method thereof. The additive is compounded by anionic surfactant naphthalene sulfonic acid formaldehyde condensation product sodium salt, lignosulphonate and non-ionic surfactant alkylphenol polyethenoxy ether (methyl) acrylic ester according to mass ratio of 8:1:1 to 1:8:1. The invention uses the naphthalene sulfonic acid formaldehyde condensation product sodium salt, lignosulphonate and alkylphenol polyethenoxy ether (methyl) acrylic ester in the preparation technology of water-coal-slurry, and the additive has wide adaptability to coal, in particular to coal with low degree of metamorphism. When ternary compound additive reaches 0.1-1wt percent of the weight (dry basis) of the coal, the water-coal-slurry with the content of coal dust being 62-70wt percent can be prepared. The slurry has good fluidity, lower apparent viscosity and favorable steady state stability. The ternary compound additive is simple in production process, excellent in performance and wide in the range of applicable coal.
Owner:ENN XINNENG BEIJING TECH

Coal water slurry additive and preparation method and application thereof

The invention discloses a coal water slurry additive and a preparation method and application thereof. The method is characterized in that the coal tar fraction wash oil is taken as the starting material, carries out sulfonation reaction with a sulfonating agent and then carries out polycondensation reaction with aminobenzene sulfonate, phenols and formaldehyde; and neutralization is carried out after reaction is completed. The method can greatly lower the production cost, and the obtained additive has the advantages of small mixing amount, excellent dispersibility, good slurry forming ability and stability and reduction of the stabilizing agent in the coal water slurry. The additive can not only be independently used for preparing the coal water slurry, but also be used by being compounded with other types of additives, such as naphthalene sulfonate-formaldehyde condensates, polycarboxylic acid additives or lignosulfonate and other anionic surfactants and synthesize the coal water slurry suitable for different types of coal by adjusting the production conditions. The coal water slurry prepared by the additive has the solid content between 63% and 70% and is easy to flow and clean. The viscosity of the coal water slurry is controlled below 1200mPa.s at the shearing rate of 100s<-1>.
Owner:CHINA COAL RES INST CCRI ENERGY SAVING TECH CO LTD +1

Insecticidal Compositions Suitable For Use in Preparation of Insecticidal Liquid Fertilizers

Insecticidal compositions suitable for use in preparation of insecticidal liquid fertilizers comprising a pyrethroid, a hydrated aluminum-magnesium silicate, and at least one dispersant selected from the group consisting of a sucrose ester, a lignosulfonate, an alkylpolyglycoside, a naphthalenesulfonic acid formaldehyde condensate and a phosphate ester are disclosed.
Owner:FMC CORP

Wood Adhesives Comprising Protein and Oxazoline Polymer or Resin

The present invention provides wood adhesive binder compositions comprising a naturally occurring protein component, e.g. soy flour, and an oxazoline-functional group containing polymer or resin component, the two components in a solids weight ratio of from 60:40 to 98:2. As formulated, the compositions may comprise from 40 to 98 wt. % of the naturally occurring protein component, preferably, 50 wt. % or more. Preferably, the wood adhesive binder further comprises lignins or lignosulfonate. Where the wood adhesive binder compositions comprise lignins or lignosulfonates, they remain more fluid and workable at a higher pH such as, for example, 4.5 or more. Any of the compositions may be formulated with one or more in situ acid generator compound to insure more rapid cure on heating or pressing. The binder enables the provision of mechanically sound, low cost and biodegradable composites, such as, medium density fiberboard (MDF).
Owner:BRADY JEAN M +4

