The invention discloses a preparation method for a self-active
lithium titanate material. The preparation method comprises the following steps: step 1, adding
lithium acetate into absolute ethyl
alcohol, and carrying out uniform stirring for 1-3 hours so as to obtain a
lithium alcohol solution; step 2, adding
titanium monoxide powder into the lithium
alcohol solution, and carrying out low-temperature ultrasonic treatment for 2-4 hours so as to obtain a mixed turbid liquid; step 3, uniformly spraying the mixed turbid liquid into a sealed reaction kettle, carrying out standing for 1-2 hours at aconstant temperature, and carrying out decompressing and cooling so as to obtain coated
titanium monoxide particles; step 4, adding the coated
titanium monoxide particles into a mold, and carrying out a constant-temperature and constant-pressure reaction for 2-4 hours so as to obtain a primary
lithium titanate plate; and step 5, soaking the primary
lithium titanate plate into tetrabutyl
titanate,carrying out low-temperature ultrasonic treatment for 3-5 hours, then carrying out an
extrusion reaction for 2-4 hours in a humid environment, and carrying out
sintering so as to obtain the self-active
lithium titanate material. According to the invention, the problem of poor
conductivity of lithium
titanate is solved; and titanium monoxide is used as an inner core, and lithium titanate is endowed with
oxygen deficiency by utilizing the
oxygen deficiency of the titanium monoxide, so an
electron-hole structure of the lithium titanate is realized, and the overall
conductivity and activity are greatly improved.