The invention in particular relates to a preparation method of
polymer dispersing
liquid crystal film by an
ultraviolet irradiating-heating plus stepwise initiated
polymerization and phase
separation method, belonging to the functional material field, which is applied in the preparation of electric controlled intelligent glass. The preparation method is characterized in that: the nematic
liquid crystal, the
monomer which can be polymerized under
ultraviolet light, the light initiator, the thermal polymerized
monomer and the
glass microsphere is blended and then are clipped between two pieces of transparent conductive film plated with
indium tin oxide, and then film with the thickness of 20 Mum if formed and is irradiated by the
ultraviolet light with the
wavelength of 365nm at 0 to 25 degrees; the intensity of the
ultraviolet light is 20.0mW / m<2> and the illumination time is 1 to 10 minutes; the thermal
polymerization temperature is 60 to 100 degrees, the
holding time is 5 to 8 hours, at last the PDLC film is prepared by solidification. The
polymer dispersing
liquid crystal film has the advantages that: because of the stepwise
polymerization crosslinking reaction which is carried out by selecting the
monomer polymerized by ultraviolet and thermal polymerized monomer and irradiating and heating under
ultraviolet light, the electro-optic performance the PDLC film is improved, the network strength of the
polymer is enhanced, meanwhile, the bonding force of the interface between the
polymer network and the ITO film are reinforced.