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306 results about "Methyl blue" patented technology

Methyl blue is a chemical compound with the molecular formula C₃₇H₂₇N₃Na₂O₉S₃. It is used as a stain in histology, and stains collagen blue in tissue sections. It can be used in some differential staining techniques such as Mallory's connective tissue stain and Gömöri trichrome stain, and can be used to mediate electron transfer in microbial fuel cells. Fungal cell walls are also stained by methyl blue.

Method for degrading organic waste water by photo-assisted activation of potassium hydrogen persulfate through bismuth ferrite

The invention discloses a method for degrading organic waste water by photo-assisted activation of potassium hydrogen persulfate through bismuth ferrite, belonging to the technical field of waste water treatment. A perovskite structure BiFeO3 in the invention has a spherical morphology and is prepared by adding a certain amount of a surface active agent under hydrothermal conditions; the specific surface area is high; and the prepared BiFeO3 self can degrade organic pollutants by photocatalysis under the irradiation of visible light. According to the method disclosed by the invention, BiFeO3 is applied to degrading the organic pollutants by activating potassium hydrogen persulfate; the methyl orange degradation rate within 15 min is 94%; the methyl blue degradation rate within 40 min is 90%; the rhodamine degradation rate within 40 min is 65%; by means of combined use of BiFeO3 and potassium hydrogen persulfate, the organic pollutants are oxidized and degraded; the organic pollutants can be effectively degraded under better illumination conditions; the organic pollutants can also be effectively oxidized and degraded without light or under poor illumination conditions; and therefore, the method has good application prospect.
Owner:ANHUI UNIVERSITY OF TECHNOLOGY

Visible-light-induced photocatalyst Bi4O5Br2 and preparation method thereof

The invention discloses a visible-light-induced photocatalyst Bi4O5Br2 and a preparation method thereof. According to the visible-light-induced photocatalyst Bi4O5Br2 and the preparation method thereof, an improved low-temperature hydrothermal method is adopted, composition of Bi, O and Br in BiOX is controlled by controlling amount of a bismuth source and a bromine source, and a novel layered-cake-shaped visible-light-induced photocatalyst Bi4O5Br2 is prepared successfully. The preparation method is simple in production process, easy to operate, low in synthesis temperature, high in reaction yield, environment-friendly and low in cost and meets the requirement of actual production, the reaction yield is 92%, and raw materials are easy to obtain. The visible-light-induced photocatalyst has good visible-light catalytic activity, can completely degrade various organic pollutants such as rhodamine b, methyl orange and methylene blue in short time under the visible light irradiation, is small in light corrosion and good in reusability, can be applied to industrial production and particularly has a better application value in organic pollutant degradation through solar photocatalysis, and the market potential is large.
Owner:YULIN NORMAL UNIVERSITY

Preparation method and application of novel silver-nanoparticle modified ultrathin graphite phase carbon nitride catalyst

The invention discloses a preparation method and application of a novel silver-nanoparticle modified ultrathin graphite phase carbon nitride catalyst. The method includes: subjecting urea to heat treatment to obtain lump graphite phase carbon nitride; subjecting the lump graphite phase carbon nitride to secondary heat treatment to obtain an annealing etched ultrathin graphite phase carbon nitridelayer; structuring a bionic mussel polydopamine biocoating on ultrathin graphite phase carbon nitride by adopting an impregnation method; based on polydopamine modification and by the aid of reducibility of silver nanoparticles, loading the silver nanoparticles on the surface of the ultrathin graphite phase carbon nitride. The two-dimensional ultrathin graphite phase carbon nitride layer is prepared by adopting the high-temperature annealing method, the silver nanoparticles are prepared by adopting the green bionic method of self-polymerization polydopamine, and good prospects of the novel composite high-activity photocatalyst are displayed in the field of organic pollutants like photocatalytic degradation of methylene blue and phenol.
Owner:NANTONG TEXTILE & SILK IND TECH RES INST

