The invention provides high-strength anti-cracking environment-friendly concrete and a preparation process thereof. The recycled concrete is prepared from the following components in parts by mass: 350 to 480 parts of PC42.5 cement, 50 to 150 parts of fly ash, 450 to 600 parts of recycled lightweight aggregate, 120 to 180 parts of coated sponge iron, 5 to 20 parts of fluorocarbon modified polyacrylamide copolymer, 40 to 70 parts of sodium bicarbonate, 60 to 120 parts of polyphenyl granules, 1 to 2.5 parts of polycarboxylic acid water reducing agent and 160 to 250 parts of mixing water, wherein the recycled lightweight aggregate comprises waste ceramsite concrete blocks and waste rock wool boards, and the coated sponge iron comprises sponge iron, borax, a polyvinyl alcohol solution and rice husks; through optimization of raw material selection and matching and application of the recycled aggregate, the concrete is green and environment-friendly, prefabricated activation components are specifically arranged, the synergistic effect, high strength, crack resistance and mechanical properties are obviously improved, the performance is lasting and stable, and the method is worthy of popularization and application.