Patents
Literature
Hiro is an intelligent assistant for R&D personnel, combined with Patent DNA, to facilitate innovative research.
Hiro

84results about How to "Increased electron transport capacity" patented technology

Nitrogen-sulfur double-doped mesoporous carbon electrode material as well as preparation method and application thereof

InactiveCN104445144AChange the local current densityIncreased electron transport capacityHybrid/EDL manufactureSolventCalcination
The invention discloses a nitrogen-sulfur double-doped mesoporous carbon electrode material as well as a preparation method and application thereof. A precursor of the electrode material comprises the following components in percentage by mass: 20%-85% of a template agent, 10%-75% of a nitrogen-containing compound and 5%-50% of a transition metal salt. The preparation method comprises the following steps: dissolving the template agent, the nitrogen-containing compound and the transition metal salt in a solvent, so as to obtain the precursor; carrying out calcination reduction on the precursor to obtain a primary carbonized material; carrying out acid pickling on the primary carbonized material to obtain a nitrogen-containing mesoporous carbon material; carrying out acid pickling and calcination reduction again, so as to obtain the nitrogen-sulfur double-doped mesoporous carbon electrode material. The application of the nitrogen-sulfur double-doped mesoporous carbon electrode material in a supercapacitor comprises the following steps: transferring a mixed solution of the electrode material, acetylene black, a binder and a dispersant to a glassy carbon electrode; carrying out three-electrode system testing in electrolyte solutions of different concentrations by virtue of an electrochemical workstation. The nitrogen-sulfur double-doped mesoporous carbon electrode material is of a hierarchical pore structure, has a high specific surface area and is an excellent supercapacitor material.
Owner:DONGHUA UNIV +1

High-nickel positive electrode material with composite coating layer and preparation method thereof

The invention discloses a high-nickel positive electrode material with a composite coating layer and a preparation method thereof. The preparation method comprises the following steps: (1) uniformly mixing a high-nickel positive electrode material and a nano-coating material, and carrying out high-temperature sintering, cooling, crushing and sieving in a preheated muffle furnace under an oxygen atmosphere to obtain a nano-material-coated high-nickel positive electrode material; and (2) adding the high-nickel positive electrode material coated with the nano material into deionized water dissolved with a soluble lithium compound, uniformly stirring, slowly adding soluble phosphate, uniformly stirring, carrying out vacuum filtration, drying and re-burning in a kiln, cooling, crushing and sieving to obtain the high-nickel positive electrode material with the composite coating layer. According to the high-nickel positive electrode material with a composite coating layer and the preparationmethod thereof, multi-layer uniform coating of the nano material and phosphate is realized through dry-process and wet-process coating, and the prepared positive electrode material has the advantagesof good cycle performance, good thermal stability and the like, and the preparation process is simple, and the positive electrode material can be used for industrial mass production and has a wide application prospect in lithium ion battery production.
Owner:NINGBO RONBAY LITHIUM BATTERY MATERIAL CO LTD

Graphite composite anode material and preparation method thereof

The invention relates to a graphite composite anode material and a preparation method thereof. The graphite composite anode material is of a core-shell structure and comprises an inner core and an outer shell, wherein the inner core is graphite; the outer shell is a nitrogen and phosphorus-doped composite material layer; the nitrogen and phosphorus-doped composite material layer is formed by adding the graphite serving as a raw material into nitrogen-containing ionic liquid in which a phosphorus-containing organic compound, a surfactant and lithium salt are dispersed and sintering; the mass ratio of the phosphorus-containing organic compound to the surfactant to the lithium salt to the nitrogen-containing ionic liquid is (10-50):(1-5):(1-5):200. The graphite composite anode material provided by the invention has the advantages that the transmission rate of lithium ions under the condition of high magnification can be improved, and the compatibility of the graphite composite anode material with an electrolyte can also be improved, so that the cycle performance is improved; the lithium salt in the outer shell can provide sufficient lithium ions, so that the first-time efficiency and the cycle performance are improved.
Owner:陕西君和聚源科技有限公司

Modified silica nanoporous membrane modified electrode, preparation method and application thereof

