The invention discloses a synthetic method of efficient
flame-retardant
epoxy vinyl ester resin. Biophenol A
diglycidyl ether, brominated
epoxy resin, a
polymerization inhibitor, a catalyst and an
antioxidant are sequentially added to a reaction kettle, the
reaction temperature slowly rises to 50 DEG C, chain extension binary acids / anhydrides are added in small quantities in batches, the mixture is heated to the temperature of 75-85 DEG C, the temperature is kept for 2 h, and the reaction
acid value is decreased to be lower than 2; (3) unsaturated monoacid is dropwise added to the reaction kettle at the dropping speed of 50 ml / h, the
reaction temperature change condition is observed, and
congelation caused by excessively fast temperature rises is avoided; after addition, the mixture is slowly heated to the temperature of 110-115 DEG C, and the temperature is kept for 4-5 h until the
acid value is decreased to be lower than 15; (4) the mixture is diluted with a crosslinking agent and fully stirred, then a
flame-retardant aid is added, after the material temperature is decreased to be lower than 45 DEG C, stirring is stopped, cooling water is turned off, and
package is performed. By means of the method, the best
flame-retardant effect can be realized and the flame-retardant requirement in certain special fields can be met.