The invention discloses a
quaternary hypoeutectic high-entropy
alloy excellent in strength and
plasticity match. The
quaternary hypoeutectic high-entropy
alloy consists of a component of AlxCoyCrzNiw,wherein x, y, z and w respectively are
molar ratios of corresponding elements, the
molar ratios meet the relationships: 16>=x>=12, 30>=y>=26, 30>=z>=26, and 32>=w>=28. The
quaternary hypoeutectic high-entropy
alloy is of hypoeutectic structure, and excellent in strength and
plasticity match. Simultaneously, the invention further provides a preparation method of the quaternary hypoeutectic high-entropy alloy. The preparation method includes: first, removing
oxide skin from the elementary metals, weighing and mixing the elementary metals according to the
molar ratios to obtain a mixture, placing the mixture in a high vacuum non-self-consuming
arc melting furnace, performing
electric arc melting in vacuum under
argon protection, obtaining an alloy solution, stirring and cooling the alloy solution, obtaining an alloy
ingot, repeating
smelting for four times to obtain a high-entropy alloy, removing
oxide skin from the obtained high-entropy alloy, performing ultrasonic cleaning twice by using ethyl
alcohol, placing a clean alloy
ingot in a high
vacuum arc smelting rollover casting and
centrifugation casting system, pouring
molten alloy obtained after remelting into a
copper mold, and then obtaining a high-entropy alloy
test sample Al14Co28Cr28Ni30. The preparation method is simple, safe and stable.