The invention discloses a modified silica nanoporous membrane modified electrode, a preparation method and an application thereof, and belongs to the technical field of novel materials. The preparation method comprises the following steps of: (1) preparing a silica nanoporous membrane having an open pore structure on an electrode substrate; and (2) inserting graphene quantum dots into pores to modify the silica nanopores to prepare the modified silica nanoporous membrane modified electrode by using a electrophoresis method, an electrostatic adsorption method, or a covalent immobilization method. The modified electrode, the preparation method and the application thereof insert small-sized GQDs as a functional block into pores to modify a VMSF electrode to prepare a variety of sensing interfaces. The electrode can realize a pre-enrichment effect on an object to be detected due to the electronegativity of the pores, and the coordination effect on metal ions and the pi-pi stacking action on the dopamine of the graphene quantum dots, so that the detection property of the object to be detected is remarkably improved. The great application prospects are achieved in direct and high-sensitivity electrochemical detection of multiple types of active compositions in complex samples combined with the anti-staining / anti-interference ability of the VMSF.
Owner:东营正诺技术服务有限公司

Organic el device

The object of the present invention is to provide an organic EL device having a structure that resolves a problem of trade-off between decrease in a drive voltage and increase in production yield. The organic EL device of the present invention includes a substrate, a pair of electrodes provided on the substrate, and an organic EL layer sandwiched by the pair of electrodes; the pair of electrodes includes a positive electrode and a negative electrode; the organic EL layer includes at least a light-emitting layer and a hole injection layer that is in contact with the positive electrode; the hole injection layer is formed of an n-type semiconductor host material and a p-type semiconductor guest material; a LUMO level EHIC of the host material and a HOMO level of the guest material or a valence band level EGV satisfy:|EHIC|+0.5 eV≧|EGV|>IHIC|−0.6 eV.
Owner:SHARP KK

Screen-printed electrode based on graphene conductive ink and processing method thereof

ActiveCN105353009ALarge specific surface areaImprove electron transfer performanceMaterial electrochemical variablesIonGraphene
The invention belongs to the field of heavy metal detection sensor, and especially relates to a screen-printed electrode based on graphene conductive ink and a processing method thereof. The screen-printed electrode comprises a substrate, and a working electrode, a counter electrode, and a conductive lead wire are printed on the substrate. The working electrode electrically communicates with the conductive lead wire by a lead wire, and the counter electrode electrically communicates with the conductive lead wire by the lead wire. The materials of the working electrode, the counter electrode, and the conductive lead wire are graphene conductive ink. The screen-printed electrode uses graphene which has large specific surface area and high electrocatalytic and electrochemical activities as the materials of the working electrode, the counter electrode, the conductive lead wire, and the lead wire, so that the electron transfer performance of the molecule or ion to be detected in an electrode reaction interface is improved. Moreover, the screen-printed electrode prepared form graphene conductive ink is beneficial to the adsorption of the heavy metal ion and the modification of the surface functionalization.
Owner:QINGDAO REALEADER ADVANCED MATERIALS TECH

Preparation method of molecularly imprinted sensor based on carbon quantum dot/hollow nickel base material composite film modified glassy carbon electrode and application thereof

The invention belongs to the technical field of preparation of electrochemical sensors, and relates to a preparation method of a molecularly imprinted sensor based on a carbon quantum dot / a hollow nickel base material composite film modified glassy carbon electrode. The preparation method comprises the following steps of firstly depositing a Ni-Cu alloy layer in a three-electrode system, and thendealloying and removing copper to obtain a nano hollow nickel sphere layer; preparing an environment-friendly carbon quantum dot solution by adopting a biomass material, and modifying a glassy carbonelectrode coated with a nano hollow nickel sphere by using a composite solution of the carbon quantum dot and chitosan; and taking 3-aminophenylboronic acid as a functional monomer, and preparing themolecular imprinted sensor which has specific recognition response to the template molecular glucose on the surface of the glassy carbon electrode modified by a composite film through an electrochemical polymerization method. The preparation method of the molecularly imprinted sensor based on the carbon quantum dot / the hollow nickel base material composite film modified glassy carbon electrode provided by the invention effectively improves the active area and the electron transport performance. Combined with the molecular imprinting technology, the molecularly imprinted sensor with specific recognition response to glucose is prepared, and the molecularly imprinted sensor has the advantages of being simple in operation, low in cost, high in selectivity and sensitivity, and is expected to bepractical.
Owner:JIANGSU UNIV

