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158results about How to "Strong oxidizing" patented technology

Preparation method and application of electrode of composite material of iron porphyrin chloride/methylene blue @metal-organic framework

The invention provides a preparation method and application of an electrode of a composite material of an iron porphyrin chloride / methylene blue @metal-organic framework. Iron porphyrin chloride (FeTCPP) is encapsulated to a Zn metal-organic framework (MOF) by a one-pot method, a composite material of the metal-organic framework has negative charges in a solution, and cationic dye methylene blue (MB) with oxidation-reduction activity can be absorbed. The composite material is modified to the surface of a glass carbon electrode, and dopamine can be catalyzed and oxidized so that an electrical signal can be produced, sensitive detection for the dopamine is realized by an electrochemical method, the lowest detection limit can reach 0.48fM, and the detection range is wide. The composite material of the metal-organic framework disclosed by the invention is synthesized for the first time, and besides, the composite material of the metal-organic framework is also applied to the field of electrochemical sensing for the first time, the method is simple, the cost is low, and high electrochemical sensing sensitivity indicates that the composite material of the metal-organic framework functionalized by porphyrin and methylene blue has good application prospects in the field of electrochemical and biological sensing.
Owner:QINGDAO UNIV

Flat-plate type high-temperature SCR (Selective Catalytic Reduction) denitration catalyst and preparation method thereof

The invention belongs to the field of environmental protection and environmental catalysis and particularly relates to a flat-plate type high-temperature SCR (Selective Catalytic Reduction) denitration catalyst and a preparation method thereof. The preparation method comprises the following steps of: by adopting a nano composite oxide CeO2-TiO2 or CeO2-ZrO2 as a carrier, and adopting WO3 as an active component, carrying out stepped mixing, rolling coating, pleating, shearing, drying and roasting to obtain the flat-plate type high-temperature SCR denitration catalyst on the basis of adopting CeO2-TiO2 or CeO2-ZrO2 composite oxide as the carrier. The product has excellent high-temperature denitration performance, and is applicable to flue-gas denitration under the temperature of 500-700 DEG C; and the product has excellent mechanical performance, sulfur-dioxide poisoning resistance and sintering resistance.
Owner:北京华电光大环境股份有限公司

Manufacturing method of high-strength oxidable aluminum alloy plate strip

The invention discloses a manufacturing method of a high-strength oxidable aluminum alloy plate strip. The manufacturing method of the high-strength oxidable aluminum alloy plate strip comprises the following steps that (1) molten aluminum alloy is prepared, specifically, chemical elements are determined, and the aluminum alloy comprises, by mass, 0.6%-0.9% of Si, 0.1%-1.4% of Fe, 0.6%-0.9% of Cu, 0.2%-0.3% of Mn, 0.9%-1.1% of Mg, 0-0.05% of Cr, 0-0.05% of Zn, 0-0.05% of Ti, 0-0.05% of single impurities, 0-0.15% of blended impurities, and the balance Al; (2) casting is conducted; (3) hot rolling is conducted; (4) intermediate annealing is conducted; (5) cold rolling and finish rolling are conducted; and (6) continuous pull-correcting or predrawing is conducted. The aluminum alloy plate strip manufactured through the method has high strength, the tensile strength T.S(delta b / MPa) is equal to or higher than 350 MPa, the yield strength Y.S(delta 0.2 / MPa) is equal to or higher than 320 MPa, the extensibility (theta / %) is equal to or higher than 8%, and the surface hardness HV is equal to or higher than 120. The type of the aluminum alloy plate strip manufactured through the method is TY62-T651, the aluminum alloy plate strip is high in supporting strength and surface strength and oxidable when used for a side key of a mobile phone support, continuous punching can be achieved, and the production efficiency is high.
Owner:昆山灿鑫精密电子科技有限公司

Cobalt-load cerium manganese oxide catalyst and preparation method thereof

ActiveCN105289641AExcellent oxygen storage and release capacityGood catalytic oxidation performanceMetal/metal-oxides/metal-hydroxide catalystsCobalt oxideManganese oxide
The invention discloses preparation of a cobalt-load cerium manganese oxide catalyst. Cerium manganese oxide is prepared through an oxidization reduction method, then cobalt is loaded to the cerium manganese oxide through an equivalent-volume impregnation method, manganese oxide has good oxidization performance, cerium oxide has excellent oxygen storage and release capacity, cobalt oxide also has certain oxidization performance, the catalyst has good purifying efficiency on low-concentration nitric oxide, the conversation rate can be 96% at the temperature of 25 DEG C, long service life can also be kept, meanwhile raw materials for preparing the catalyst are easy to obtain, the technology is simple, cost is low, and industrial production can be achieved easily.
Owner:SHANGHAI NAT ENG RES CENT FORNANOTECH

