The invention relates to super-hard organic
silicone hydrophobic glass resin and a preparation method thereof. Under the
catalysis of a Karsted catalyst, active
silicon-
hydrogen bonds and carbon-carbon double bonds in
hydrogen-containing polymethylhydrogensiloxane, vinyl MQ
silicone resin, polyhydroxy polysiloxane, and amino
silicone oil are crosslinked, and active
silicon-
hydrogen bonds and hydroxyl or amino in the hydrogen-containing polymethylhydrogensiloxane, the vinyl MQ
silicone resin, the polyhydroxy polysiloxane, and the amino
silicone oil are crosslinked, so that three-dimensional network-shaped organic
silicone resin is formed, and then in the presence of a catalyst,
polysilazane reacts with hydroxyl, amino or carbon-carbon double bonds in the organic
silicone resin through active -Si-H to be grafted on the molecular chain of the organic silicone resin. The glass resin provided by the invention can be self-catalyzed and cured at a
room temperature, and has uniform film formation without
cracking or powdering; the film has good
water resistance and
stain resistance, and the
contact angle of water and the film formed after the glass resin coats the surface of a tile can reach 130 degrees; the transparency is good, and the light
transmittance is up to 80%; and the
hardness of the film is high, the pencil
hardness is up to 7H or above, and the film can withstand the hightemperature of 300 DEG C.