The invention discloses a water-based hollow
fluorine-
silicon composite water-repellent and breathable
textile finishing agent and a preparation method. A hollow
fluorine-containing polyacrylate-
siloxane composite polymer shell serves as the effective component of the
textile finishing agent. The preparation method of the
textile finishing agent mainly includes the three stages of firstly, preparation of an emulsification
system; secondly, preparation of shell-core
emulsion, wherein
fluorine-containing monomers,
acrylate monomers, unsaturated
carboxylate monomers, organosilicone monomers and other functional monomers serve as raw materials, and the shell-core
emulsion is obtained through a shell-core
emulsion polymerization method under the action of an initiator, a
buffering agent, an emulsifying agent and a defoaming agent; thirdly, hollowness treatment. According to the textile finishing agent, organosilicone monomers are introduced in a free
radical polymerization mode to achieve crosslinking synergism with fluorine-containing monomers while the good water repellency of C-F long-chain
polymer emulsion is maintained, and the
water resistance, wash fastness and softness of textiles are improved; besides, due to the unique hollow structure of the textile finishing agent, the breathability is improved, the
light scattering performance is also improved, and the cost is reduced.