The invention discloses a method for preparing
cell-grade high-purity
manganese sulfate by low-grade
manganese ore high-pressure
crystallization. The method comprises the following steps of
grinding low-grade
pyrolusite and
pyrite into
powder particles, preparing a
manganese sulfate solution, mixing the manganese
sulfate solution and the
pyrolusite powder particles to obtain preliminary pulp, mixing the preliminary pulp, concentrated
sulfuric acid and the
pyrite powder particles according to a certain ratio, carrying out heating, stirring and manganese impregnation on the mixture, adding a neutralizer into the mixture to adjust a pH value, adding
barium sulphide and
sodium dimethyldithiocarbamate into the mixture to remove impurities so that a pure manganese sulfate solution is obtained, carrying out heating pressurization stirring on the pure manganese sulfate solution, discharging a supernatant to obtain a manganese sulfate
crystal-containing solution, carrying out standing
precipitation of the manganese sulfate
crystal-containing solution at a normal temperature, carrying out
filtration to obtain a high-concentration manganese sulfate solution, adding the high-concentration manganese sulfate solution into a high-pressure
autoclave, carrying out
crystallization at a high temperature under
high pressure, discharging a supernatant after
crystallization to obtain manganese sulfate
crystal-containing
magma, separating the manganese sulfate crystal-containing
magma to obtain high-purity manganese sulfate crystals, and
drying and crushing the high-purity manganese sulfate crystals to obtain the
cell-grade high-purity manganese sulfate.