Energy-saving catalyst for phenylethylene dehydrogenation

The present invention relates to an energy saving ethylbenzene dehydrogenation catalyst mainly solves the problems that the low-kalium catalyst in the prior art has poor activity under a low temperature condition. The invention adopts a technical proposal of inducing tellurium dioxide into a Fe-K-Ce-W-Mg system and the reaction temperature of the obtained catalyst is lower than the same catalyst by 5 to 10 DEG C. The present invention can be used for the industrial production of styrene by ethylbenzene dehydrogenation.
Owner:CHINA PETROLEUM & CHEM CORP +1

Method for preparing active conducting polymer hydrogel with oxidoreduction function

A method for preparing active conducting polymer hydrogel with an oxidoreduction function is characterized by comprising the first step of dissolving active compounds with an oxidoreduction performance in water, and stirring and carrying out ultrasonic process to form solution with the concentration of 1-20mmol / L, wherein the solution is reserved, the second step of dissolving polystyrolsulfon acid in the water, stirring and carrying out the ultrasonic process to form dispersion liquid, mixing the dispersion liquid with the solution obtained in the first step, stirring and carrying out the ultrasonic process continuously to form dispersion liquid, the third step of adding conducting polymer monomer 3,4-aethylenum dioxo thiophene into the dispersion liquid obtained in the second step, stirring and carrying out the ultrasonic process to form a reaction system, the fourth step of dissolving an oxidizing agent in the water to form aqueous solution, adding the aqueous solution to the reaction system obtained in the third step at a time, mixing the reaction system and the aqueous solution evenly, standing the reaction system and the aqueous solution, reacting for 4-24 hours, purifying and balancing a product in distilled water for 2-6 days, freezing and drying the product, and the active conducting polymer hydrogel with the oxidoreduction function is obtained. Compared with pure conducting polymer hydrogel, the active conducting polymer hydrogel with the oxidoreduction function has higher specific capacitance and cycling stability.
Owner:HOHAI UNIV

Preparation method of graphene/carbon nano tube co-reinforced conducting polymer hydrogel

The invention relates to a preparation method of graphene / carbon nano tube co-reinforced conducting polymer hydrogel. The method comprises the following steps that: (1) carbon nano tubes are added into a polystyrene sulfonate and graphene oxide aqueous solution, and the mixture of the carbon nano tubes and the polystyrene sulfonate and graphene oxide aqueous solution are stirred; (2) a conducting polymer monomer is added into the solution obtained in the step (1), and the mixture of the conducting polymer monomer and the solution is stirred, and the concentration of the conducting polymer monomer ranges from 0.05 to 0.5mol / L; (3) an oxidant solution is added into the reaction system obtained in step (2), and the mixture of the oxidant solution and the reaction system is stirred, and ratio of the conducting polymer to the oxidant ranges from 1:3 to 1:30; (4) the mixture of the oxidant solution and the reaction system stands and reacts, and a product obtained in the step (3) is purified and balanced in distilled water, so that the graphene / carbon nano tube co-reinforced conducting polymer hydrogel can be obtained; and (5) the hydrogel obtained in the step (4) is soaked in hydriodic acid, so that the graphene / carbon nano tube co-reinforced conducting polymer hydrogel can be obtained. Compared with a pure conducting polymer hydrogel, the graphene / carbon nano tube co-reinforced conducting polymer hydrogel has high conductivity and super capacitance performance.
Owner:SHANDONG UNIV OF SCI & TECH

Preparation method of electrochemical nonyl phenol sensor on basis of doped titanium dioxide/molybdenum disulfide composite material

The invention discloses a preparation method of an electrochemical biosensor. According to the method, a novel two-dimensional manometer electrode material-doped titanium dioxide / molybdenum disulfide composite material Cu-TiO2 / MoS2 is firstly prepared, and the material is a copper-doped titanium dioxide manometer square in-situ composite molybdenum disulfide two-dimensional manometer composite material; good biocompatibility and large specific surface areas of the material are utilized; a nonyl phenol antibody is loaded; during detection, copper-doped titanium dioxide can catalyze hydrogen peroxide to generate O2 in situ; an electrochemical signal is generated; the influence of the specificity quantitative combination of the antibody and an antigen on the electronic transmission capability is utilized, so that the current intensity is correspondingly reduced; the building of a biosensor for detecting nonyl phenol by an unmarked electrochemical method is finally realized.
Owner:UNIV OF JINAN

