345results about How to "Potential application value is good" patented technology

The invention relates to a composite material of a nitrogen-doped porous carbon-wrapped carbon nano tube as well as a preparation method and an application of the composite material. The preparation method comprises the following steps: dispersing the carbon nano tube in water, adding a carbon source to obtain a reaction system, subsequently performing hydrothermal reaction, performing thermal treatment on the carbon nano tube wrapped with a carbon layer on the surface, and a nitrogen source at the high temperature so as to obtain the composite material of the nitrogen-doped porous carbon-wrapped carbon nano tube. According to the preparation method, the carbon source is polymerized under a hydrothermal reaction condition so as to obtain the carbon layer, the outer surface of the carbon nano tube is wrapped with the carbon layer, subsequently the carbon layer is carbonized and decomposed to generate a porous structure under high temperature treatment, and at the same time, the gasified nitrogen source is diffused to the carbon layer through ducts to be subjected to in-situ doping. The composite material provided by the invention can be used as a cathode oxidation reduction catalyst of a fuel battery, is excellent in catalysis, and is high in oxidation activity when being compared with other nitrogen-doped materials reported in documents. The preparation method provided by the invention is simple and economic in process, convenient to operate and easy to achieve the large-scale production.

The invention discloses a sericite / nano-zinc oxide composite material and a preparation method thereof. The composite material is characterized in that the surface of sericite powder is coated with nano-zinc oxide. The preparation method comprises the following step: adding calcium hydroxide or calcium oxide into a mixed system of the sericite powder and zinc sulfate solution so as to directly obtain the nano-zinc oxide coated sericite powder composite material. According to the method, the sericite which is taken as a base material is a natural mineral, so that the raw material is easily available, free of pollution and low in cost; the preparation process is simple, safe, reliable and easy to control; the obtained composite material is stable in quality, and has the good dispersibility in an organic solvent and also has the excellent ultraviolet resistance and the excellent antibacterial and deodorant performance. Thus, the composite material can be applied to the field of coatings, cosmetics and the like. The method has a good potential application value in the field of synthesis of the composite material or other related sciences.

The invention discloses a preparation method for monophosphate-adjuvant water-soluble fluorescent carbon quantum dot solid powder, which belongs to the technical field of nanometre materials. The preparation method comprises the following steps of: by taking soluble phosphate solution as an adjuvant, taking saccharides, amino acids and some low-molecular-weight organic matters containing hydroxyl and carboxyl as reaction precursors and adopting a microwave heating means, directly preparing solid carbon quantum dot powder in one step; and adding an appropriate amount of ethanol aqueous solution to precipitate and removing most of salts, then performing further purification by virtue of strong-base anion exchange resin and strong-acid cation exchange resin sequentially, centrifuging and then performing rotary evaporation on the supernatant, so as to obtain the purified carbon quantum dot solid powder. The carbon quantum dots prepared by the preparation method disclosed by the invention are good in solubility in water, and solid powder samples can be stored for a long time; meanwhile, the obtained carbon quantum dots further are also excellent in water solubility and fluorescence characteristic. The whole preparation process is simple to operate, requirements on equipment are low, and raw materials are low in cost, wide and easily available; the preparation method is an environment-friendly preparation method for carbon quantum dots.

The invention relates to a preparation method and application of a composite material of a carbon nanotube coated by a carbon layer embedded with precious metal nano particles. The carbon nanotube composite material is simple and economic in preparation process and easy to produce in large scale, and precious metal nano particles with different grain diameters and the carbon layers with different coating thicknesses can be obtained by changing preparation conditions. The composite material prepared by the invention can be used as a cathodic oxygen reduction catalyst of a fuel cell, and the catalytic stability of the composite material is obviously superior to that of a simple material and a currently used commercialized carbon supported platinum catalyst.

