The invention discloses special mold powder for all-headless high-efficiency continuous casting ESP low-carbon steel and a preparation method thereof. The preparation method of the mold powder comprises the steps of preparation of raw materials, homogenization of the raw materials, electronic proportioning, mixing of dry materials, levigation slurrying, spray granulation, sorting and detection ofparticle sizes of finished products, online analysis and detection of X fluorescence spectra, packaging and warehousing of qualified products and the like. The raw materials of the mold powder comprise, by weight part, 30-35 parts of electro-fused calcium silicate, 10-15 parts of 97 fluorite powder, 3-5 parts of sodium fluoride, 10-15 parts of sodium carbonate, 20-25 parts of pre-fusing additives,5-8 parts of cryolite, 2-4 parts of N oil carbon black, 1-2 parts of natural gas carbon black, 3-5 parts of battery grade lithium carbonate and 2-5 parts of carboxymethyl cellulose sodium. The binarybasicity of the mold powder is 1.13-1.23, and the viscosity at 1300 DEG C is 0.08-0.22 Pa.s; and the fusing point is 965 DEG C-1025 DEG C. The special mold powder for the all-headless high-efficiencycontinuous casting ESP low-carbon steel has the excellent characteristics of stable powder consumption, stable heat flow, reduction of the bonding alarm number, novel formula, high rate of continuouscasting finished products, significant reduction of cost compared with the cost of imported powder, etc.