Preparation method and application of adsorbent

The invention provides a preparation method and application of an adsorbent. The preparation method comprises the following steps: grafting amido to the tail end of cyclodextrin, and then adding the cyclodextrin and polyacrylic acid to a graphene oxide dispersion liquid for reaction; preparing a surface grafting graphene oxide nanocomposite material through a one-step method, wherein the surface grafting graphene oxide nanocomposite material can fast and effectively treat dye wastewater and especially absorb methylene blue. The adsorbent prepared through the method provided by the invention has the advantages of property of forming clathration with a dye molecule by sufficiently utilizing a cyclodextrin molecule, large specific area of a nanometer material and a high-molecular material, abundance of oxygen-containing functional groups, good water solubility of the high-molecular material, abundance of hydroxy and carboxyl and the like and is capable of fast and effectively treating the dye wastewater by generating electrostatic attraction effect with a cationic dye by concentrating functional group carboxyl on the surfaces of the nanometer material and the high-molecular material; and the adsorbent prepared through the method provided by the invention is capable of fast and effectively treating the dye wastewater because the functional groups, namely the hydroxy, the carboxyl and the like, easily form hydrogen bonds with a water molecule.
Owner:ANHUI NORMAL UNIV

Silver chloride-silver phosphate composite photocatalyst and preparation method thereof

The invention discloses a silver chloride-silver phosphate composite photocatalyst and a preparation method thereof. In the composite photocatalyst, the mole percent ratio of silver chloride and silver phosphate, i.e. silver chloride: silver phosphate, ranges from 1:0-0.3. The preparation method comprises the steps of: preparing a mixed solution of chloride ions and phosphate ions first, and then adding Ag+ ions to the mixed solution, thus obtaining the silver chloride-silver phosphate composite photocatalyst. Application of the silver chloride-silver phosphate composite photocatalyst provided in the invention to photocatalytic degradation of the organic pollutant methylene blue can greatly improve the reaction activity of a silver chloride photocatalyst. In addition, the preparation method of the silver chloride-silver phosphate composite photocatalyst in the invention is simple and practicable, thus benefiting large-scale popularization.
Owner:SHANGHAI UNIVERSITY OF ELECTRIC POWER

Preparing method and application of nitro phthalocyanine zinc/sulfur-containing carbon nitride composite catalyst

The invention discloses a preparing method and application of a nitro phthalocyanine zinc / sulfur-containing carbon nitride composite catalyst and belongs to the field of preparation of photocatalytic materials. The preparing method of the nitro phthalocyanine zinc / sulfur-containing carbon nitride composite catalyst comprises the following steps that 1, the composite catalyst is prepared, wherein nitro phthalocyanine zinc and sulfur-containing carbon nitride are prepared respectively, then a nitro phthalocyanine zinc / sulfur-containing carbon nitride composite material (ZnTNPc-CNS) is prepared through the dipping method, and a series of composite materials are prepared by adjusting the different sulfur content of the carbon nitride; 2, the property characterization of photocatalytic degradation of the organic pollutant-methylene blue is achieved, wherein the effect of degradation of methylene blue by pure nitro phthalocyanine zinc is not obvious, and the photocatalytic degradation effect is obviously improved after the nitro phthalocyanine zinc is combined with the sulfur-containing carbon nitride. The novel nitro phthalocyanine zinc / sulfur-containing carbon nitride composite material prepared through the method has good methylene blue photocatalytic degradation performance and is an environment-friendly and efficient photocatalyst.
Owner:常州创嬴建材制造有限公司

Preparation method and application of nano MFe2O4 supported hollow fiber composite ceramic membrane with catalytic separation function

The invention relates to a preparation method and application of a nano MFe2O4 supported hollow fiber composite ceramic membrane having catalytic separation function, pollution resistance and low energy consumption, and belongs to the field of application of inorganic ceramic membranes in water treatment. A hollow fiber ceramic membrane is used as a support, stable nitric metal salt of citric acid is used as a catalyst mother liquid, and dipping and temperature calcining process is performed to prepare the nano MFe2O4 supported hollow fiber composite ceramic membrane. In in-situ coupling with the sulfuric free radical advanced oxidation technique, the nano MFe2O4 supported hollow fiber composite ceramic membrane can be applied to the treatment of low-concentration organic wastewater, such as dye wastewater and medicine and personal nursing product wastewater, in order to efficiently remove typical contaminants, such as methyl blue, rhodamine B and ibuprofen drugs, with the removal rate stilling being 91.8% and above in 55-60 min while methyl blue wastewater concentration is < / =25 mg / L and water level is 30 cm (2.94 kPa); similarly, the removal rate of rhodamine B is 90.7%; after 1 h of operation, when ibuprofen wastewater concentration is < / =10 Mu mol / L, the removal rate of ibuprofen is kept to 99.5% and above.
Owner:DALIAN UNIV OF TECH