Diesel vehicle oxidized form catalyst having low temperature activity and preparation method thereof

The invention relates to a diesel vehicle oxidized form catalyst having low temperature activity and a preparation method thereof.The catalyst comprises a carrier and a coating applied to the carrier, the coating is loaded with noble metal, the coating comprises tungsten-aluminum silicon composite oxide and molecular sieves, the noble metal is one of Pt and Pd or a mixture of the two types of substances, the coated weight of the coating is 80-180 grams/liter, and the coated weight of the noble metal is 0.5-4.5 grams/liter.The preparation method comprises the steps of firstly, preparing the tungsten-aluminum silicon composite oxide through an equivalent-volume impregnation method, then making slurry with the molecular sieves and the tungsten-aluminum silicon composite oxide according to the mass ratio of 1: (2-10), adding the noble metal Pt and Pd, finally immersing the carrier into the slurry, and conducting drying and sintering, so that the diesel vehicle oxidized form catalyst is obtained.The preparation method of the catalyst is simple, the steps are easy to operate, the prepared diesel vehicle oxidized form catalyst is low in combustion temperature, high in conversion rate and good in thermal stability, good capability for oxidizing HC and CO in tail gas of a diesel vehicle is achieved, and good sulfur resistance is achieved.
Owner:WUXI WEIFU ENVIRONMENT PROTECTION CATALYST

Ozone oxidation reactor

The invention discloses an ozone oxidation reactor. The ozone oxidation reactor comprises a tank body and a water inlet pipe communicated with the tank body. The water inlet pipe is provided with a water inlet and an ozone inlet. Ozone is fed in the ozone inlet. A hydrodynamic cavitation device allowing water and the ozone to generate hydrodynamic cavitation is arranged in the water inlet pipe. Ultrasonic oscillators allowing the water and the ozone to generate ultrasound cavitation are arranged in tank body and connected with an ultrasonic generator. A cavity of the tank body is filled with catalysts for motivating the ozone to generate hydroxyl radical. According to the ozone oxidation reactor, ozone oxidation is combined with an ultrasonic cavitation technology and a hydrodynamic cavitation technology to form a synergetic catalytic ozonation technology, the hydroxyl radical with the higher oxidation performance and lower reaction selectivity is generated, the oxidation potential of the hydroxyl radical can reach 2.8 V, the hydroxyl radical can generate a chain reaction with most of organic pollutants unselectively, hazardous substances are converted into CO2, H2O and mineral salt, the chemical oxygen demand is lowered, and meanwhile secondary pollution is avoided.
Owner:INST OF SINOPEC OILFIELD EQUIP CORP +1

Membrane functional monomer containing hexafluoroisopropanol group and nanofiltration membrane preparation method thereof

The invention relates to a membrane functional monomer containing a hexafluoroisopropanol group and a nanofiltration membrane preparation method thereof. A monomer which contains 1-hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl dianil compound as a nanofiltration membrane is designed and synthesized. The fluorine-containing nanofiltration membrane monomers are different monomers obtained from the reaction of a 4, 4'-dianil compound containing different substituent groups and hexafluoroacetone trihydrate. The nanofiltration membrane preparation method comprises the following steps of: fixing a basement membrane; soaking the basement membrane into a fluorine-containing monomer aqueous-phase solution; removing the superfluous aqueous-phase solution on the membrane surface, and then performing single interfacial polymerization on the basement membrane and a polybasic acyl chloride solution; drying for 1-5 minutes in air; performing heat treatment at 40-100 DEG C for 2-15 minutes; and rinsing, thereby obtaining the fluorine-containing nanofiltration membrane. The nanofiltration membrane preparation method has the advantages that the prepared fluorine-containing nanofiltration membrane has an excellent effect of retaining bivalent cations and anions and has ultrahigh property for resisting oxidation of free chlorine.
Owner:EAST CHINA UNIV OF SCI & TECH

