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Water-retaining agent and manufacture method thereof

A production method and water-retaining agent technology, applied in chemical instruments and methods, applications, organic fertilizers, etc., can solve the problems of post-processing granulator drying difficulties, water-retaining agent fine powder, plant growth threats, etc., to achieve the benefit of manufacturing Granular and dry, short reaction time, hard appearance

Inactive Publication Date: 2017-12-05
YANGXIAN COUNTY ZHUHUAN ORGANIC IND TECH CONSULTATION CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The polymerization method of acrylic acid as a raw material under low-temperature cooling conditions is usually to dissolve acrylic acid, acrylamide, and crosslinking agent N, N'-methylenebisacrylamide neutralized by sodium hydroxide in water, and react with an inducer Prepared, in which acrylic acid is neutralized with a strong base, a large amount of heat will be released during the reaction process, and it needs to be cooled with water, which greatly increases the production cost. Drying consumes a lot of energy and produces a lot of fine powder of water-retaining agent, which is reflected in the increase of the water solubility of the gel after water absorption, and the water absorption performance is 24-200 times of its own total amount; at the same time, it is found that during the application process, sodium ions will affect the soil. have adverse effects
Water-retaining agents are ubiquitous and easy to breed microorganisms, which can easily rot the roots of plants and pose a fatal threat to plant growth.

Method used

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  • Water-retaining agent and manufacture method thereof
  • Water-retaining agent and manufacture method thereof
  • Water-retaining agent and manufacture method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment example

[0021] The steps to implement the case are as follows:

[0022] (a) Acid-base neutralization: acrylic acid is formulated into a 50% aqueous solution, neutralized with 15% potassium hydroxide aqueous solution, wherein the mass ratio of acrylic acid to potassium hydroxide is 4:1, and acrylic acid is neutralized with potassium hydroxide aqueous solution Finished, and then add ammonium carbonate solid to neutralize the aqueous acrylic acid solution again, finally, the neutralization degree of acrylic acid is controlled to 70%, and neutralization mixture A (acrylic acid, potassium acrylate, ammonium acrylate mixture) is obtained;

[0023] (b) Polymerization reaction: Add acrylamide and crosslinking agent N, N'-methylenebisacrylamide to the neutralization mixture A, the dosages are respectively 30% and 0.18% of the total mass of the reaction monomer acrylic acid and acrylamide, After stirring and dissolving, put it into a strip-shaped polymerization reaction tray, and then add induc...

Embodiment 2

[0029] The steps to implement the case are as follows:

[0030] (a) Acid-base neutralization: acrylic acid is formulated into a 52% aqueous solution, neutralized with 10% potassium hydroxide aqueous solution, wherein the mass ratio of acrylic acid to potassium hydroxide is 4.5:1, and acrylic acid is neutralized with potassium hydroxide aqueous solution Finished, and then add ammonium carbonate solid to neutralize the aqueous acrylic acid solution again, finally, the neutralization degree of acrylic acid is controlled to 75%, to obtain neutralization mixture A (acrylic acid, potassium acrylate, ammonium acrylate mixture);

[0031](b) Polymerization reaction: Add acrylamide and crosslinking agent N, N'-methylenebisacrylamide to the neutralization mixture A, the dosages are respectively 34% and 0.2% of the total mass of the reaction monomer acrylic acid and acrylamide, After stirring and dissolving, put it into a strip-shaped polymerization reaction plate, and then add the induce...

Embodiment 3

[0038] The steps to implement the case are as follows:

[0039] (a) Acid-base neutralization: prepare acrylic acid into a 50% aqueous solution, neutralize with 15% potassium hydroxide aqueous solution, and finally control the neutralization degree of acrylic acid to 75%, and obtain neutralization mixture A (acrylic acid, potassium acrylate mixture) ;

[0040] (b) Polymerization reaction: Add acrylamide and crosslinking agent N, N'-methylenebisacrylamide to the neutralization mixture A, the dosages are respectively 30% and 0.18% of the total mass of the reaction monomer acrylic acid and acrylamide, After stirring and dissolving, put it into a strip-shaped polymerization reaction plate, and then add inducing agents potassium persulfate and potassium sulfite in sequence, the doses are respectively 0.1% and 0.1% of the total mass of the reactants, stir well and carry out polymerization synthesis at room temperature to obtain strips -like intermediate B;

[0041] (c) Granulation:...

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Abstract

The invention provides a water-retaining agent and a manufacture method thereof. The method is characterized by comprising the following steps: adding a few amount of low-concentration potassium hydroxide solution into an acrylic acid aqueous solution for neutralization, neutralizing with ammonium carbonate, controlling neutralization degree of acrylic acid to 70-75%, adding acrylamide, a cross-linking agent N,N'-methylene bisacrylamide, an inducer potassium persulphate and potassium sulfite to carry out normal-temperature synthesis, mixing with a rooting agent naphthylacetic acid and an anti-bacteria agent Xitujunke and granulating, and drying. During the whole synthesis, potassium and ammonium ion compounds which are beneficial to plants are adopted; by normal-temperature synthesis, energy consumption is saved; the process is safe and reaction time is short; and the preparation method is simple, and the prepared water-retaining agent has advantages of large molecular weight, less powder, fast water absorption speed, good water retention and antibacterial and root-promoting effects.

Description

technical field [0001] The invention relates to a water retaining agent and a preparation method thereof, belonging to the technical field of agricultural production. Background technique: [0002] Drought has the characteristics of high frequency, long duration and wide range. The frequent occurrence and long-term persistence of drought will not only bring huge losses to the social economy, especially agricultural production, but also cause many ecological and environmental adverse effects such as water shortages, intensified desertification, and frequent sandstorms. From 2000 to 2015, the average annual drought-affected area in my country was 21.22 million hectares, accounting for about 60% of the area affected by various meteorological disasters. [0003] Water-retaining agent, also known as water-absorbing agent, moisture-retaining agent, jelly for agriculture and forestry, hydrated soil, soil conditioner, polywater glue, etc. in agriculture and forestry, is a general t...

Claims

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Application Information

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IPC IPC(8): C08F220/06C08F220/56C08F222/38C09K17/20C09K101/00
CPCC08F220/06C09K17/20C09K2101/00C08F220/56C08F222/385
Inventor 周宝龙周佳周子恒丁鹏
Owner YANGXIAN COUNTY ZHUHUAN ORGANIC IND TECH CONSULTATION CO LTD
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