The invention discloses a preparation method of a ternary positive
electrode material of a high-
nickel monocrystal-like
lithium ion battery and the prepared ternary positive
electrode material. The preparation method comprises the following steps:
sintering a precursor and a
lithium source in air or
oxygen; uniformly mixing the precursor
metal oxide A and
lithium oxide obtained by
sintering according to a
molar ratio of lithium to
metal ions in A of 1.0-1.1, and carrying out primary
sintering in
oxygen to obtain B; adding 30-70% by
mass of B into pure water, uniformly mixing, adding 0.5-3% bymass of an
oxidizing agent without
metal ions, and stirring at 10-50 DEG C for 10-30 minutes; filtering,
drying, carrying out secondary sintering in
oxygen, and sieving to obtain the ternary positiveelectrode material LiNi<x>Co<y>Mn<z>M<t>O<2> of the high-
nickel single-
crystal-like
lithium ion battery, wherein x is more than or equal to 0.60 and less than or equal to 0.90, y is more than or equalto 0.05 and less than or equal to 0.20, z is more than or equal to 0 and less than or equal to 0.20, t is more than or equal to 0 and less than or equal to 0.005, x+y+z+t is equal to 1, and M is oneof Al, Ca, Mg, Zr, Ti, Sr, Mo, W and Ce. The ternary positive
electrode material of the high-
nickel single-
crystal-like
lithium ion battery contains
divalent nickel, has few surface impurities lithiumand impurities, and is good in processability, high in capacity and good in cycle performance when being used for manufacturing the battery.