The invention discloses a tomato S1lPIF4 gene, protein and application thereof to improving the low temperature resistance of plant. The nucleotide sequence of the S1lPIF4 gene is SEQ ID NO.1, and thecorresponding amino acid sequence is as shown in SEQ ID NO. 2. A tomato SlIPIF4 overexpression plant or a gene knockout plant through the gene means to regulate the expression level of the S1lPIF4 gene in order to do research on the regulatory mechanism of the S1lPIF4 gene on the low temperature resistance of tomato. According to the result, overexpression of S1lPIF4 at the lower temperature canpromote accumulation of plant hormone abscisic acid (ABA) and jasmonic acid (JA), inhibits accumulation of gibberellin (GA), further induces expression of the low temperature resistant gene of the tomato, and finally improves the low temperature resistance of the tomato. Therefore, the S1lPIF4 gene of the tomato enhances the low temperature resistance by inducing formation of hormones ABA and JA in the body. The tomato S1lPIF4 gene provides the gene resource for breeding new varieties of low temperature resistant tomato, has the good potential application value, and lays theoretical basis fordoing research on tomato plant distress response signal mechanism and molecular mechanism of being tolerant to adverse environment.

The invention belongs to the technical field of high-molecular chemistry and relates to a multiple sensitive hydrogel material and a preparation method thereof. The hydrogel material comprises a polymer with cyclodextrin (subject) and polyether pluronic modified by ferrocene (object) group. A gel formation method comprises steps of: simultaneously dissolving the polymer with cyclodextrin and the polyether pluronic with ferrocene group in water; and stirring and dispersing thoroughly under certain solution condition, so as to form a large amount of crosslinking netted organizations based on subject and object identification in the solution. The gel material can response to environment temperature change, oxidizing agent, existence of electric field or change of glucose concentration to generate gel-sol conversion. The invention has advantages of simple preparation method, environment-friendliness and thrift, and has huge application value in biomedicine.

The invention relates to a method for preparing micro-fibrillated nanocellulose by use of degummed ramie. The degummed ramie is used as a raw material and is crushed into short fibers by a physical-mechanical method, then the short fibers are soaked with distilled water, and then are prepared into cellulose pulp by a beating machine; the cellulose pulp is ground continuously in a reciprocating manner by an ultra-fine refiner to enable the cellulose to be stressed in a refining manner to obtain suspension liquid; and finally, the nanocellulose and water are separated by a centrifugal washing method, and drying is carried out by a vacuum freezing method to finally obtain the powdery micro-fibrillated nanocellulose. The method is simple, has high efficiency, raw material price is low, no chemical agent needs to be added, the energy consumption is low, pollution is slight, the control is easy, and the prepared micro-fibrillated nanocellulose has high yield, good repeatability and good performances and has important scientific significance and considerable application prospect.

The invention provides a derivate of low molecular weight fucosylated glycosaminoglycan (dLFG) and a medical composition containing the dLFG or pharmaceutically acceptable salt and application of the dLFG and the medical composition for preparing medicines for treating thrombotic diseases.

The invention belongs to the field of energy storage materials and particularly relates to a modified carbon dioxide shaped phase change material and a preparation method thereof. The energy storage material comprises the following components in percentage by weight: 10-90wt% of an organic phase change material and 10-90wt% of a chemical bond bonded carbon material modified carbon dioxide supporting material, wherein the structure of the chemical bond bonded carbon material modified carbon dioxide supporting material is shown in a general formula (I) shown in the description, R is CnH2n straight chain saturated alkyl bonded with a carbon atom, n is greater than or equal 2 but less than or equal to 5, and n is an integer; Carbon represents the carbon material. The energy storage material provided by the invention has the advantages of great energy storage density and high stability, is suitable for the field of energy-saving building materials, solar energy storage and utilization, industrial waste heat recovery and the like, and has a broad application prospect.

The invention discloses a four-needle shaped zinc oxide crystal whicker of functional coating layer and preparation method thereof, comprising the steps of coating product prepared by high temperature cracking reaction containing metal organic silicon polymer on surface of the four-needle shaped zinc oxide crystal whicker. The prepared four-needle shaped zinc oxide crystal whicker of functional coating layer can not only obtain conduct crystal whicker or magnetic crystal whicker, but also maintain the four-needle structure of the crystal whicker to maintain regularity of the shape and consistency of the size, characterized in high intensity, high modulus, high temperature resistance and so on. The invention has great potential application value in the fields of anti-static, electric-magnetic screen, radar absorbing and so on.

