The present invention relates to a high temperature resistant adhesive for carbon materials and a preparation method thereof. The high temperature resistant adhesive is composed of high residual carbon resi and a compound filler. The ratio of the high residual carbon resin to the compound filler is 100:(55-95). The high residual carbon resin comprises phenolic resin, furan resin, benzoxazine resin, etc. The compound filler consists of two or more of graphite powder, boron powder, boron carbide, boron nitride, zirconium powder, silicon powder, zirconium boride, zirconium oxide, etc., and a curing agent corresponding to the high residual carbon resin, and the compositions are selected according to use temperature of the materials to be adhered. The high temperature resistant adhesive has the characteristics of being high in applicable temperature and wide in temperature range, can be used for a long time at 800 DEG C or more, has excellent electrical and thermal conductivity at the high temperature, and effectively solves the problems that currently when the high temperature resistant adhesive is applied at 800 DEG C or more, the adhesive strength is relatively low, the electrical and thermal conductivity is low, etc.