Method for discoloring sulfuric acid by using potassium permanganate

The invention relates to a method for discoloring sulfuric acid by using potassium permanganate. The method comprises the following steps of: filling potassium permanganate saturated water solution at normal temperature into sulfuric acid in a closed sulfuric acid discoloring tank at a speed of 0.1-0.8L / min.t, wherein the volume ratio of sulfuric acid to potassium permanganate saturated water solution at normal temperature is 1000: (2-8); and continuously stirring at a speed of 8-15 turns per minute, and statically placing the discolored sulfuric acid discharged from the sulfuric acid discoloring tank at least 1 day to obtain the finished product sulfuric acid. The method for discoloring sulfuric acid by using potassium permanganate has the advantages that since the potassium permanganate solution is used, the oxidizability is strong, the selectivity is good, the process is simple, convenient and flexible and the tawny or black brown sulfuric acid can be discolored; and the problem that the color and the clarity of the finished product sulfuric acid which is produced by using gypsum flue gas cannot satisfy the standard can be solved, the quality of the sulfuric acid which is produced by using the gypsum flue gas can be enabled to satisfy the standard on industrial concentrated sulfuric acid high-class products, the market competitiveness of the sulfuric acid which is produced by using gypsum is improved and the economic benefits of enterprises are increased.
Owner:刘立文

Easy-cleaning ceramic glaze as well as preparation method and application thereof

InactiveCN104909837AImproved cleanlinessImprove self-cleaningIron removalKaolin clay
The invention discloses an easy-cleaning ceramic glaze as well as a preparation method and application thereof. The easy-cleaning ceramic glaze consists of the following raw materials in percentage by weight: 33-35% of potash feldspar, 10-12% of kaolin, 13-15% of calcium oxide, 8-10% of magnesium oxide, 6-8% of zinc oxide and 24-26% of quartz. All the raw materials are mixed and crushed to perform wet ball milling so as to obtain a glaze slip, and the glaze slip is subjected to iron removal, screening and aging for later use. According to the easy-cleaning ceramic glaze disclosed by the invention, various metal oxides are added in the formula of an easy-cleaning daily ceramic glaze to improve the easy-cleaning degree of the ceramic glaze and generate a synergistic action, the easy-cleaning degree and the glossiness of the obtained easy-cleaning ceramic glaze are much higher than those of the ceramic glaze in the past, and a glaze surface is smooth and nonstick to greasy dirt, so that the easy-cleaning ceramic glaze not only has significant self-cleaning capability and easy-cleaning property, but also has effective sterilizing, antibacterial, odor-removing and enzyme-preventing effects; and meanwhile, the obtained easy-cleaning ceramic glaze is leadless, green and safe.
Owner:GUANGDONG SHUNXIANG ENERGY SAVING LIGHTING TECH

VOCs catalyst for synergistic catalytic oxidation of ultraviolet-light self-excited ozone and preparation method and application thereof

The invention relates to a VOCs catalyst for synergistic catalytic oxidation of ultraviolet-light self-excited ozone and a preparation method and application thereof. Alkali-free wax-free glass fiberis taken and cooked with a nitric acid solution, then is washed with ionized water to be neutral, and is dried; tetrabutyl titanate is used as a precursor and is mixed with anhydrous ethanol to obtaina solution A; deionized water, zirconium oxychloride and acetic acid are dissolved in ethanol, and a solution B is obtained by stirring; the solution A is evenly stirred and then the solution B is added to get a light yellow precursor C; the glass fiber is soaked in the light yellow precursor C, drying is performed after impregnation, ageing is performed at room temperature, vacuum drying is executed in a vaccum drying oven, roasting is carried out in a muffle furnace, and natural cooling is executed to room temperature to obtain Zr-Ti supported glass fiber; a solution D is obtained by mixingthe manganese nitrate, ethanol, acetic acid and deionized water; the Zr-Ti supported glass fiber is impregnated in solution D, aged, dried and roasted to obtain the VOCs catalyst for synergistic catalytic oxidation of ultraviolet-light self-excited ozone.
Owner:NANJING UNIV OF TECH +1

Soil improvement material suitable for oxidative soil

The invention relates to a soil improvement material suitable for oxidative soil. A method comprises the following steps of: 1, sieving clay minerals through a screen of over 40 meshes for later use; 2, uniformly stirring biomass, the clay minerals and a catalyst to obtain a preprocessed biomass raw material; 3, collecting solid residue biological cokes as the raw material for preparing a soil structure conditioner from a discharge port on the tail part of a cracking unit; and 4, using the neutralized biological cokes as the structure conditioner of multiple kinds of oxidative soil. The invention has the advantages that: 1, the return utilization of the biological cokes which are modified reasonably is a main feasible approach of solving the problem that the biomass is excessively developed and utilized to possibly cause nutrient loss of the soil and cause balance destruction of soil organic matters; 2, the soil improvement material is particularly effective for structure improvement of the oxidative soil with obvious desilicication and aluminum enrichment trend, such as yellow soil, red soil, laterite and the like; and 3, due to the application of clay in biomass cracking, a tar substance, particularly condensed nuclear hydrocarbon is avoided.
Owner:NANCHANG UNIV

