Heat-resistant and ageing-resistant acrylonitrile-butadiene-styrene (ABS) resin with high tensile strength and preparation technology of resin

A technology of ABS resin and high tensile strength, applied in the field of resin, can solve the problems of slightly insufficient application of ABS resin, difficulty in maintaining rigidity and hardness, and achieve the effects of no shrinkage and warping, improved heat resistance, and prolonged service life.

Inactive Publication Date: 2014-10-01
ANHUI WANDONG CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, conventional ABS resin is limited by its own structure, and it is difficult to maintain its good rigidity and hardness when the temperature is higher than 100 ° C, which makes the application of ABS resin slightly insufficient.

Method used

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  • Heat-resistant and ageing-resistant acrylonitrile-butadiene-styrene (ABS) resin with high tensile strength and preparation technology of resin
  • Heat-resistant and ageing-resistant acrylonitrile-butadiene-styrene (ABS) resin with high tensile strength and preparation technology of resin
  • Heat-resistant and ageing-resistant acrylonitrile-butadiene-styrene (ABS) resin with high tensile strength and preparation technology of resin

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Effect test

Embodiment 1

[0021] The present invention also proposes a method for preparing heat-resistant and aging-resistant high-tensile-strength ABS resin according to the above ratio of materials, comprising the following steps: feeding ABS resin, polybutylene terephthalate, and silicone oil into a high-speed mixer Mix evenly, then add tetrabromobisphenol A, antioxidant 1010, light stabilizer 944, light shielding agent, zinc stearate, nano silicon dioxide, toughening modifier, polycarbonate resin and polyurethane resin After mixing for 20 minutes, send it to a twin-screw extruder for extrusion, wherein the speed of the twin-screw extruder is 270r / min, and the temperatures of the front, middle, rear and head of the barrel of the twin-screw extruder are respectively: 180°C , 210°C, 205°C, 210°C.

Embodiment 2

[0023] The present invention also proposes a method for preparing heat-resistant and aging-resistant high-tensile-strength ABS resin according to the above ratio of materials, comprising the following steps: feeding ABS resin, polybutylene terephthalate, and silicone oil into a high-speed mixer Mix evenly, then add tetrabromobisphenol A, antioxidant 1010, light stabilizer 791, light shielding agent, zinc stearate, nano silicon dioxide, toughening modifier, polycarbonate resin and polyurethane resin After mixing for 30 minutes, send it to a twin-screw extruder for extrusion, wherein the speed of the twin-screw extruder is 250r / min, and the temperatures of the front, middle, rear and head of the barrel of the twin-screw extruder are respectively: 200°C , 205°C, 215°C, 200°C.

Embodiment 3

[0025] The present invention also proposes a method for preparing heat-resistant and aging-resistant high-tensile-strength ABS resin according to the above ratio of materials, comprising the following steps: feeding ABS resin, polybutylene terephthalate, and silicone oil into a high-speed mixer Mix evenly, then add tetrabromobisphenol A, antioxidant 1010, light stabilizer 770, light stabilizer 3853, light shielding agent, zinc stearate, nano silicon dioxide, toughening modifier, polycarbonate Resin and polyurethane resin are mixed at high speed for 25 minutes and sent to the twin-screw extruder for extrusion. The twin-screw extruder speed is 265r / min, and the temperature They are: 190°C, 208°C, 213°C, 205°C.

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Abstract

The invention discloses heat-resistant and ageing-resistant acrylonitrile-butadiene-styrene (ABS) resin with high tensile strength. The ABS resin comprises the following raw materials in parts by weight: 50-60 parts of ABS resin, 15-30 parts of polybutylene terephthalate, 15-20 parts of silicone oil, 2-4.5 parts of polycarbonate resin, 6-8 parts of polyurethane resin, 0.5-1.5 parts of tetrabromobisphenol A, 1-1.2 parts of an antioxidant 1010, 0.5-0.8 part of a hindered amine light stabilizer, 0.2-0.75 part of a light screener, 0.5-1 part of zinc stearate, 0.5-3 parts of nanosilicon dioxide and 8-13 parts of a toughened modifier. The invention also discloses a preparation technology of the heat-resistant and ageing-resistant ABS resin with high tensile strength. The heat-resistant and ageing-resistant ABS resin with high tensile strength has excellent fire resistance, heat resistance, ageing resistance and weatherability, high tensile strength and good tenacity.

Description

technical field [0001] The invention relates to the technical field of resins, in particular to a heat-resistant and aging-resistant high tensile strength ABS resin and a preparation process thereof. Background technique [0002] Polycarbonates are resins that can maintain good mechanical properties at high temperatures, but their relatively high price limits their applications. Conventional ABS resin (acrylonitrile-butadiene-styrene terpolymer) has many advantages such as good impact resistance, processability, dimensional stability, wear resistance and chemical corrosion resistance, and its service temperature range can be It varies between -40 and 100°C, so ABS resin has been widely used in many fields such as automobiles, home appliances, daily necessities, sporting goods, and office supplies in recent years. However, conventional ABS resin is limited by its own structure, and it is difficult to maintain its good rigidity and hardness when the temperature is higher than...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L55/02C08L67/02C08L83/04C08L69/00C08L75/04C08L9/02C08L9/06C08K13/02C08K5/098C08K3/36C08K5/136
Inventor 姚能平梅德华王玉岚
Owner ANHUI WANDONG CHEM
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