The invention relates to a recycling method for waste CO
sulfur-tolerant shift catalysts. The recycling method comprises the following steps: crushing the waste CO
sulfur-tolerant shift catalysts, milling the crushed waste CO
sulfur-tolerant shift catalysts, Fe(OH)3 and Cr(OH)3 together for 1-2 hours to be made into particles through a 8-mesh screen cloth,
roasting the particles for 6-8 hours at the low temperature of 250-300 DEG C, cooling the roasted particles, and then tabletting and shaping the cooled particles to obtain CO high-temperature shift catalysts. Through detection according to the national
chemical industry standard HG / T 3546-2011, all the performance indexes are much higher than quality technology requirements of B116 type CO high-temperature shift catalysts which are sold in the market. Through the adoption of the recycling method, the
resource utilization rate of the waste CO sulfur-tolerant shift catalysts reaches 100%, sulfur in waste catalysts does not need to be removed, SO2
waste gas, NO
waste gas and NO2
waste gas are not generated in the whole
recovery process, and waste liquid and waste residues are not generated, so that the purposes of zero secondary
pollution and zero new 'three wastes' are really realized, and not only are
molybdenum sources saved, but also the recycling method is environmental-friendly.