The invention relates to a preparation method of a mesoporous silica microsphere. The method comprises the following steps that 1, a polystyrene microsphere is prepared; 2, the polystyrene microsphereis subjected to sulfonation; 3, a polystyrene / silicon dioxide composite microsphere is prepared; 4, polystyrene in the polystyrene / silicon dioxide composite microsphere is removed, and finally the mesoporous silica microsphere is obtained. According to the prepared mesoporous silica microsphere, by adjusting the cross-linking degree of a polystyrene template, the particle size of generated nano silicon dioxide can be controlled, therefore, the mesoporous size generated after particles are stacked is controlled, and pore diameter adjustable excellent performance is achieved. No expensive pore-forming agent is needed, and then the mesoporous silica microsphere which is uniform in pore diameter and high in specific surface area can be obtained.

The invention discloses a rhizobium and microbial inoculum, preparation method and application thereof. The rhizobium is a Rhizobium radiobacter A32, the preservation department of the rhizobium is the China General Microbiological Culture Collection Center (CGMCC), the preservation date of the rhizobium is November 21, 2014, and the preservation serial number is CGMCC, No.10031. The rhizobium belongs to the kingdom of bacteria, the phylum of mycetozoan, the class of alpha-mycetozoan, the order of rhizobia, the family of rhizobia and the genus of rhizobia. The rhizobium is microbial inoculum which has active components and is obtained after plate culture, seed culture and fermentation are conducted on the radioactive rhizobium. Bacillus is microbial inoculum which has active components and is prepared through plate culture, seed culture, fermentation and fungicide preparation. The microbial inoculum is used for phosphate solubilizing and potassium solubilizing of soil and increase of the amount of soil mineral nitrogen.

The invention belongs to the field of materials, and specifically relates to a perovskite nanosheet material as well as a preparation method and application thereof. The preparation method of the perovskite nanosheet material comprises the following steps: (1) mixing cesium carbonate powder with octadecene and oleic acid, dissolving the cesium carbonate powder by heating to 100-130 DEG C under aninert atmosphere, rising the temperature of a system to 140-160 DEG C and reacting for 10-60 min to obtain a cesium oleic acid precursor; mixing iron bromide power with octadecene, oleic acid and oleylamine, dissolving, then adding lead bromide power into an obtained mixed solution, and dissolving the lead bromide powder by heating to 100-120 DEG C under an inert atmosphere so as to obtain an ironand lead mixed solution; and (2) heating the cesium oleic acid precursor to 80-100 DEG C, uniformly mixing with the iron and lead mixed solution, performing a thermal insulation reaction for 5 s-5 min at 120-140 DEG C, cooling and then performing centrifugal separation. Therefore, the obtained perovskite nanosheet material has relatively short light-emitting wavelength; the light-emitting peak position is at about 436 nm; the half peak width is only 14 nm; the light-emitting peak is fully symmetric; and the two-dimensional perovskite nanosheet material is very uniform in size and thickness, and is easy to control.

The invention discloses a preparation method for a catalyst efficiently catalyzing hydrogenation reduction of 4-nitrophenol, and belongs to the technical field of nanometer material preparation and application. Employed graphene-shaped non-integer-ratio cobaltous selenide (Co[0.85]Se) has the thickness not larger than 10 nanometer, and titanium dioxide supported by the cobaltous selenide (Co[0.85]Se) has the particle size of about 10 nanometer. The catalyst is large in specific surface area, has high catalytic efficiency on hydrogenation reduction of 4-nitrophenol, does not employ noble metals and is low in cost. The preparation method is simple, easy to operate, free of organic templates and surfactants, and suitable for industrial production. The prepared titanium dioxide / cobaltous selenide (Co[0.85]Se) is pure in phase, large in specific surface area, good in catalytic reduction effect on 4-nitrophenol and high in repeated utilization value, and has potential utilization value on the aspect of sewage processing.

The invention discloses a super capacitor electrode material and a preparation method thereof. According to the electrode material, a conductive agent and a binder are not used, a hydrothermal method is used to directly attach an active material to a surface of a flexible conductive substrate, and then the material is subjected to high temperature calcination in a muffle furnace to obtain a final electrode material. Since the conductive agent and the binder are not used, the fast transfer of ions is facilitated by a growth method, for an electrode with a blocked mass transfer process, the electrode impedance is effectively reduced by the growth method, the electrode specific capacity is improved, through a test, the specific capacity can reach 1590.4F / G in current density of 1 A / g, the electrode still can maintain 102% capacity after 10000 cycles under the current density of 10 A / g, and the electrode material has an industrialization prospect.

