Provided is inorganic chloride ion remover. The inorganic chloride ion remover comprises one or both of calcium oxide and calcium carbonate, and meta-aluminate, wherein one or both of the calcium oxide and the calcium carbonate are mixed to form a mixture, and the mixture and the meta-aluminate are mixed to form the inorganic chloride ion remover according to the ratio. According to the total mass of calcium oxide inorganic chloride ion remover, the calcium oxide accounts for 70-80% of the calcium oxide inorganic chloride ion remover, and the meta-aluminate accounts for 30-20% of the calcium oxide inorganic chloride ion remover; according to the total mass of calcium carbonate inorganic chloride ion remover, the calcium carbonate accounts for 75-85% of the calcium carbonate inorganic chloride ion remover, and sodium metaaluminate accounts for 15-25% of the calcium carbonate inorganic chloride ion remover; according to the total mass of mixed inorganic chloride ion remover, the calcium oxide and the calcium carbonate account for 70-85% of the mixed inorganic chloride ion remover, and the meta-aluminate accounts for 15-30% of the mixed inorganic chloride ion remover. An application method of the inorganic chloride ion remover comprises the steps of adding the inorganic chloride ion remover to chloric waste water, setting the addition mass ratio to be 1-5%, continuously stirring the mixture for 10-30 minutes, standing to carry out layering, and carrying out separation, wherein the supernatant is waste water without chloride ions. The inorganic chloride ion remover has the advantages of being low in price, easy to obtain, low in addition amount, simple in removal technology, small in investment, low in operation cost and the like, and the removal rate of chloride ions in industrial waste water with the chloride ion content of 50% can reach 99.9%.