Method for preparing titanium oxide coated sulfur-doped carbon nanotube lithium-sulfur battery cathode material

The invention belongs to the field of electrode materials and in particular to a method for preparing a titanium oxide coated sulfur-doped carbon nanotube lithium-sulfur battery cathode material. Themethod comprises firstly adding a carbon nanotube into deionized water, performing a dispersing process, adding a sodium sulfide solution, adding a resultant solution to a reaction kettle, performinga thermostatic reaction, centrifugal separation, washing, and vacuum drying to obtain a sulfur-doped carbon nanotube; and finally, adding a solution A composed of concentrated ammonia water, tetraethyl titanate, and a organic solvent to the sulfur-doped carbon nanotube dispersion liquid, performing constant-temperature stirring, centrifugal separation, washing, vacuum drying and calcination to obtain the titanium dioxide coated sulfur-doped carbon nanotube. The method for preparing the titanium dioxide coated sulfur-doped carbon nanotube is easy to operate and low in economic cost and can realize large-scale production. The prepared titanium dioxide coated sulfur-doped carbon nanotube has large specific surface area, high electron transport capacity and first charge and discharge capacity,and excellent cycle performance.
Owner:DONGGUAN UNIV OF TECH

High-cycle nickel-cobalt-manganese ternary material and preparation method thereof

InactiveCN106848255AImprove lattice structure stabilityImprove cycle performanceCell electrodesSecondary cellsPolymer scienceManganese
The invention belongs to the field of preparation of lithium-ion battery materials and particularly relates to high-cycle nickel-cobalt-manganese ternary material and a preparation method thereof; the high-cycle nickel-cobalt-manganese ternary material is mainly characterized in that the cycle performance of the material is improved by coating nickel-cobalt-manganese ternary material with a layer of nitrogen-phosphorus-containing compound to improve the compatibility of the material with electrolyte. The preparation method comprises: adding a nitrogen-phosphorus-containing polymer and a binder to 1-methyl-2-pyrrolidinone, stirring well, adding ternary material, stirring well, carbonizing, and soaking in ethylene carbonate solution to obtain the nickel-cobalt-manganese ternary material with nitrogen-phosphorus coating. The material prepared herein has surface charge distribution that is improved by means of nitrogen doping in the nitrogen-phosphorus compound, electron transfer performance is improved, quasi-Faraday effect is achieved, and capacity is given to better play; in addition, lattice structural stability of the material and the compatibility of the material with electrolyte are improved by the aid of phosphorus doping; the ethylene carbonate adsorbed by the material can provide improved compatibility of the material with electrolyte, the synergy of the doped nitrogen-phosphorus and the ethylene carbonate can be given to play, and the cycle performance of the material is improved.
Owner:江苏元景锂粉工业有限公司

Preparation method of CNTs/Ni-Fe3O4 functional material

The invention relates to a preparation method of a CNTs / NiFe3O4 functional material, and belongs to the technical field of functional nano composite materials and environmental biology. The preparation method of the CNTs / NiFe3O4 functional material comprises the following specific steps: purifying and activating multiwalled carbon nanotubes; preparing CNTsFe3O4: preparing the CNTs / NiFe3O4 nano composite material. The CNTs / NiFe3O4 functional material prepared by the invention is used as an efficient biological catalytic material and a wave-absorbing material, has the characteristics of promoting oxidation-reduction reaction and electron transfer, is used as a stabilizer and a catalyst in sewage treatment anaerobic digestion reaction, can improve the methane yield and produce biomass energy,can play a role once being added, and has a good application prospect. The catalyst is good in dispersity in a reactor and uniform and consistent in reaction, and can be recycled to save the cost.
Owner:KUNMING UNIV OF SCI & TECH

