Patents
Literature
Hiro is an intelligent assistant for R&D personnel, combined with Patent DNA, to facilitate innovative research.
Hiro

55results about How to "Effective catalytic degradation" patented technology

Modified titanium-containing furnace cinder catalyst with visible light catalytic activity and method for producing the same

The invention relates to a modified titanium-bearing blast furnace slag catalyst with visible photocatalytic activity and a preparation method thereof, which belong to the field of material science. The compositions of crystal phase of the catalyst are 33 to 40 weight percent of perovskite, 50 to 59 weight percent of diopside and 7 to 10 weight percent of akermanite-submellite; and the specific surface area is between 9.7 and 20.5 square meters pre gram, and the maximum absorption capacity is between 3.9 and 8.3 milligrams per gram. The preparation method comprises the following steps: firstly, titanium-bearing blast furnace slag is crushed, and titanium-bearing blast furnace slag powder is obtained; secondly, ammonium sulfate is mixed with the titanium-bearing blast furnace slag powder; thirdly, mixture of the titanium-bearing blast furnace slag powder and the ammonium sulfate is grinded; and fourthly, the mixture is roasted for 1 to 4 hours at a temperature of between 300 and 700 DEG C, and is cooled to the room temperature. The STBBFS catalyst prepared by the method has strong photoabsorption and photoresponse when excited by visible light, so that the photocatalyst which is prepared by adoption of the titanium-bearing blast furnace slag as a raw material can utilize visible light sources such as sunlight to effectively photodegrade organic pollutant and inorganic pollutant in the water, and has high energy conversion efficiency.
Owner:NORTHEASTERN UNIV

Preparation method of functionalized photocatalyst fibers

The invention discloses a preparation method of functionalized photocatalyst fibers. The preparation method comprises the following steps: (1) preparing functionalized nano TiO2 powder, namely, adding 5.0g of ferric trichloride and 3.0g of graphene oxide into 1000ml of nano TiO2 hydrosol, stirring at room temperature for 2 hours, cooling, filtering and baking to obtain the functionalized nano TiO2 powder; (2) preparing functionalized PET master batch, namely, uniformly mixing 15wt%-45wt% of functionalized nano TiO2 powder, 1.0wt%-2.0wt% of a polyethylene dispersant with relative molecular weight being 2000 and 53wt%-84wt% of PET sections in a high-speed mixer, performing melting extrusion at 180-240 DEG C, and performing water cooling, granulating and vacuum drying to obtain the functionalized PET master batch; and (3) spinning the functionalized photocatalyst fibers, namely, drying 20wt%-50wt% of master batch and 80wt%-50wt% of PET sections in vacuum for 1 hour, performing melt spinning on the dried product combined with skin cores at 280 DEG C, and stretching by 3-3.5 times, thereby obtaining the functionalized photocatalyst fibers.
Owner:TIANJIN POLYTECHNIC UNIV

Preparation method of visible-light response carbon-doped nano-titanium dioxide catalyst

The invention discloses a preparation method of a visible-light response carbon-doped nano-titanium dioxide catalyst. The preparation method includes the following steps: dissolving a titanium-containing compound in an alcohol solution to obtain a solution A; mixing an alkali solution with an alcohol solution to obtain a solution B; dropwise adding the solution B to the solution A, stirring for 30-60 min, and then carrying out a reaction for 6-24 h at the temperature of 50-70 DEG C, to obtain a white gel; and drying the obtained white gel for 10-24 h at the temperature of 80-120 DEG C, grinding into a powder, washing the powder with an alcohol solution or deionized water, then drying, calcining the obtained powder with the calcination temperature of 200-600 DEG C and the time of 1-10 h, and thus obtaining the carbon-doped titanium dioxide visible light catalyst. Raw materials used in the preparation method have no need of precious metals, has no need of aging, has no additional addition of a carbon source and no addition of water, the cost and time are saved, the preparation technology is simple, and the requirements on equipment are not high.
Owner:NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI

