Heavy metal polluted soil treatment processing agent and preparation method thereof
A technology of contaminated soil and treatment agent, which is applied in the field of treatment agent and its preparation for heavy metal-contaminated soil, can solve the problems of unsatisfactory treatment effect and long treatment cycle, and achieve the goal of increasing utilization rate, reducing preparation cost and being easy to realize Effect
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Embodiment 1
[0037] An improvement of the treatment agent for treating heavy metal-contaminated soil provided by the present embodiment, in terms of mass percentage, includes the following components:
[0038] Sodium dimethyl dithiocarbamate chelating agent 60%;
[0039] Sodium diethyldithiocarbamate chelating agent 30%;
[0040] Polyethyleneimine 10%.
[0041] Its preparation method is:
[0042] Include the following steps:
[0043] In the first step, liquid dimethylamine is added to ethylenediamine to make a mixture of ethylenediamine and dimethylamine, wherein the molar ratio of ethylenediamine and dimethylamine is 1:3;
[0044] In the second step, a sufficient amount of carbon disulfide is added to the mixture of ethylenediamine and dimethylamine obtained in the first step, so that ethylenediamine and dimethylamine react with carbon disulfide respectively, and the reaction temperature is controlled below 10°C to obtain the intermediate product;
[0045] The 3rd step, in intermediate...
Embodiment 2
[0048] An improvement of the treatment agent for treating heavy metal-contaminated soil provided by the present embodiment, in terms of mass percentage, includes the following components:
[0049] Potassium Dimethyl Dithiocarbamate Chelating Agent 52%;
[0050] Potassium diethyldithiocarbamate chelating agent 40%;
[0051] Polyethyleneimine 8%.
[0052] Its preparation method is:
[0053] Include the following steps:
[0054] In the first step, liquid dimethylamine is added to ethylenediamine to make a mixture of ethylenediamine and dimethylamine, wherein the molar ratio of ethylenediamine and dimethylamine is 1:2;
[0055] In the second step, a sufficient amount of carbon disulfide is added to the mixture of ethylenediamine and dimethylamine obtained in the first step, so that ethylenediamine and dimethylamine react with carbon disulfide respectively, and the reaction temperature is controlled below 10°C to obtain the intermediate product;
[0056] The 3rd step, in inter...
Embodiment 3
[0059] An improvement of the treatment agent for treating heavy metal-contaminated soil provided by the present embodiment, in terms of mass percentage, includes the following components:
[0060] Iron dimethyl dithiocarbamate chelating agent 63%;
[0061] Iron diethyldithiocarbamate chelating agent 25%;
[0062] Polyethyleneimine 12%.
[0063] Its preparation method is:
[0064] Include the following steps:
[0065] In the first step, liquid dimethylamine is added to ethylenediamine to make a mixture of ethylenediamine and dimethylamine, wherein the molar ratio of ethylenediamine and dimethylamine is 1:4;
[0066] In the second step, a sufficient amount of carbon disulfide is added to the mixture of ethylenediamine and dimethylamine obtained in the first step, so that ethylenediamine and dimethylamine react with carbon disulfide respectively, and the reaction temperature is controlled below 10°C to obtain the intermediate product;
[0067] The third step is to add ferric...
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