The invention relates to a method for preparing diantimony
trioxide nano-particles by a mechanochemical modification technology. The method comprises the following steps: (1) mixing and ball-milling
micrometer diantimony
trioxide, small hard
alloy steel balls and
distilled water to obtain nano-Sb2O3 particles; (2) washing,
drying and sieving the nano-Sb2O3 particles to obtain a nano-Sb2O3 sample;(3) mixing the nano-Sb2O3 sample, small hard
alloy steel balls and
distilled water, adjusting the pH value, adding
hexadecyltrimethylammonium bromide, carrying out ball milling, and cleaning, filtering and
drying the obtained mixture to obtain cationic surfactant CTAB modified nano-Sb2O3 particles; (4) adding the cationic surfactant CTAB modified nano-Sb2O3 particles into an
ethanol-water solution, and carrying out
ultrasonic dispersion so as to obtain cationic surfactant CTAB modified nano-Sb2O3 particles; and (5) mixing and ball-milling the cationic surfactant CTAB modified nano-Sb2O3 particles, a
silane coupling agent KH580, small hard
alloy steel balls and
anhydrous ethanol, and cleaning, filtering and
drying the obtained mixture to obtain CTAB and KH580 compounded modified nano-Sb2O3.The method has the advantages of simple process, high yield, high
operability, and easiness in realization of industrial production.