Preparation method and application of MnTiO3 and F-MnTiO3

The invention discloses a preparation method and application of MnTiO3 and F-MnTiO3. According to a hydro-thermal synthesis method which is taken as the preparation method, titanate nanowires are taken as a Ti source, MnCl2 is taken as a Mn source, NaF is taken as an F source; the hydro-thermal synthesis method can be used for preparing the MnTiO3 and the F-MnTiO3 which are uniform in feature and diameter and of sheet-shaped structures on the condition of adding NaOH; and the MnTiO3 and the F-MnTiO3 are catalyzed and degraded to obtain organic dyestuff named rhodamine B under the irradiation of visible light. The MnTiO3 and the F-MnTiO3 both have catalytic degradation performance under visible light, and the F-MnTiO3 has higher catalytic performance than the MnTiO3 since an F element is doped in the F-MnTiO3 material, wherein F is an element with greatest electronegativity and can be combined with photoproduction electrons to restrain the combination of the photoproduction electrons and electron holes and further improve the photocatalytic efficiency of visible light. The preparation method provided by the invention is safe and rapid and is high in stability.
Owner:ZHEJIANG SCI-TECH UNIV

Rhodamine B-doped modified titanium concentrate photocatalyst and preparation method thereof

The invention belongs to the field of photocatalytic chemistry, and particularly relates to a rhodamine B-doped modified titanium concentrate photocatalyst. A crystalline phase composition of the catalyst comprises the following components in percentage by weight: 15-20 percent of titanomagnetite, 30-40 percent of ilmenite, 20-(-30) percent of titanium dioxide, 20-35 percent of titanium oxide and0.9-7 percent of undecomposed rhodamine B, wherein the specific surface area is 351-528m<2> / kg, and the average particle diameter is 10-16mum. A preparation process of the catalyst comprises the following steps of: crushing massive titanium concentrate; mixing the crushed titanium concentrate with the rhodamine B according to different doping proportions; performing ultrasonic dispersion, ball milling and wet mixing, drying and grinding on mixed powder; performing low-temperature roasting and activation on the obtained compound; cooling and then grinding. The rhodamine B-doped modified titanium concentrate photocatalyst has high light absorption and light response under the excitation of visible light, is used for catalyzing photodegradation of organic and inorganic pollutants and complexsystems in water, and has high social and economic benefits.
Owner:NORTHEASTERN UNIV

Compound microbial inoculant for purifying mariculture wastewater

The invention discloses a compound microbial inoculant for purifying mariculture wastewater. The compound microbial inoculant comprises a compound microbial flora, an adsorption vector and an effervescent auxiliary material, wherein the compound microbial flora is primarily composed of pseudomonas SC221-M and bacillus subtilis. The adsorption vector comprises nano titanium dioxide, nano silicon dioxide, medical stone flour and bamboo carbon powder. The effervescent auxiliary material is preferably carbonate and an organic acid. The invention also discloses a preparation method of the compoundmicrobial inoculant for purifying mariculture wastewater. The invention has the beneficial effects that the compound microbial inoculant is prepared by mixing the compound microbial flora, the adsorption vector and the effervescent auxiliary material, wherein the specific surface area, adsorptivity, biocompatibility and good microorganism fixing property of the adsorption vector is coordinated with gas buoyancy generated by the effervescent auxiliary material to increase the contact area of the compound microbial inoculant and the mariculture wastewater, enhance the degrading ability to pollutants and remove wastewater pollutants effectively, so as to achieve the purpose of purifying the mariculture wastewater.
Owner:ZHEJIANG OCEAN UNIV

Composite (BiO)2CO3/C photocatalyst and application thereof

The invention discloses a composite (BiO)2CO3 / C photocatalyst and application thereof, and belongs to the field of photocatalysis materials. Carbon fibers are prepared by adopting bamboo fibers as a carbon source, and (BiO)2CO3 is uniformly loaded on the carbon fibers by utilizing a hydrothermal method. The material is excellent in photocatalysis performance, and especially under the illumination of a xenon lamp, organic pollutants in sewage can be effectively degraded.
Owner:UNIV OF JINAN

