The invention provides a
pyrolysis gasoline nickel system selective hydrogenation catalyst and a preparation method of the
pyrolysis gasoline nickel system selective hydrogenation catalyst and belongs to a catalyst containing
metal or
metal oxide or
hydroxide. The
pyrolysis gasoline nickel system selective hydrogenation catalyst is characterized by being provided with a mesopore-
macropore or double-mesopore compound pore channel, taking aluminum
oxide as a carrier, taking nickel as a main
active component, taking
molybdenum as an auxiliary
active component and taking the
metal oxide as an auxiliary agent; the
pyrolysis gasoline nickel system selective hydrogenation catalyst is composed of following components in parts by weight: 15-19 parts of
nickel oxide, 6.5-20 parts of
molybdenum oxide, 2.2-4.5 parts of the auxiliary agent and the balance of the aluminum oxide; the auxiliary agent is one or the combination of more than two of
potassium oxide,
magnesium oxide and
lanthanum oxide. The invention provides the
pyrolysis gasoline nickel system selective hydrogenation catalyst which is large in pore capacity and high in specific surface, has good reaction activity, high
hydrogenation reaction selectivity, good stability, good
arsenic dissolving and glue resisting capabilities and is provided with the compound pore channel, and the preparation method of the
pyrolysis gasoline nickel system selective hydrogenation catalyst. When the catalyst is used for selectively hydrogenating full-fraction pyrolysis gasoline, the average
diene hydrogenation rate is 99%.