The invention provides a method for measuring a cadmium isotope ratio in rice by using a multi-receiving inductance coupling plasma mass spectrum. The method comprises the following steps: 1, performing microwave digestion on a rice sample to measure the content of total cadmium; 2, performing microwave digestion on the rice sample to measure the content of total cadmium in a separated and purified rice sample, thereby obtaining a separation and purification rate; 3, performing microwave digestion on a to-be-measured rice sample, and performing separation and purification to obtain to-be-measured liquid; and 4, measuring the cadmium isotope ratio in the to-be-measured liquid by using the multi-receiving inductance coupling plasma mass spectrum, wherein the separation and purification process specifically comprises the following steps: a, converting a nitric acid medium of a digestion solution into a hydrochloric acid medium; b, leaching the digestion solution of the hydrochloric acid medium for five times by using hydrochloric acid, and then leaching for two times by using Milli-Q water to obtain a leachate; c, eluting and collecting the leachate; and d, converting an eluting solution into a nitric acid medium from a hydrochloric acid medium. By adopting the method provided by the invention, the technical problem of separating and purifying cadmium from a rice sample low in cadmium content is solved, and a cadmium pollution source can be quickly and accurately restored, so that the method has a good application value.

A chip implanted closed-loop blood pressure control method and system features that after a microprocessor chip is implanted in human body, its blood pressure sensor can acquire the arterial blood pressure signal and the electric stimulation with the intensity relative to said arterial blood pressure signal is output via electrode to act on the lead-in nerve channel. Said stimulation intensity is dynamically regulated by the chip to form a closed-loop negative feedback regulation, so controlling the blood pressure in a predefined range.

The invention discloses a method for preparing soft magnetic mesoporous nickel-zinc ferrite microspheres and overcomes the disadvantages that steps are fussy, the requirements of reaction conditions are high, the size, morphology and structure of particles are difficult to control, and the reproducibility is low in the conventional method. The method comprises the following steps of: performing hydrothermal reaction on a glucose solution which is taken as a raw material, and centrifuging at high speed to obtain C microspheres; matching the C microspheres which are taken as a template with ammonium acetate, Ni salt, Zn salt and Fe salt in a glycol environment to obtain nickel-zinc ferrite-C precursor composite microspheres; and finally, removing the C microsphere template from the nickel-zinc ferrite-C precursor composite microspheres through calcination to obtain a residual product, namely the soft magnetic mesoporous nickel-zinc ferrite microspheres. The method is low in cost and high in yield and productivity, is easy to operate, can repeat and amplify, can be applied to the fields of medicine carriers, electromagnetic shielding, nano-magnetic packing and the like, and has good potential application value, reaction conditions are mild and pollution-free, and the process is easy to control.

The invention provides a method for determining microcystic toxins concentration and is based on that molybdenum disulfide quantum dots can interact with gold nanoparticles through the internal filtration effect. Microcystic toxins can affect the degree of aggregation of aptamer-modified gold nanoparticles in the high salt solution, and detection of the microcystic toxins concentration in the water environment is achieved. The method is advantaged in that upconversion fluorescence of the molybdenum disulfide used can effectively avoid interference of background matrix fluorescence in the waterenvironment, optical stability is good, the detection result is accurate and reliable, cost is low, operation is simple, environmental protection is realized, detection specificity is good, influenceof other common metal ions or anions on determination of the microcystic toxins is avoided, the anti-interference ability is strong, the result is sensitive and reliable, the detection limit is low,the response speed is fast, the entire reaction process takes only 20 minutes, detection efficiency is greatly improved, good stability is achieved, real-time online fast, specific detection can be realized, and the method can be used for simple and rapid detection of microcystic toxins in the actual water environment.

The invention discloses a method for preparing an orientation arrangement Nb2O5 nanorod through single-reagent self reaction. The method comprises the following steps that (1) potassium fluoniobate powder is selected and dissolved in deionized water; a potassium fluoniobate dilute solution is put into a pretreated noble metal tube; sealing is performed; (2) the noble metal tube is put into a hydrothermal reaction kettle for sealing; the temperature in the hydrothermal reaction kettle is regulated to 200 to 500 DEG C; inert gas or deionized water is used for regulating the pressure in the hydrothermal reaction kettle to be 50 to 200MPa; hydrolysis reaction is performed for 12 to 24h; after the reaction is finished, the reaction kettle is subjected to temperature reduction to room temperature; (3) the hydrothermal reaction kettle is opened; the noble metal tube after the reaction is taken out and opened; residual solution is recovered; samples are collected; the orientation arrangement Nb2O5 nanorod is obtained. The method has the advantages that the single reagent is used as a synthetic raw material; the raw materials are simple and can be easily obtained; the cost is low; the energy consumption is low; the Nb2O5 nanorod obtained through preparation has good crystal form; the directionality is obvious.

