The invention discloses a preparation method of an
acrylic acid modified waterborne
polyurethane dispersion liquid used for metallic paint. The preparation method of the
acrylic acid modified waterborne
polyurethane dispersion liquid used for the metallic paint comprises the following steps: uniformly mixing
isophorone diisocyanate, polyether polylol and
polyester polylol, performing reaction under the catalytic action of
stannous octoate for 1-3 hours at the temperature of 80-95 DEG C, so as to obtain a
prepolymer; adding a micromolecule chain
extender and a
hydrophilic monomer into the
prepolymer, performing chain extension for 0.5-1 hour at the temperature of 80-85 DEG C, sealing residual end -NCO by utilizing hydroxyethyl
acrylate, then adding a neutralizing agent for
neutralization and salification, and adding water for emulsification, so that water-based dispersion liquid is obtained; adding an initiator, an emulsifier and other
acrylic acid monomers into the water-based dispersion liquid, and performing free
radical polymerization for 3-5 hours at the temperature of 85-100 DEG C, so that acrylic acid modified waterborne
polyurethane dispersion liquid is obtained. According to the preparation method of the acrylic acid modified waterborne
polyurethane dispersion liquid used for the metallic paint,
ammonium persulphate is used as the initiating agent, polyether
phosphate ester and alkylolamide surfactant are used as the emulsifier, completely successfully emulsified acrylic acid modified waterborne
polyurethane dispersion liquid can be prepared, and the obtained acrylic acid modified waterborne
polyurethane dispersion liquid has excellent
acid resistance, alkali resistance and salt
fog resistance and excellent
hardness and
mechanical property.