Embedded nano iron/composite microbial agent and preparation method thereof

ActiveCN106754855AGuaranteed activity and stabilityWide variety of sourcesBacteriaWater contaminantsChemistryAluminium salts
The invention relates to an embedded nano iron / composite microbial agent and a preparation method thereof. The preparation method comprises the steps of firstly using agrobacterium tumefaeiens, enterobacter cloacae, bacillus, gordonia, pseudomonas putida and pseudomonas stutzeri to prepare a nano iron solution B, preparing embedding medium agar, PVA (Polyvinyl Alcohol) and a SiO2 solution C, and preparing a cross-linking agent aluminum sulfate saturated boric acid solution D; according to volume ratio, respectively taking and adding 15-18% of a solution B and 6-15% of thallus A into 57-66% of the solution C, stirring and mixing evenly, dropwise adding the mixture into 1-22% of a solution D at room temperature in a nitrogen protected environment, carrying out crosslinking treatment, rinsing and preserving to obtain the nano iron / composite microbial agent. The embedded nano iron / composite microbial agent takes advantage of a synergistic effect between the nano iron and microorganisms to improve the degradation efficiency of triclosan; and the microbial agent prepared is high in strength, small in microbial toxicity and low in raw material source cost, and can be used for treatment of a water body polluted by triclosan.
Owner:SOUTH CHINA UNIV OF TECH

Method for producing acetic acid by utilizing self-assembly conductive biological membrane electrode to reduce carbon dioxide

The invention discloses a method for producing acetic acid by utilizing a self-assembly conductive biological membrane electrode to reduce carbon dioxide. The method comprises the following steps: (1) adding an inhibitor chloromethane into an inoculum, continuously performing biological acclimatization under H2 / CO2 atmosphere and continuously shortening the turning time, thereby acquiring the acclimatized self-oxidation microorganism; and (2) taking a carbon felt as an electrode, inoculating the self-oxidation microorganism acquired in the step (1) and the culture medium suitable for microbial growth in the carbon felt, reacting for 5-7 days under H2 / CO2 atmosphere, replacing by a new culture medium, reacting for 3-5 days under the same atmosphere, thereby acquiring the conductive biological membrane electrode, and then generating acetic acid by using the conductive biological membrane electrode for performing bioelectrochemical reduction on carbon dioxide. The biological membrane electrode disclosed by the invention is simple in preparation process, is high in catalytic efficiency and is capable of effectively increasing the electron transfer rate of a biological cathode, so that the efficiency of generating acetic acid through the bioelectrochemical reduction of carbon dioxide can be increased.
Owner:NANJING UNIV OF TECH

Method for removing heavy metals in pig manure by using biochar enhanced indigenous ferrous oxide bacteria

The invention discloses a method for removing heavy metals in pig manure by using biochar enhanced indigenous ferrous oxide bacteria; the method can be used for removing heavy metals in the pig manureand other livestock and poultry manure by using the biochar enhanced indigenous ferrous oxide bacteria. Biochar is prepared by carrying out anoxic calcination on wheat straw at 500 DEG C. The methodcomprises the steps of adding the pig manure to be treated into a bioreactor, respectively inoculating 10-15% of indigenous ferrous oxide bacteria and 5-10g / L of biochar, and carrying out aeration treatment for 4-7 days at 30+ / 2 DEG C; pumping out the treated pig manure, dehydrating the pig manure, adjusting the pH of a liquid phase part to precipitate the heavy metals, and neutralizing a solid phase part so as to realize the agricultural utilization of the pig manure. The removal rate of the heavy metals in the pig manure reaches up to 90-98%, and the nutrient loss in the pig manure is reduced by 10% or above. The method is simple and convenient to operate, economically feasible and safe, and is an efficient method for removing the heavy metals in the pig manure.
Owner:NANKAI UNIV

