The invention provides a comprehensive recycling technique of valuable elements in
smelting soot, which comprises the steps of: adding
sulfuric acid in the
smelting soot to pulpify the same, leaching for twice, and filter pressing the
smelting soot to form lead-silver-
bismuth slag; smelting,
casting, electrolyzing, refining and reducing and smelting the lead-silver-
bismuth slag in a converter to obtain rough lead,
copper matte, pure
bismuth and silver-
zinc slag; adding
cupric hydroxide in the supernatant to deposit
arsenic, depositing the
copper in the
copper arsenate slag with deposited
arsenic to form copper-
arsenic solution, concentrating, crystallizing, dissolving and separating the solution to obtain
white arsenic and cupric
sulfate solution; performing twice electrodeposition treatments on the copper-
zinc-
cadmium solution with deposited arsenic to respectively obtain electrolytic copper and black copper, sequentially adding
zinc oxide and zinc
powder to perform deacidification, high-temperature copper removal and low-temperature
cadmium removal treatments to obtain
sponge cadmium, smelting the
sponge cadmium to obtain rough cadmium, concentrating and crystallizing the zinc
sulfate solution to obtain heptahydrate zinc
sulfate. The comprehensive recycling technique provided by the invention has the advantages of improving the
recovery of multiple metals, having extensive treatment raw materials, low production cost and high economic benefit, and avoiding the secondary
pollution of decentralized
processing and
secondary loss of valuable metals.