The invention relates to the field of a lithium ion capacitor, in particular to a method for lithium pre-embedment of a negative electrode of the lithium ion capacitor. The method comprises the following steps of preparing active paste of the negative electrode, and applying the paste onto a porous copper foil through which lithium ions can pass to prepare a negative pole plate; attaching a layer of low-cost lithium-containing material lithium sheet or a lithium foil on the back surface of the negative pole plate to prepare the negative pole plate capable of lithium embedment; preparing the lithium ion capacitor by the negative pole plate capable of lithium embedment; and enabling the lithium sheet attached onto the back surface of the negative electrode to be spontaneously embedded into a negative electrode material during the formation of the capacitor so as to complete the lithium pre-embedment of the negative electrode of the lithium ion capacitor. The method is simple and convenient, is low in cost and has very important significance to industrial production of the lithium ion capacitor.

The invention discloses a preparation method of a polymer microsphere drug slow-release carrier with three responses to an oxidant, glucose and an electric field. The microsphere material consists of a polymer with beta-cyclodextrin, ferrocene-modified polyether and alpha-cyclodextrin. The preparation method of the polymer microsphere drug carrier comprises the following steps: firstly, synchronously dissolving the polymer with beta-cyclodextrin and the ferrocene-modified polyether in an aqueous solution, and stirring uniformly to ensure that the beta-cyclodextrin and ferrocene are fully compounded; and then adding alpha-cyclodextrin, and further stirring for a certain period of time to ensure that alpha-cyclodextrin and polyether are fully compounded. Along with the progress of compounding, a system gradually becomes cloudy, and polymer microspheres are formed. The polymer microspheres have good performance of wrapping macromolecular drugs and performance of effectively disintegrating the oxidant, glucose and electric field stimulation, so that gradual disintegration and slow release of a drug are realized. The polymer microsphere drug slow-release carrier disclosed by the invention is simple in preparation method and good in response effect, is environment-friendly and economical, and has a relatively great application value in the field of drug controllable slow-release.

The invention discloses a preparation method of a polyaniline / stretchable fabric electrode material, an obtained material and applications of obtained materials. The preparation method comprises the following steps: 1) enabling a stretchable fabric substrate to soak in an acidic aqueous solution containing aniline monomers; 2) dropping an aqueous solution of an oxidizing agent into the mixed system obtained in the step 1) under a stirring condition, carrying out an in-situ chemical oxidation polymerization reaction, cleaning and naturally drying an obtained product to obtain a pre-electrode material; 3) placing the pre-electrode material in a three-electrode system device and making the pre-electrode material serve as a working electrode to carry out an electrochemical polymerization reaction, cleaning and naturally dry an obtained product, and then obtaining a polyaniline / stretchable fabric electrode material. The prepared polyaniline / stretchable fabric electrode material has good tensile performance and flexibility, and also has good electrical conductivity, and has great potential application values in the fields of wearable electronic equipment, supercapacitors and the like.

The invention belongs to the field of covalent organic framework materials, and particularly relates to a thioether functionalized pyrenyl covalent organic framework material and a preparation method and application thereof. The preparation method comprises the following steps: adding 2, 5-bis (2-(ethylthio) ethoxy) terephthalylhydrazine and 1, 3, 6, 8-4-(p-formylphenyl)-pyrene into a solvent system, and reacting to obtain the thioether functionalized pyrenyl covalent organic framework material. Equipment and chemical reagents used in the synthesis method are easy to obtain, the process operation is simple and convenient, the applicability is high, the industrial application value is high, the synthesis yield is relatively high, and the pyrenyl covalent organic framework material prepared by the method has good response to visible light, has good potential application value in the field of hydrogen production by photocatalytic decomposition of water, and is easy to popularize and utilize.

