The invention belongs to the technical field of building materials, in particular to waterproof cement slurry resistant to chemical harmful erosion. The waterproof cement slurry comprises the following raw materials: cement, hydroxy-terminated lactic acid oligomer with a molecular weight of 800-2000, a surface-active substance, a composite filler, glycollic acid, nickel sulfate hexahydrate, starchsodium octenylsuccinates, terpenyl epoxy resin and acrylate emulsion. Compared with the prior art, the waterproof cement slurry disclosed by the invention has the advantages that a powdered flexiblewaterproofing material made from multiple active chemicals is doped into cement, wherein ephedra fiber powder can contribute to improving the flexibility of the cement slurry and effectively improvingthe penetrating function and chemical harmful erosion, and the waterproof cement slurry has ultra-strong penetration capacity and excellent impervious performance, and is high in harmful chemical erosion resistance, capable of automatically and rapidly repairing micro-cracks, safe, environment friendly and excellent in waterproof performance.