The invention discloses a method for extracting salt from coking desulphurization waste solution and a special device thereof. The method comprises the following steps of: heating
raw material waste solution for
decomposition, adsorbing and decolorizing, then heating, evaporating and concentrating to obtain concentrated solution, performing heat
filtration at constant temperature to remove fine
sulfur particles, cooling and crystallizing in a crystallizer, filtering at constant temperature, separating filtrate to obtain crystals, washing the crystals to obtain high-purity
ammonium thiocyanate, dissolving mixed salt crystals in
ammonium sulfate mother liquor, regulating the acidity to be below 20 percent, preheating to ensure that the temperature is between 90 and 110 DEG C, blowing air oroxygen, performing oxidative transformation for 1min to obtain
ammonium sulfate transformation liquid, and adding
ammonium sulfate production
mother liquor to obtain an
ammonium sulfate product. By the method, a high-purity product can be extracted from the waste solution through one-time operation, so that
processing and treatment times are reduced;
solid-phase impurities are effectively intercepted and prevented from transferring to the crystals at constant temperature; and the mixed salt is subjected to oxidative transformation treatment, all
ammonium thiosulfate is transformed into the
ammonium sulfate product with
high nitrogen content, the process is simple, operation cost is low, and product marketing is broad.