The invention relates to a preparation method of an amphiphilic Janus hierarchical pore microcapsule with an opening structure. The preparation method comprises the following steps of performing occupying modification on the outer surfaces of core / shell composite microspheres; then, swelling the core / shell composite microspheres to form the anisotropic composite microspheres with bulges, and dissolving by a good solvent to remove a template, so as to form a microcapsule with the opening structure; finally, performing different functionalizing on the inner surfaces of the microcapsules, so as to obtain the microcapsule material with the hydrophilic inner surface and the hydrophobic outer surface, or the hydrophobic inner surface and the hydrophilic outer surface. The prepared microcapsule material has excellent biological compatibility, good organic solvent-resistant property, chemical corrosion-resistant property and high mechanical stability, and has huge potential application value in the fields of micrometer-nanometer reactors, load catalyzing and the like.

The invention discloses a polarization sensitive terahertz wave reflection controller based on geometrical phase. The controller is made up of eight superunits arranged in a certain order, in which each supercell consists of 4 * 4 identical cell structures, There are eight cell configurations, eight of which are obtained by rotating the top metal structure cell of the basic cell structure by a 22.5 degree rotation angle difference in the range of 0 degree to 157.5 degree, so that the geometrical dimensions of the eight cell configurations are identical but the reflection angle phase of the adjacent cell structures is 45 degrees. When different polarized terahertz waves are vertically irradiated on the reflective controller, the same magnitude phase gradient will be generated in different directions, so that the perpendicular incident terahertz waves can be reflected in different directions to achieve polarization sensitive characteristics. The invention has the advantages of simple andnovel control principle, good control effect and the like. The controller has great potential applications in terahertz communication, terahertz reflection imaging, beam control and so on.

The invention discloses a high-yield phosphorous-doped porous carbon material and a preparation method thereof. The yield of porous carbon is higher than 60 percent. The preparation method of porous carbon comprises the following steps: under a non-oxidization condition, calcining metal phytate to obtain a precursor; then treating with acid; carrying out water washing; centrifuging and collectingsediment; drying to obtain the phosphorous-doped porous carbon material. The phosphorous-doped porous carbon with high yield is directly prepared through one-step pyrolysis of potassium / sodium phytate; the porous carbon has micropore and mesoporous structures; the preparation method is simple, green and environmentally friendly; the production cost is low and the yield is high; the preparation method is very suitable for large-scale production; the high-yield phosphorous-doped porous carbon material has a huge potential application value in a plurality of fields including water treatment, pollutant adsorption, super-capacitors, fuel cells, lithium-sulfur batteries and the like.

The invention discloses a WRKY20 protein and application of an encoding gene thereof in regulating stress resistance of plants. The WRKY20 protein disclosed by the invention is a protein as shown in A1), A2), A3) or A4), wherein A1) is a protein, the amino acid sequence of which is a sequence 4, A2) is a protein, the amino acid sequence of which is a sequence 13, A3) is a protein, the amino acid sequence of which is a sequence 14, and A4) is a protein, the amino acid sequence of which is a sequence 21. Experiments verify that reduction of the WRKY20 protein content plays a role of improving resisting cotton bollworm, two-spotted spider mite and aphids and increase of the WRKY20 protein content plays a role of preventing bemisia tabaci, fungal diseases and geminivirus for plants, thereby providing a gene resource for culturing new species of insect-resistant and / or anti-disease plants. The protein has relatively good potential application value.

The invention discloses a rare earth metal organic framework material, which has a chemical formula: {[(CH3)2NH2][Eu4(FDA)7(DMF)2.0.5DMF]}n. A preparation method of the framework material comprises the following steps: (1) respectively dissolving organic ligands H2FDA and 4,4'-diphenyldicarboxylic acid in N,N-dimethylformamide solvent; (2) dissolving Eu(NO3)3.6H2O in a N,N-dimethylformamide solvent containing nitric acid; (3) mixing the above two solutions, placing the mixture into a sealed hydrothermal reaction kettle, carrying out a reaction at a constant temperature for 72 hours, separatingsolids from products which are taken out from the reaction kettle; and (4) washing the solids for a plurality of times with N,N-dimethylformamide to obtain a colorless block-shaped crystal. The abstract drawings are three-dimensional structural drawings of the framework material. The preparation method of the framework material is simple and convenient in synthesis, easy to implement, high in yield, low in cost, good in reproducibility, stable in water and stable in solvents. The framework material can be used to detect the presence of Cr(VI) ions in water by fluorescence quenching effects.