Supported photocatalyst for treating liquid methylene blue pollutant and its prepn process and application

The present invention relates to one kind of supported photocatalyst and its preparation process and application. The technological scheme is that the supported photocatalyst for treating liquid methylene blue pollutant is prepared fixing nanometer TiO2 powder onto the surface of active carbon fiber with resin as adhesive and the subsequent calcining in nitrogen atmosphere to obtain the supported photocatalyst adhered with the residue. The supported photocatalyst has TiO2 supporting amount of 25-55 wt% and calcining temperature of 400-550 deg.c. Under illumination of ultraviolet ray, the supported photocatalyst can eliminate methylene blue and other organic pollutant from water solution in the degradation efficiency up to 99 % and basically unchanged circularly using efficiency.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

High-selectivity magnetic dye adsorbent and preparation method thereof

The invention discloses a high-selectivity magnetic dye adsorbent and a preparation method thereof. The preparation method comprises the following steps: preparation of magnetic nano-Fe3O4; preparation of nano-Fe3O4-SiO2; surface amino modification of nano-Fe3O4-SiO2; bromination modification of nano-Fe3O4-SiO2-NH2; preparation of nano-Fe3O4-SiO2-PGMA (polyglycidyl methacrylate); and Lysine modification of nano-Fe3O4-SiO2-PGMA. The adsorbent is larger in specific surface area and rich in bisexual activated adsorption sites; high-selectivity separation can be performed on an organic dye such aslemon yellow and methylene blue; the adsorbent is higher in adsorption capacity and high in adsorption rate; due to the characteristic of good magnetic response, cyclic regeneration of a material isensured, and secondary pollution to water bodies can be prevented, and therefore, the adsorbent has a considerable application prospect in the aspect of treatment of water pollution caused by the organic dye.
Owner:SHANDONG UNIV

Preparation method of compound nanotube photocatalytic film of titanium dioxide and silicon dioxide

The invention relates to a preparation method of a compound nanotube photocatalytic film of titanium dioxide and silicon dioxide, which belongs to the field of nanofilms. At present, the problem of easy compound of photo-excited holes and electron pairs of a titanium dioxide photocatalytic film causes that the titanium dioxide photocatalytic film has lower efficiency when being applied to sewage treatment. The preparation method comprises the following steps: adopting anodic aluminum oxide (AAO) as a template and dipping the AAO into a mixed solution of (NH4)2TiF6 and (NH4)2SiF6 at 30-40 DEG C for co-deposition in-situ growth by utilizing a liquid-phase deposition method so as to prepare the compound nanotube photocatalytic film of titanium dioxide and silicon dioxide with a good appearance; after cleaning and drying the prepared film, preparing the compound nanotube photocatalytic film of titanium dioxide and silicon dioxide with high photocatalytic performance by carrying out heat treatment and preserving heat for 2-4 hours at 400-600 DEG C. The preparation method completes the nanofilm and compound treatment at one time, and the film has strong repeatability, is convenient for mass production and can get a treatment efficiency of 70-95 percent after being applied to a photocatalytic reaction of a methyl blue solution of 100mg/L (0.1wt%).
Owner:BEIJING UNIV OF TECH

Method for simultaneously synthesizing hydrophilic and hydrophobic carbon points and application of method to detection of Au<3+> and preparation of white light-emitting diodes

