The invention provides a hot dipping plating assistant agent containing a fluoro-carbon surfactant, which belongs to the technical field of surface plating process of steel materials. A compounded fluoro-carbon surfactant is added in plating assistant agents which take
zinc chloride, or
zinc chloride and
ammonium chloride as the main part, to improve the
coating effect of the plating assistant agent and the
wetting property of the plating assistant agent which contacts with
zinc-based
molten metal. The method comprises the steps: nonionic N-propyl, N-ethoxyl perfluorooctylsulfonyl
amide and cationic perfluorooctanosulfonyl
quaternary iodide are mixed to form a compounded fluoro-carbon surfactant, and then the compounded fluoro-carbon surfactant is blended with water solution which takes zinc chloride, or zinc chloride and
ammonium chloride as the main part to form the hot dipping plating assistant agent containing the fluoro-carbon surfactant. The addition level of the compounded fluoro-carbon surfactant in the hot dipping plating assistant agent containing the fluoro-carbon surfactant is 0.1 to 10 g / L, wherein the
mass fraction of the perfluorooctanosulfonyl
fluoride quaternary iodide accounts for 5 to 90 percent, and the rest are N-propyl and N-ethoxyl perfluorooctylsulfonyl
amide. The
operation temperature and the plating assistant
drying temperature are equal with that during the plating assistant process of the traditional zinc chloride and zinc
chloride salt system plating assistant agent. The hot dipping plating assistant agent has the advantages that the preparation operation of the plating assistant agent is simple, the
wetting effect of the surface of a steel finished piece in zinc liquid is good after plating, the uniformity of the plating layer can be improved, the plating leakage ratio is reduced, and the use level of the
chlorine salt in the plating assistant agent can be also reduced.