Rod-like g-C3N4@SnIn4S8 composite photocatalyst and method for preparing same

The invention belongs to the technical field of photocatalysts, and particularly relates to a rod-like g-C3N4@SnIn4S8 composite photocatalyst and a method for preparing the same. The method for synthesizing the rod-like g-C3N4@SnIn4S8 composite photocatalyst by the aid of hydrothermal processes includes calcining urea at the high temperatures to obtain pure g-C3N4; weighing the g-C3N4, dissolvingcrystallized tin tetrachloride (SNCl4.5H2O) in deionized water, carrying out ultrasonic treatment, adding quantitative indium nitrate hydrate [In(NO3)3.5H2O] and thioacetamide (C2H5NS) into the deionized water, stirring the indium nitrate hydrate [In(NO3)3.5H2O], the thioacetamide (C2H5NS) and the deionized water to obtain mixtures, transferring the mixtures into a reaction kettle and keeping thetemperatures of the mixtures in a drying oven constant; carrying out negative-pressure suction filtration after reaction is completely carried out and washing and drying reaction products to obtain samples. The urea is a raw materials for the rod-like g-C3N4@SnIn4S8 composite photocatalyst. The rod-like g-C3N4@SnIn4S8 composite photocatalyst and the method have the advantages that the rod-like g-C3N4@SnIn4S8 composite photocatalyst prepared by the aid of the method is mainly applied to photocatalysis, gas adsorption and separation, chemical sensors and the like; the method is simple and is easy to operate, low in cost and free of pollution, and accordingly the rod-like g-C3N4@SnIn4S8 composite photocatalyst and the method have excellent application prospects in the technical field of environmental pollution control.
Owner:TAIZHOU VOCATIONAL & TECHN COLLEGE

Device and method for degrading high temperature coke quenching waste water

The invention discloses a device for degrading high temperature coke quenching waste water. The device comprises a coke quenching circulation pool, a coagulative reaction tank, a coagulative precipitation tank, an advanced catalytic oxidizer and a filter, wherein the coke quenching circulation pool is connected with the coagulative reaction tank; the coagulative reaction tank is connected with thecoagulative precipitation tank, the coagulative precipitation tank is connected with the advanced catalytic oxidizer, and the advanced catalytic oxidizer is connected with the filter. The coke quenching waste water in a high temperature state is sequentially subjected to coke powder precipitation, suspended solid precipitation and catalytic oxidative degradation in a degradation device, and the degraded product is then filtered, so that the coke quenching waste water is enabled to reach the discharge standard of the Coking Chemical Industry Pollutant Discharge Standard. The degradation devicecan be used for degrading the high temperature coke quenching waste water, and is high in degradation efficiency and low in degradation cost, thus having very high use value and promotion value.
Owner:深圳市清源宝科技有限公司

Method for preparing tin reduced nano titanic oxide catalyst

The invention provides a method for preparing a tin reduced nanometer titanium dioxide catalyst. The prior hydrogen reduction method has the deficiencies of complex process, long time consumption and high cost, and is difficult to realize industrialization. The method for preparing the tin reduced nanometer titanium dioxide catalyst comprises the following steps: weighing 1 to 100 portions of nanometer titanium dioxide powder according to a ratio in portion by weight; adding the nanometer titanium dioxide powder into a stannous chloride solution at room temperature to be immersed for 1 to 60 minutes; pumping and filtering the mixed solution; washing the filtrate by water for three times; and drying the filtrate to obtain the tin reduced nanometer titanium dioxide catalyst. The method can be used for preparing the tin reduced nanometer titanium dioxide catalyst.
Owner:HEILONGJIANG UNIV

