The invention discloses a high-conductivity film phase change material for a thermal battery in the technical field of thermal batteries. Raw materials comprise: a soluble inorganic salt, a conductiveagent and an adhesive, wherein the soluble inorganic salt comprises at least two of NaCl, Na2SO4, Na2CO3, KCl, K2SO4, K2CO3, LiCl, Li2SO4, Li2CO3, MgCl2 and MgSO4, and the conductive agent comprisesone of expanded graphite, carbon nanotubes, graphene and activated carbon. The preparation method comprises the following steps: dissolving the easily soluble inorganic salt in water by using the principle that the easily soluble inorganic salt is soluble in water, fully stirring and mixing the components, mixing the conductive agent and the soluble inorganic salt together by using the adhesive toform slurry, and coating the slurry to form the thin film phase change material. Firstly, phase change is utilized to slow down thermal shock and prolong the working time of the electrolyte; secondly, the conductive agent plays a conductive role, electrons can be transmitted through the high-conductivity thin film phase change material, and then the service life of the thermal battery is prolonged.