The invention relates to a super double-phase stainless steel composite steel plate and manufacturing method thereof. The super double-phase stainless steel composite steel plate has a four-layer structure, wherein, the middle two layers are double-phase stainless steel, and the upper and lower layers are carbon steel; the double-phase stainless steel comprise the following components by weight percentage: less than or equal to 0.03% of C, less than or equal to 1.20% of Mn, less than or equal to 0.80% of Si, 24.0-26.0% of Cr, 6.0-8.0% of Ni, 3.0-5.0% of Mo, 0.24-0.32% of N, and the balance ofFe and inevitable impurities; the carbon steel comprises the following components by weight percentage: 0.03 to 0.12% of C, 0.10 to 0.45% of Si, 0.70 to 1.60% of Mn, less than 0.020% of P, less than 0.025% of S, 0-0.35% of Cu, 0-0.40% of Cr, 0-0.40% of Ni, 0-0.05% of Nb, 0-0.40% of Mo, 0-0.018% of Ti, 0.015-0.045% of Al, and balance of Fe and unavoidable impurities. The composite steel plate of the invention can obtain good structural strength and corrosion resistance. The composite steel plate is the rolled composite plate, which can realize metallurgical bonding of a coating layer and a basematerial, so that the good bonding force can be obtained.