Method for degrading methylene blue solution

The invention discloses a method for degrading a methylene blue solution. According to the method, CuO is used as a catalyst for catalyze the decomposition of hydrogen peroxide to the methylene blue solution. As an effective catalyst, copper oxide can degrade sewage containing the methylene blue solution in a relatively short time. Furthermore, CuO is a nano-structured CuO membrane which has a large specific surface area and relatively strong base adhesion force and is capable of effectively catalyzing the decomposition of hydrogen peroxide to the methylene blue solution and effectively decoloring the methylene blue solution within 0.5 hour, and 100% degradation efficiency can be achieved within 4 hours; furthermore, the CuO membrane has very high stability and can be repeatedly used.
Owner:QUANZHOU NORMAL UNIV

Method for in-situ synthesis of FeOOH/Fe3O4/cellulose composite material and application thereof

The invention discloses a method for in-situ synthesis of a FeOOH / Fe3O4 / cellulose composite material and application thereof. The preparation method comprises the following steps: dissolving cellulosepretreated by mechanical activation in cooperation with FeCl3 into a NaOH / urea solution; by taking a cellulose solution as a precipitator and a template agent, synthesizing a Fe3O4 / cellulose compoundin situ by adopting a coprecipitation method; then generating needle-shaped FeOOH on the surface of the Fe3O4 / cellulose to obtain the FeOOH / Fe3O4 / cellulose composite material which is used for catalytic degradation of Congo red. The composite material has a very good catalytic degradation effect, and is good in reuse performance and stability. The method disclosed by the invention is simple and low in cost, and the synthesized FeOOH / Fe3O4 / cellulose composite material is good in stability, can effectively and quickly catalyze and degrade dye Congo red in heterogeneous Fenton reactions, and hasa good application prospect.
Owner:GUANGXI UNIV

Preparation method of two-dimensional porous Co3O4-ZnO composite nanosheet

The invention discloses a preparation method of a two-dimensional porous Co3O4-ZnO composite nanosheet. The method comprises the following steps: (1) collecting plant petals and pretreating the petalsto obtain a petal template; (2) dipping the template; and (3) taking out the dipped template, cleaning, soaking and drying the template, calcining the template by a muffle furnace and then naturallycooling the template to obtain the two-dimensional porous Co3O4-ZnO composite nanosheet. The preparation method of the two-dimensional porous Co3O4-ZnO composite nanosheet is simple, sources of raw materials are wide, the cost is low, the method is green and pollution-free, the prepared material has a unique two-dimensional porous structure, high catalytic activity and heat stability, and when thematerials is used for purifying organic dyestuff wastewater, the organic dyestuff wastewater can be decomposed catalytically.
Owner:SHANDONG UNIV OF SCI & TECH

Preparation method and product of self-supporting VO2 Fenton-like catalytic material

The invention belongs to the field of catalyst preparation, and specifically discloses a preparation method and a product of a self-supporting VO2 Fenton-like catalytic material. The preparation method comprises the following steps: (1) preparing V2O5 sol and aging; (2) immersing anode and cathode conductive base materials into the V2O5 sol for carrying out electrophoretic deposition to obtain a V2O5-coated conductive base material; (3) putting the V2O5-coated conductive base material prepared in the step (2) in a tubular furnace, and carrying out calcinations under a ventilation condition, wherein the heating rate of calcinations is 1 to 20 DEG C per minute, the temperature of calcinations is 600 to 1000 DEG C, the holding time is 0.5 to 10 h, and the air introduction speed is 0.1 to 10 Lper minute, therefore, the self-supporting VO2 Fenton-like catalytic material is obtained. The self-supporting VO2 Fenton-like catalytic material prepared in the invention has excellent self-supporting characteristic and catalytic performance, and is free of secondary pollution to the environment, so that low-cost and large-scale production can be realized.
Owner:HUAZHONG UNIV OF SCI & TECH

Synthesis of copper complex and application of copper complex as photodegradation catalyst