Preparation method of nitrogen-doped nanocellulose/carbon nanofiber composite

The invention relates to a preparation method of a nitrogen-doped nanocellulose / carbon nanofiber composite and belongs to the field of nanocomposites. According to the preparation method, a coconut petiole structure is destroyed by steam explosion treatment, and hemicellulose, lignin and the like are hydrolyzed; then, impurities are removed by dissolving to prepare coconut petiole nanocellulose with high strength, high elasticity modulus and good light transparency; next, a great number of nitrogen-doped carbon nanotubes with relatively uniform shapes and sizes are produced by gaseous-phase detonation according to the characteristic that the radius of a nitrogen atom is close to that of a carbon atom and the nitrogen atom easily enters a carbon nanotube lattice to form a C-N bond, the local charge density of the carbon nanotubes is changed by virtue of nitrogen doping, the electron transfer property of the carbon nanotubes is improved, the resistance coefficient is reduced, and a nitrogen-containing functional group introduced by nitrogen doping can bring a quasi faraday effect, so that the specific capacity of a carbon nanotube supercapacitor is effectively improved, and the nanocomposite with high strength and good conductivity is prepared. The nitrogen-doped nanocellulose / carbon nanofiber composite can be applied to the fields such as lithium ion batteries and supercapacitors.
Owner:陈毅忠

Nitrogen-doped carbon nanotube/rare earth metal ion-doped lithium iron phosphate composite cathode material and preparation method thereof

The invention discloses a nitrogen-doped carbon nanotube / rare earth metal ion-doped lithium iron phosphate composite positive electrode material and a preparation method thereof, and is applied to the field of lithium ion batteries. The preparation method of the material comprises the following steps: mixing hydrazine hydrate and carbon nanotubes, and then carrying out reflux, suction filtration and freeze drying to prepare nitrogen-doped carbon nanotubes; preparing rare earth metal ion doped lithium iron phosphate by taking lithium hydroxide, ferric phosphate, oxalic acid, glucose and rare earth metal oxide as raw materials; and finally, adding the nitrogen-doped carbon nanotube and the rare earth metal ion-doped lithium iron phosphate into dispersion liquid for dispersion, and performing ball milling to obtain a final product. Compared with the traditional lithium iron phosphate, the nitrogen-doped carbon nanotube / rare earth metal ion-doped lithium iron phosphate composite positive electrode material prepared by the method has excellent rate charge-discharge performance.
Owner:HEFEI GUOXUAN HIGH TECH POWER ENERGY CO LTD CO LTD

Surface molecular imprinting SERS (Surface Enhanced Raman Scattering) sensor based on core-shell structure polydopamine coated gold nanoparticles as well as preparation and application of surface molecular imprinting SERS sensor

The invention relates to a surface molecular imprinting SERS (Surface Enhanced Raman Scattering) sensor based on core-shell structure polydopamine coated gold nanoparticles as well as preparation andapplication of the surface molecular imprinting SERS sensor. A preparation method comprises the following steps: by taking dopamine as a functional monomer and a phthalate substance as a template molecule, carrying out self-polymerization on the surfaces of gold nanoparticles to obtain a molecularly imprinted polymer, eluting the molecularly imprinted polymer, and dropwise coating the surface of ascreen-printed electrode with the molecularly imprinted polymer to obtain the surface molecularly imprinted SERS sensor. Compared with the prior art, the invention is combined with a Raman spectrometer, by combining electrochemical enrichment and molecular imprinting technologies, high-selectivity and high-sensitivity detection of phthalate substances in a water body in a complex environment canbe realized at the same time, and the sensor has the advantages of simple preparation process, high detection speed, no need of sample pretreatment, environmental friendliness, low cost and the like,and shows a wide application prospect.
Owner:SHANGHAI INST OF TECH

Low steam-to-oil ratio ethylbenzene dehydrogenation catalyst

The invention relates to a low steam-to-oil ratio ethylbeneze dehydrogenation catalyst and a preparing method thereof. The low steam-to-oil ethylbeneze dehydronation catalyst mainly solves the problems that in the prior art, a low-potassium catalyst has poor stability and low activity under the condition of a low steam-to-oil ratio. According to the technical scheme, the low steam-to-oil ratio ethylbeneze dehydrogenation catalyst is prepared from, by weight, 66-79% of Fe2O3, 4-9% of K2O, 6-11% of CeO2, 1-5% of WO3, 0.5-5% of BaO, 0.5-8% of Nb2O5 and 0.5-5% of middle rare earth oxide, wherein the middle rare earth oxide is selected from at least one of Eu2O3, Tb2O3 and Ho2O3, the problems in the prior art are favorably solved, and the low steam-to-oil ratio ethylbenzene dehydrogenation catalyst can be used in industrial production of using ethylbenzene dehydrogenation to prepare styrene under the condition of the low steam-to-oil ratio.
Owner:CHINA PETROLEUM & CHEM CORP +1

