The invention belongs to the technical field of chemical industries, in particular to a method for preparing a graphene-phthalocyanin nano composite material by a mercaptan-alkene clicking chemical method. The method comprises the following steps: introducing a plurality of carbon-carbon double-bond functional group by chemically modified graphite oxide; selecting proper sulfydryl phthalocyanin; and preparing the functional graphene-phthalocyanin nano composite material at one step by mercaptan-alkene clicking chemical reaction. The invention does not use a heavy metal ion as a catalyst, solves the problems of loose combination, easy falling, and the like of a traditional phthalocyanin macromolecule on the surface of the grapheme and has favorable environmental protection and advancement.The method has the advantages of simplicity, convenience, one-step completion, no catalyst addition, low cost, no pollution to environment, wide application prospect, and the like. The graphene-phthalocyanin nano composite material product has higher photosensitivity, compatibility and thermostability and favorable dissolubility, film forming performance and photoelectric performance, is a new generation high-performance organic-inorganic nano composite photoelectric function material and can be applied to the fields of conducting materials, solar energy cell materials, photoelectric conducting materials, photoelectric converting materials, and the like.