The invention provides preparation of a copper metal complex and application of the copper metal complex in a photodegradation catalyst. The chemical formula of the complex is [Cu (L) (AIP) (H2O). H2O] n, wherein H2AIP is equal to 5-aminoisophthalic acid, and L is equal to 3, 5-bis (1H-benzimidazole-1-yl) pyridine. The copper metal complex is of a two-dimensional structure formed by self-assembling copper ions through AIP <2-> and an L ligand. The copper complex has stable and efficient catalytic photodegradation dye properties: methylene blue is basically completely degraded within 60 minutes, and is easy to separate and can be recycled for multiple times.
Owner:YANCHENG TEACHERS UNIV

Micron-scale elemental copper catalyst and preparation method and application thereof

The invention discloses a micron-scale elemental copper catalyst and a preparation method and application thereof. According to the key points of the technical scheme, the micron-scale elemental copper catalyst is prepared by the steps of reacting copper salt with an organic ligand to form a precursor and then performing calcination under the protection of nitrogen at the temperature of 400 to 800 DEG C, wherein the molar mass ratio of the copper salt (n) to the organic ligand (n) is (1-4) to 1, the copper salt is Cu(NO3)2.3H2O, and the organic ligand is 1,3,5-trimesic acid, terephthalic acid, isophthalic acid, phthalic acid, formic acid or 4,4',4''-s-triazine-1,3,5-three-para aminobenzoic acid. The invention further discloses the preparation method of the catalyst and the application of the catalyst to processing of nitrophenol waste water. The micron-scale elemental copper catalyst has the advantages of environmental friendliness, simple preparation process, high innovativeness and practicability and the like, nitrophenol pollutants in organic waste water can be effectively catalyzed and degraded, and the catalyst has circulating renewable use performance.
Owner:HENAN NORMAL UNIV

Titanium dioxide-doped tourmaline ceramic ball photocatalyst and preparation method thereof

The invention discloses a titanium dioxide-doped tourmaline ceramic ball photocatalyst and a preparation method thereof. The titanium dioxide-doped tourmaline ceramic ball photocatalyst is a composite photocatalyst composed of tourmaline ceramic particles and nano-titanium dioxide as a doping element carried by the tourmaline ceramic particles. The preparation method comprises the following steps of dissolving the doping element in an ethanol acidic aqueous solution, slowly and dropwisely adding an ethanol solution of butyl titanate into the ethanol acidic aqueous solution with stirring to obtain a semitransparent flavescent mixed solution A, dipping the tourmaline ceramic particles into an ethanol alkaline solution to obtain an immersion solution, dropwisely adding the semitransparent flavescent mixed solution A into the immersion solution under the action of ultrasonic wave, carrying out ultrasonic treatment for 1 to 2 hours to obtain a gel covered material composed of the tourmaline ceramic particles and nano-titanium dioxide-doped gel covered on the tourmaline ceramic particles, carrying out filtration, washing and adding of the gel covered material, putting the treated gel covered material into a muffle furnace, gradually heating, and carrying out sintering at a temperature of 400 to 550 DEG C to obtain the titanium dioxide-doped tourmaline ceramic ball photocatalyst. The titanium dioxide-doped tourmaline ceramic ball photocatalyst can carry out effective deep-degradation treatment on trace amounts of various HOCs in drinking water in visible light.
Owner:大连市疾病预防控制中心 +1

Molecular imprinting type MOFs catalyst and preparation and application thereof in specific catalytic degradation of antibiotics