Low water ratio ethylbenzene dehydrogenation catalyst

The present invention relates to a low water ratio ethylbenzene dehydrogenation catalyst and a preparation method thereof. A purpose of the present invention is mainly to solve the problems of poor stability and low activity of the low potassium catalyst under the low water ratio condition in the prior art. According to the present invention, the low water ratio ethylbenzene dehydrogenation catalyst comprises, by weight, 66-79% of Fe2O3, 4-9% of K2O, 6-11% of CeO2, 1-5% of WO3, 0.5-5% of BaO, 0.5-8% of ZrO2, and 0.5-5% of a medium rare earth oxide, wherein the medium rare earth oxide is at least one selected from Dy2O3, Tb2O3 and Ho2O3; with the technical scheme, the problems in the prior art are well solved; and the dehydrogenation catalyst can be used for the styrene preparation under the low water ratio condition through the ethylbenzene dehydrogenation in the industrial production.
Owner:CHINA PETROLEUM & CHEM CORP +1

Pomelo peel porous carbon material and preparation methodand application thereof

The invention discloses a pomelo peel porous carbon material and a preparation method and application thereof, and relates to electrode materials. The carbon material contains a certain amount of nitrogen elements, the hydrophilicity of an electrode material can be improved, thus the electrode material can form a double-electric-layer capacitance with a water electrolyte well, and the specific capacitance of the electrode material is improved. The preparation method of the carbon material comprises the following steps that (1) pomelo peel is placed in a tube furnace, nitrogen is firstly introduced for 20-40 min, then temperature is raised to 440-460 DEG C at the rate of 1-3 DEG C / min, and cooling is conducted naturally after carbonizing for 1-3 h to obtain carbonized pomelo peel; (2) afterthe carbonized pomelo peel is mixed with KOH according to the mass ratio of 1:(1-4), grinding is conducted, a mixture is placed into the tube furnace, the nitrogen is introduced for 20-40 min, the temperature is raised to 790-810 DEG C at the rate of 1-3 DEG C / min, and cooling is conducted naturally after activating for 1-3 h to obtain activated pomelo peel; and (3) the pH of the activated pomelopeel is adjusted to 10, decompressing, filtering and washing are conducted after centrifuging, and the activated pomelo peel is placed into a blast drying box for drying to obtain the pomelo peel porous carbon material.
Owner:SOUTH CHINA NORMAL UNIVERSITY

Planting method for improving growth and development and fruit quality of tomatoes

The invention discloses a planting method for improving growth and development and fruit quality of tomatoes. The planting method comprises the steps that tomato seedlings are cultivated; LED plant growth lamps are adopted as light sources to be arranged above the tomato seedlings for irradiation, and the light period every day is set to be 12 h illumination / 12 h non-illumination or 16 h illumination / 8 h non-illumination; when the tomatoes enter the flowering stage, an EDTA-Fe aqueous solution with the concentration of 100-200 [mu] mol.L <-1 > is sprayed to tomato plants, the EDTA-Fe aqueous solution is uniformly sprayed to the front and back surfaces of leaves once a week, and the tomato plants are irrigated with a nutrient solution containing no Fe element once every other month to ensure sufficient nutrients; and after the EDTA-Fe aqueous solution is sprayed for 55-65 days, when 80% of the tomatoes on the tomato plants turn red and peels are slightly soft, spraying of the EDTA-Fe aqueous solution is stopped. According to the planting method for improving growth and development and fruit quality of the tomatoes, the tomato quality improvement effect is optimal by spraying 100 to 150 [mu] mol.L <-1 > EDTA-Fe aqueous solution on the surfaces of the leaves in the photoperiod of 16 h illumination / 8 h non-illumination.
Owner:SHANXI AGRI UNIV +1

Selenium and nitrogen co-doped biochar catalytic material as well as preparation method and application thereof

