A porous bubble electrostatic spinning device comprises a liquid storage tank, a high pressure electrostatic generator, an air pump, a sprayer, and a dash receiver, wherein the sprayer is connected with the air pump through an air duct, the dash receiver is connected with a grounded electrode, an opening is arranged at the upper end of the liquid storage tank, the liquid storage tank is connected with the high pressure electrostatic generator through a metal electrode, the liquid storage tank is internally provided with a middle flat plate, and a plurality of small holes with adjustable diameters are formed in the middle flat plate in a penetrating way. As the small holes are formed in the middle flat plate, solution in the liquid storage tank generates a large quantity of bubbles through the plurality of small holes under the action of the air pump. When filed stress is greater than surface tension of the solution, and jet flow is ejected from the top of the bubbles and is deposited on the dash receiver to form a large amount of nanofiber. The porous bubble electrostatic spinning device can produce the nanofiber in a large scale, so that according to the device, the production efficiency is high, the production cost is low, the equipment is simple, the operation is easy, the adaptability is high and the requirement of batch production can be met.