The invention discloses a molecular imprinting type MOFs catalyst and preparation and application thereof in specific catalytic degradation of antibiotics, and relates to the technical field of new materials. The preparation method comprises the following steps: dissolving ferric salt, a template agent and an organic ligand to obtain a mixed solution, the template agent being an antibiotic molecule; transferring the mixed solution into a hydrothermal reaction device for hydrothermal reaction, eluting precipitates obtained by the hydrothermal reaction to elute the template agent to form molecularly imprinted holes, and drying in vacuum to obtain the molecular imprinting type MOFs catalyst. According to the prepared catalyst material, the advantages of molecular imprinting specific recognition and the characteristic of high adsorption capacity of MOFs materials are effectively combined, and specific recognition and high-capacity adsorption of low-concentration antibiotic pollutants in acomplex system and selective catalytic degradation of the antibiotic pollutants are achieved.
Owner:HUAZHONG UNIV OF SCI & TECH

a stick g-c 3 no 4 @snin 4 the s 8 Composite photocatalyst and preparation method thereof

The invention belongs to the technical field of photocatalysts, and particularly relates to a rod-like g-C3N4@SnIn4S8 composite photocatalyst and a method for preparing the same. The method for synthesizing the rod-like g-C3N4@SnIn4S8 composite photocatalyst by the aid of hydrothermal processes includes calcining urea at the high temperatures to obtain pure g-C3N4; weighing the g-C3N4, dissolvingcrystallized tin tetrachloride (SNCl4.5H2O) in deionized water, carrying out ultrasonic treatment, adding quantitative indium nitrate hydrate [In(NO3)3.5H2O] and thioacetamide (C2H5NS) into the deionized water, stirring the indium nitrate hydrate [In(NO3)3.5H2O], the thioacetamide (C2H5NS) and the deionized water to obtain mixtures, transferring the mixtures into a reaction kettle and keeping thetemperatures of the mixtures in a drying oven constant; carrying out negative-pressure suction filtration after reaction is completely carried out and washing and drying reaction products to obtain samples. The urea is a raw materials for the rod-like g-C3N4@SnIn4S8 composite photocatalyst. The rod-like g-C3N4@SnIn4S8 composite photocatalyst and the method have the advantages that the rod-like g-C3N4@SnIn4S8 composite photocatalyst prepared by the aid of the method is mainly applied to photocatalysis, gas adsorption and separation, chemical sensors and the like; the method is simple and is easy to operate, low in cost and free of pollution, and accordingly the rod-like g-C3N4@SnIn4S8 composite photocatalyst and the method have excellent application prospects in the technical field of environmental pollution control.
Owner:TAIZHOU VOCATIONAL & TECHN COLLEGE

Synthesis method of two-dimensional cobalt complex, and applications of two-dimensional cobalt complex as photodegradation catalyst and ferroelectric material

The invention provides a preparation method of a cobalt complex, and applications of the cobalt complex as a photodegradation catalyst and a ferroelectric material. The molecular formula of the complex is [Co5(OH-BDC)4(TMIB)4(NO3)2(DMA)2.2H2O]n, wherein -OH-H2BDC=5 is 5-hydroxyisophthalic acid, and TMIB is 1,3,5-tri(2-methyl-1-imidazolyl)benzene. The cobalt complex is of a two-dimensional networkstructure formed by self-assembling Co<2+> with OH-BDC<2-> and TMIB ligands. The cobalt complex has the property of efficiently catalyzing photodegradation of dyes: methylene blue is basically completely degraded within 90 minutes; and the cobalt complex is easy to separate, and can be recycled for multiple times. In addition, the cobalt complex has excellent ferroelectric properties: when an external electric field is 1100 V, the residual polarization Pr is 1.751 [mu]C / cm<2>, the coercive field Ec is 654 V / cm, and the saturated polarization Ps is 1.991 [mu]C / cm<2>, so that the cobalt complexis expected to be a novel ferroelectric material and has a wide application prospect in the field of information storage.
Owner:YANCHENG TEACHERS UNIV