Metal oxide-loaded molecular sieve catalyst and preparation method thereof

A metal oxide-loaded molecular sieve catalyst comprises pure cryptomelane type manganese dioxide and transition metal. A method for preparing the molecular sieve catalyst comprises the following steps: 1, preparing solution of potassium permanganate; 2, preparing solution of manganese acetate; 3, adding the solution obtained by the step one into a three-neck flask, and heating, condensing and refluxing the solution; 4, adding the solution obtained by the step two into the three-neck flask of the step three, condensing and refluxing the solution, filtering and drying the obtained black pasty sediment, and roasting the sediment to obtain an octahedral manganese oxide molecular sieve catalyst (OMS-2) solid; 5, adding cerium ammonium nitrate, cobalt nitrate hexahydrate, copper nitrate trihydrate, ferric nitrate nonahydrate or yttrium nitrate into deionized water to form solution; and 6, mixing the solid taken from the step four and the solution in the step five, soaking cerium on the octahedral manganese oxide molecular sieve catalyst (OMS-2) solid, and drying and roasting the obtained solid to obtain the metal oxide-loaded molecular sieve catalyst. The metal oxide-loaded molecular sieve catalyst has the characteristics of high purification efficiency, low price and good thermal stability.
Owner:TSINGHUA UNIV

Device and method for degrading pesticide residues in traditional Chinese medicinal materials

InactiveCN103656957AImprove the effect of removing pesticide residues in Chinese herbal medicinesAggressiveChemical protectionPesticide residueHydroxyl radical
The invention discloses a device for degrading pesticide residues in traditional Chinese medicinal materials. The device comprises a cleaning water tank, a hydroxyl radical generator, an ultrasonic system and a photocatalyst. Meanwhile, the invention provides a method for degrading pesticide residues in traditional Chinese medicinal materials. The method comprises the steps of soaking; hydroxyl radical oxidation; ultrasonic cleaning and the like. The device can be used for safely and efficiently cleaning the traditional Chinese medicinal materials and has a favorable pesticide residue removal effect.
Owner:长沙安迪生物科技有限公司

CrXCo3-XO4 spinel type catalyst and preparation method thereof

The invention relates to a CrXCo3-XO4 spinel type catalyst for purifying tail gas of gas-fueled vehicles. An A site of a spinel AB2O4 structure comprises positive divalent cobalt elements, and a B site comprises chromium elements or chromium elements and positive divalent cobalt elements, wherein the molar ratio of the positive divalent cobalt elements to the sum of positive trivalent cobalt elements and the chromium elements to oxygen elements is 1:2:4. The preparation method of the CrXCo3-XO4 spinel type catalyst comprises the steps of: (1) respectively preparing a chromic nitrate solution and a cobalt nitrate solution with deionized water; (2) according to the proportion of the cobalt elements and the chromium elements, weighing the chromic nitrate solution and the cobalt nitrate solution which are prepared in the step (1), and uniformly mixing the two solutions by magnetic stirring; (3) adding an ammonia solution to regulate the pH value to obtain a suspension; and (4) carrying out vacuum filtration on the suspension obtained in the step (3), putting filter cakes in a drying box for drying, and then, transferring the filter cakes into a muffle furnace for roasting. The CrXCo3-XO4 spinel type catalyst has the characteristics of good heat stability, simple structure, low cost and wide application prospects.
Owner:TSINGHUA UNIV

Method for recovering vanadium, aluminum and molybdenum from waste catalyst

The invention provides a method for recovering vanadium, aluminum and molybdenum from a waste catalyst. According to the method, the oxidizing leaching of an alkaline solution is enhanced through an aeration process, and the solubility of oxygen, and the leaching rate of vanadium, aluminum and molybdenum are improved; and the reaction time is shortened, so that the reaction and energy consumptionof alkaline solution evaporation are reduced. Finally, leachate containing the vanadium, aluminum and molybdenum, and tailings enriched with other valuable elements can be obtained, and resource utilization of the waste catalyst is achieved.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI
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