The invention discloses a high-piezoelectric property and high-stability anti-reduction
potassium-
sodium niobate-based leadless piezoelectric
ceramic and a preparation method thereof. The
chemical formula of the piezoelectric
ceramic is as follows: (1-x)[(1-y)K0.5Na0.5Nb<1-z>Ta<z>O<3-y>Bi0.5(Na0.82K0.18)0.5ZrO3]-xCaZrO<3+k%>M, wherein x, y, z and k represent
molar fractions, x is greater than or equal to 0 and less than or equal to 0.03, y is greater than or equal to 0.02 and less than or equal to 0.05, z is greater than or equal to 0 and less than or equal to 0.12, k is greater than or equalto 0.2 and less than or equal to 0.6, x, y and z are not zero at the same time, and m represents a
manganese compound. According to the anti-reduction
potassium-
sodium niobate-based leadless piezoelectric
ceramic provided by the invention, the
piezoelectric constant d33 reaches 275 pC / N or above, the planar
electromechanical coupling coefficient kp can reach 0.50, the ceramic strain can reach 0.20% in a 50 kV / cm
electric field, and the maximum inverse
piezoelectric constant d33* reaches 500 pm / V (E = 25 kV / cm). Under a 35kV / cm
electric field, the d33* of a sample at
room temperature is equal to 460pm / V, and the temperature Te of the inverse
piezoelectric coefficient d33* is stabilized within 125 DEG C within the fluctuation range of + / -10%.