Black Ta2O5, and preparation method and application thereof

The invention discloses a preparation method of black Ta2O5. The preparation method comprises the following steps: dissolving TaCl5 in absolute ethyl alcohol, adding an acetylacetone stabilizer, and magnetically stirring to obtain a TaCl5 sol precursor; aging the TaCl5 sol precursor in a drying oven, taking out a blocky solid at the bottom, and transferring the blocky solid into a ball milling tank, and performing ball milling to obtain tantalum oxide gel powder; feeding the tantalum oxide gel powder into a muffle furnace, heating, and performing heat preservation to obtain white Ta2O5 powder;uniformly mixing and grinding the white Ta2O5 powder and NaBH4, putting the obtained mixture into a tubular furnace, carrying out annealing treatment in a protective atmosphere, and cooling to obtainthe black Ta2O5. Low-valence Ta4<+> ions and oxygen vacancies are introduced into Ta2O5 crystal lattices to improve the visible light absorption, enhance the photo-induced electron and hole separation efficiency and realize efficient degradation of methylene blue pollutants in the water body through photocatalysis, toxic and harmful reagents are not used, the period is short, and the method is anew method capable of simply and rapidly producing the black Ta2O5 photocatalytic material on a large scale.
Owner:苏州机数芯微科技有限公司

Preparation method of beta-Ga2O3/SiC nanometer composite material

The invention relates to a preparation method of a beta-Ga2O3 / SiC nanometer composite material, and solves the problems of large particle diameter, complex preparation process and long reaction time of the traditional method. The preparation method comprises the following steps: 1, adding urea to deionized water, heating and stirring till the urea is completely dissolved, then adding a Ga(NO3)3 solution, and stirring till a colorless transparent solution is obtained; 2, transferring into a container with a polytetrafluoroethylene lining, then placing the container into a microwave digestion furnace for heating, and after reaction is finished, naturally cooling to room temperature to obtain a gamma-Ga2O3 precursor; 3, dropwise adding the gamma-Ga2O3 precursor to SiC, and then firstly drying moisture through microwave evaporation and then carrying out microwave heat treatment to obtain an SiC-containing solid mixture; 4, adding the SiC-containing solid mixture to the deionized water for centrifugalization, and then carrying out vacuum drying to obtain the beta-Ga2O3 / SiC nanometer composite material.
Owner:HEILONGJIANG UNIV

Three-dimensional cadmium complex, preparation method thereof, and application of cadmium metal complex as fluorescent probe and photodegradation catalyst

The invention provides a preparation method of a cadmium metal complex and an application of the cadmium metal complex as a fluorescent probe and a photodegradation catalyst. The chemical formula of the complex is [Cd(L)(H2O).5H2O]n, wherein H2L is 1,1'-(4-carboxylphenyl)-2,2'-biimidazole. The cadmium metal complex is of a three-dimensional structure formed by self-assembling cadmium ions with anL<2-> ligand. The cadmium complex has an obvious fluorescence quenching effect on ferric ions, dichromate ions and antibiotics furacilin and nitrofurantoin, can be used as the fluorescent probe, and has potential application values in the fields of environmental monitoring and life science. In addition, the cadmium complex has stable and efficient catalytic photodegradation dye properties: methylene blue, methyl orange and rhodamine B are basically and completely degraded within 60 min under the condition of visible light, and the cadmium complex is easy to separate and can be recycled for multiple times.
Owner:YANCHENG TEACHERS UNIV

Mn-ZnO catalyst as well as preparation method and application thereof

The invention relates to the technical field of catalysts, and provides a Mn-ZnO catalyst which comprises ZnO and Mn doped in the ZnO. The mass ratio of Mn to ZnO in the Mn-ZnO catalyst is (0.001 to 10): 100. Mn is used as a doping metal, so that the lattice structure in ZnO is effectively changed, the photocatalyst can absorb sunlight to generate electron and hole pairs, electrons and holes are rapidly separated and migrated to the surface of a Mn-ZnO semiconductor, recombination of photon-generated carriers is inhibited, and therefore, the service life of the photo-gnerated electron-hole pair participating in the photocatalytic reaction is prolonged; and the electrons and holes migrated to the surface of the Mn-ZnO semiconductor and CH4 adsorbed on the surface of Mn-ZnO are subjected to a redox reaction, so that the photocatalytic efficiency is improved. Experimental results show that the Mn-ZnO catalyst provided by the invention can efficiently catalyze and degrade methane under simulated sunlight.
Owner:HUBEI UNIV