The invention discloses a method for simultaneously synthesizing hydrophilic and hydrophobic carbon points and an application of the method to detection of Au<3+> and preparation of white light-emitting diodes, and belongs to the field of fluorescent carbon nano-materials. The method includes the steps: taking sulfuric acid as a raw material, dissolving the sulfuric acid by ethyl alcohol, and stirring mixture to form uniform mixed solution; transferring the mixed solution into a polytetrafluoroethylene high-pressure reactor, and heating the mixed solution at the temperature of 200 DEG C; cooling the mixed solution to reach the indoor temperature to obtain black lower-layer solution serving as a hydrophilic carbon point and red upper-layer solution servicing as a hydrophobic carbon point. According to the simple method for simultaneously synthesizing the hydrophilic and hydrophobic carbon points, 8mg of methylene blue is added into the raw material, the prepared hydrophilic carbon pointcan be used for manufacturing the white light-emitting diodes under irradiation of 365nm ultraviolet rays, the prepared hydrophilic carbon point can sensitively and selectively detect gold ions whenserving as a fluorescent probe, and the gold ions in cells can be visually detected and analyzed.
Owner:HENAN UNIVERSITY

Adsorbing agent capable of selectively removing dyes containing sulfonic acid groups in wastewater and method of adsorbing agent

The invention discloses an adsorbing agent capable of selectively removing dyes containing sulfonic acid groups in wastewater and a method of the adsorbing agent. Nanometer flake basic copper nitrate is used as the adsorbing agent to remove the dyes containing the sulfonic acid groups in the wastewater. The adsorbing agent can be put into a single dye (Congo red or methyl blue or methyl orange) solution containing sulfonic acid groups, and the adsorbing agent can also be put into a mixed solution of Congo red and methyl blue and a mixed solution of methyl orange and methyl blue. It is shown through results that the adsorbing agent achieves a very high adsorbing quantity on the dyes containing the sulfonic acid groups and can selectively adsorb the dyes containing the sulfonic acid groups.
Owner:ANHUI UNIVERSITY

Preparation method of sheet-shaped g-C3N4 composite petal-shaped BiOBr photocatalytic material

The invention provides a preparation method of a sheet-shaped g-C3N4 composite petal-shaped BiOBr photocatalytic material(BiOBr/g-C3N4 photocatalytic material). The method comprises the steps of usingcerium nitrate pentahydrate, cetyltrimethylammonium bromide, bismelamine, ethylene glycol and nitric acid (2mol/L)as main raw materials, using solvothermal synthesis to prepare the BiOBr/g-C3N4 photocatalytic material, using an xenon lamp as a light source to simulate sunlight, filtering 420 nanometre ultraviolet light (lambade), and conducting photocatalytic performance testing on the BiOBr/g-C3N4 photocatalytic material; degrading toxicorganic pollutants such as methyl orange, methylene blue, rhodamine B and the like in water to prove that the BiOBr / g-C3N4 photocatalytic material has good photocatalytic properties under visible light. The BiOBr/g-C3N4 photocatalytic material is a composite of a non-metal semiconductor and a hafnium oxyhalide material, a special band structure and good optical properties are the basis of being a photocatalyst, the material has the advantages of being non-toxic, inexpensive and easy to prepare, and the material has broad application prospects in the treatment of the pollutants and the development of new energy sources by using the solar energy.
Owner:NANCHANG HANGKONG UNIVERSITY

Preparation method for titanium oxynitride photocatalyst

The invention specifically reveals a preparation method for a titanium oxynitride photocatalyst, which belongs to the technical field of chemical engineering of titanium dioxide photocatalysts. The method comprises the following steps: uniformly mixing TiN powder and concentrated alkali, adding an oxidizing agent and homogenizing an obtained mixture with stirring so as to obtain a mixed emulsion;transferring the mixed emulsion to a hydro-thermal kettle and allowing the mixture to maintain a temperature of 150 to 200 DEG C for 6 to 18 h so as to obtain a sample; rinsing the sample with deionized water until the sample is neutral and drying the sample so as to obtain the titanium oxynitride photocatalyst which is chrysanthemum powder. The oxidation degree of titanium oxynitride can be controlled by adjusting the concentration of alkali, hydro-thermal time, hydro-thermal temperature or the concentration of the oxidizing agent. The preparation method provided in the invention is simple. According to results of photocatalysis tests, the chrysanthemum-like titanium oxynitride prepared by the method has excellent activity of photocatalytic degradation of methylene blue and photocatalytic decomposition of water into hydrogen.
Owner:FUDAN UNIV
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