The invention discloses a method for preparing 1,4,5,8-tetraaminonaphthalene
tin chloride hydrochloride and relates to a method for preparing
hydrochloride. The method aims at solving the technical problems of more by-products, high cost, low yield, tedious after-treatment and difficulty in industrial large-scale production of the existing method for preparing 1,4,5,8-tetraaminonaphthalene
tin chloride hydrochloride. The method disclosed by the invention comprises the following steps: firstly, preparing high-purity 1,4,5,8-tetranitronaphthalene; and secondly, preparing high-purity 1,4,5,8-tetraaminonaphthalene
tin chloride hydrochloride. Due to the method, high-purity 1,4,5,8-tetranitronaphthalene which is difficult to synthesize by virtue of the conventional method can be successfully prepared and 1,4,5,8-tetraaminonaphthalene
tin chloride hydrochloride is prepared from stannous chloride and concentrated
hydrochloric acid in high efficiency by virtue of adding catalytic addictives and the operation process is simplified. The method has the advantages of inexpensive and available selected raw materials, high yield, low cost and environmental friendliness and is suitable for
industrial scale-up. The method is applied in the field of preparation of organic intermediate.