Three-unit UV ambient air purification device

The invention discloses a three-unit UV high-performance ambient air purification device, and belongs to the technical field of high-performance novel ambient air purification. The device comprises amachine body, a display panel, an exhaust inlet, an exhaust outlet, a humidity adjusting device, a fixed handle, a power supply, a high-power mute variable-speed turbofan, a UVA ultraviolet lamp bank,a photocatalytic oxidation unit reactor, an electrostatic dust collection device, a primary filter screen, an activated carbon filter screen and a composite Ag<+> / TiO2 sterilization-disinfection filter screen. The three-unit UV high-performance ambient air purification device is characterized in that a machine body shell and part of parts are made of metal materials; air is sucked in from three sides and is exhausted from the top; particulate matters in the air can be subjected to dust removal and purification, and indoor dust is reduced; and volatile organic compounds are degraded through photocatalysis, the effects of sterilization, disinfection and epidemic prevention are achieved, planktonic bacteria and viruses in air can be efficiently killed, cross infection of epidemic situationsis controlled, indoor air is purified, and public health and safety are guaranteed.
Owner:CHINA CATALYST HLDG CO LTD

Preparation method and application of g-C3N4 (101)-(001)-TiO2 composite material

The invention discloses a preparation method and application of a g-C3N4 / (101)-(001)-TiO2 composite material. The preparation method is simple and easy to control, a synthesized g-C3N4 / (101)-(001)-TiO2 composite photocatalytic system takes carbon nitride as a main body, and TiO2 containing surface heterojunction as an object. The conduction capability of electrons between interfaces is improved, the separation of photo-induced electron hole pairs is promoted, and the catalytic capability under visible light is improved. The composite material not only makes up the defects of g-C3N4, but also accelerates the transfer of photo-induced electron hole pairs on the interface of g-C3N4 and (101)-(001)-TiO2, and can effectively catalyze and degrade paracetamol and methylene blue under visible light.
Owner:QILU UNIV OF TECH

Method for preparing tin reduced nano titanic oxide catalyst

The invention provides a method for preparing a tin reduced nanometer titanium dioxide catalyst. The prior hydrogen reduction method has the deficiencies of complex process, long time consumption and high cost, and is difficult to realize industrialization. The method for preparing the tin reduced nanometer titanium dioxide catalyst comprises the following steps: weighing 1 to 100 portions of nanometer titanium dioxide powder according to a ratio in portion by weight; adding the nanometer titanium dioxide powder into a stannous chloride solution at room temperature to be immersed for 1 to 60 minutes; pumping and filtering the mixed solution; washing the filtrate by water for three times; and drying the filtrate to obtain the tin reduced nanometer titanium dioxide catalyst. The method can be used for preparing the tin reduced nanometer titanium dioxide catalyst.
Owner:HEILONGJIANG UNIV

Biological template method for preparing tubular ZnO-SnO2 composite nano material

The invention discloses a method for preparing a tubular ZnO-SnO2 composite nano material based on a bean sprout template method. The method comprises the following steps: (1) purchasing fresh bean sprouts, and pretreating the fresh bean sprouts to form a bean sprout template; (2) dipping the template; and (3) taking out the impregnated template, cleaning, soaking and drying the template, calciningthe template in a muffle furnace, and naturally cooling the template to obtain the tubular ZnO-SnO2 composite nano material. The method for preparing the tubular ZnO-SnO2 composite nanomaterial is simple, the raw materials are wide in source, low in cost, green and free of pollution, and the prepared material has high catalytic activity and thermal stability; when the material is applied to purification treatment of organic dye wastewater, the organic dye wastewater can be effectively catalytically degraded.
Owner:SHANDONG UNIV OF SCI & TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products