The invention relates to a preparation method of a high-durability hydrophobing agent, which comprises the following steps: (1)
hydrolysis of long-chain fluoroalkyl low-surface-energy substances: adding long-chain fluoroalkyl low-surface-energy substances, a catalyst and water into an
organic solvent, and stirring so that the long-chain fluoroalkyl low-surface-energy substances have the activity of reacting with
hydroxy group; and (2) extraction: adding a perfluoro
solvent into the
system, extracting the hydrolyzed long-chain fluoroalkyl low-surface-energy substances into the perfluoro
solvent by utilizing favorable
solubility of the long-chain fluoroalkyl low-surface-energy substances in the perfluoro
solvent, and removing the supernatant liquid, thereby obtaining the hydrophobing agent. The invention also provides a preparation method of hydrophobic glass with high performance, which comprises the following step: preparation of hydrophobic film layer:
coating the hydrophobing agent on the surface of the glass to prepare the hydrophobic film layer, thereby obtaining the hydrophobic glass. The perfluoro solvent can improve the
solubility of the long-chain fluoroalkyl low-surface-energy substances and prevent the long-chain fluoroalkyl low-surface-energy substances from
polymerization and
crystallization; and the perfluoro solvent is hardly dissolved in water, thereby avoiding water in the
system, enhancing the reaction density between the long-chain fluoroalkyl low-surface-energy substances and the
hydroxy group on the glass surface, and improving the durability of the hydrophobic film layer.