The invention discloses a selenium and nitrogen co-doped biochar catalytic material as well as a preparation method and application thereof. High-toxicity selenite is reduced into low-toxicity biological nano-selenium under the biological detoxification action of bacteria (Bacillus megaterium B10 with the preservation number of CGMCC No.15753), then selenium-enriched thalli serve as a carbon source of biochar, a nitrogen source is added, and the novel selenium and nitrogen co-doped biochar catalytic material is prepared with a simple one-step carbonization method. The preparation method of theselenium and nitrogen co-doped biochar provided by the invention is simple, convenient, safe, cheap and easy to control, and can be used for large-scale production. Meanwhile, the reduction effect ofbacteria on high-valence selenium can rapidly achieve detoxification of selenite pollutants, the environment-friendly advantage is achieved, in addition, the biochar can effectively degrade refractory organic matter or pollutants by activating monopersulfate, the removal effect is good, the reaction speed is high, and the application prospect in the field of wastewater remediation is very wide.
Owner:CENT SOUTH UNIV

Three-dimensional porous carbon/polythionine compound modified electrode, and production method and application thereof

The invention belongs to the field of chemical analysis and detection, provides a three-dimensional porous carbon / polythionine compound modified electrode and a production method thereof, and also provides an electrochemical detection method based on the electrode. The three-dimensional porous carbon / polythionine compound modified electrode includes a base electrode, a polythionine coating and a three-dimensional porous carbon coating, the external surface of the base electrode is wrapped with the polythionine coating, and the external surface of the polythionine coating is wrapped with the three-dimensional porous carbon coating to form the three-dimensional porous carbon / polysulfide composite modified electrode. The three-dimensional porous carbon / polythionine compound modified electrodehas good electron transfer ability and can improve the reaction rate of the electrode, the production method has the advantages of simplicity, easiness in implementation, and low cost, and the electrochemical detection method based on the electrode has the advantages of simplicity in operation, good selectivity and high sensitivity.
Owner:SOUTH CHINA NORMAL UNIVERSITY

Preparation method of nitrogen-doped carbon nanotube supercapacitor

The invention discloses a preparation method of a nitrogen-doped carbon nanotube supercapacitor. The preparation method comprises the following steps: (1) preparing a stainless steel substrate; (2) carrying out vapor deposition on a one-dimensional carbon nanotube on the stainless steel substrate; (3) carrying out air annealing; and (4) preparing the nitrogen-doped carbon nanotube. Stainless steelis adopted as a substrate to be directly used for preparing the carbon nanotube, and Fe and Ni which are uniformly distributed in the substrate are used as catalysts, so other catalysts do not need to be introduced any more, and the raw material cost is reduced; Fe and Ni based on the stainless steel are uniform in distribution and good in corrosion resistance, and the prepared carbon nanotube isuniform and stable in structure; the specific surface area and the electrochemical activity are improved through air annealing treatment; nitrogen doping treatment can improve the hydrophilicity of the carbon nanotube, and enables the electrode to have an electric double-layer capacitor and a Faraday capacitor at the same time, thereby improving the capacitance performance of the electrode. The method provided by the invention is low in equipment requirement, controllable in cost and short in preparation time, and has a relatively great application prospect.
Owner:WUHAN UNIV OF SCI & TECH

Method for enhancing electron transfer capability of humic acid to promote anaerobic fermentation and acid production of sludge

The invention discloses a method for enhancing the electron transfer capacity of humic acid to promote anaerobic fermentation and acid production of sludge, and belongs to the field of sludge treatment. Humic acid in a sludge hydrolysate is subjected to catalytic reduction through Pd-C / H2, so that the electron transfer capacity of the humic acid is enhanced, the function of the humic acid as an electron intermediate or an anaerobic respiration electron acceptor in a sludge anaerobic fermentation system is enhanced, and by improving electron transfer between a sludge substrate and functional microorganisms, the conversion rate of sludge organic matter is improved. The modified humic acid can increase the yield of volatile fatty acid in the anaerobic fermentation process by 30-50%. According to the method, 100% of the Pd-C catalyst can be recycled, the cost is low, the efficiency is high, the method is a novel method and thought for improving the yield of volatile fatty acid in the anaerobic fermentation process of the sludge, sludge reduction and resource utilization are integrated, and the method has high application value.
Owner:JIANGNAN UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products