Novel active water fracturing fluid for fracturing of coal bed gas well

InactiveCN101948684AWith anti-expansion effectHas the effect of reducing resistanceDrilling compositionPotassiumFracturing fluid
The invention relates to a fracturing fluid for the fracturing construction of coal bed gas well. In general, a coal bed gas well cannot be put into operation before the fracturing construction. Owing to the characteristics of small harm, low cost, convenient preparation and the like, the active water is extensively applied to the fracturing construction of coal bed gas well. The typical active water fracturing fluid is generally prepared from clear water, anti-swelling agent (typically potassium chloride) and cleanup additive (typically complex of surfactants, typical cleanup additive for oil field is D-60 and HP-8, etc.) based on certain proportions. The active water fracturing fluid shows, when being used for the fracturing construction, the defects of high frictional resistance and no dispersion effect on coal dusts generated in the process of the fracturing construction. The active water fracturing fluid according to the invention is prepared in a manner of adding the typical active water fracturing fluid with drag-reducing agent (anionic or nonionic polyacrylamide) and coal dust dispersing agent (lignosulfonate, such as sodium lignin sulfonate) based on the mass percents as below: 1%-2% of potassium chloride, 0.02% to 0.06% of drag-reducing agent and 0.01% to 0.03% of dispersing agent. The fracturing fluid according to the invention has the characteristics of simple formula, the effect of reducing frictional resistance of construction tubular columns and uniformly dispersing coal dusts, small harm to coal bed and easy flowback.
Owner:CHINA UNITED COALBED METHANE +1

Stable Mixtures of Microencapsulated and Non-Encapsulated Pesticides

The present invention is directed to a composition comprising i) a microencapsulated pesticide, ii) a dispersant selected from the group consisting of a lignin, b) a lignosulfonate salt and c) a lignosulfonate salt combined with the sodium salt of substituted naphthalene sulfonate formaldehyde polymer, iii) a salt selected from the group consisting of magnesium sulfate, sodium chloride, sodium nitrate and calcium chloride, and iv) a non-encapsulated pesticide. The present invention is also directed to methods of making and using the compositions of the present invention.
Owner:FMC CORP

Carboxylated lignin based binders

The present invention provides binder compositions comprising an ethylenically unsaturated carboxy acid grafted lignin or lignosulfonate component, and an oxazoline-functional group containing polymer or resin component, the two components in a solids weight ratio of from 50:50 to 98:2. As formulated, the compositions may comprise from 40 to 98 wt. % of the acid grafted lignosulfonate, preferably, 50 wt. % or more. Preferably, the binder composition further comprises one or more in situ acid generator compound to insure more rapid cure on heating or pressing. The binder enables the provision of low cost composite materials comprising a majority component derived from natural materials, and having a reasonable wet strength.
Owner:CRESCIMANNO STEPHEN A +1

Concrete material and preparation method thereof

The invention provides a concrete material, comprising the following components with corresponding proportions: cement, fine aggregate, coarse aggregate, fly ash, silica fume, carbon nanotube, nano silica, ceramsite, polyphenyl particles, steel fibers, nano kaolin particles, ultrafine natural zeolite powder, gypsum, polymer emulsion, a diol compound, modified lignosulfonate, a layered silicate mineral material, polysiloxane, oxalic acid, styrene acrylic emulsion, crystalline hydrated magnesium aluminum silicate minerals, water, a super plasticizer, a barium-containing naphthalene superplasticizer, an organic polymer plastic retaining agent, a composite retarder and an air entraining agent. The invention further relates to a preparation method of the concrete material. Compared with the existing concrete, various properties of the concrete material provided by the invention are greatly improved. The concrete material has a wide application range, a significant practical engineering value and remarkable technical and economic significance.
Owner:NORTH CHINA UNIV OF WATER RESOURCES & ELECTRIC POWER

Set retarders for foamed cements

An improved non-dispersing set retarder additive for foamed cements, cement compositions containing the additive, and methods of cementing in a subterranean zone penetrated by a well bore are provided. The set retarder additive includes a blend of a sulfonated lignin, preferably a lignosulfonate, with an alkali lignin, preferably a kraft lignin, having an organic sulfur content of 0-3.5% by weight in a ratio of about 6:4 to 8:2. The methods are basically comprised of the steps of preparing a foamed cement composition comprised of hydraulic cement, a non-dispersing set retarder, sufficient water to form a slurry, sufficient gas to foam the slurry and a foaming and foam stabilizing surfactant present in an amount sufficient to facilitate the formation of the foam and stabilize the foamed cement composition.
Owner:LIGNOTECH USA INC
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