The invention relates to a method of combined production of multiple phosphates and a
phosphate fertilizer from low grade
phosphate ore. The method comprises the following steps: decomposing low grade
phosphate ore
powder by using
hydrochloric acid to obtain an extract liquid containing
calcium dihydrogen phosphate and
calcium chloride; neutralizing the extract liquid by using
ammonia by two segments to respectively obtain
fertilizer-grade
potassium dihydrogen phosphate and feed-grade
calcium hydrogen phosphate, carrying out reaction on the
neutralization liquid from the two segments and
potassium sulfate and / or
potassium bisulfate, and concentrating a filtrate to prepare a great amount of element
water soluble fertilizers, or adding low molecular weight
ammonium polyphosphate into the filtrate to prepare a suspended
water soluble fertilizer. According to the method disclosed by the invention, by utilizing the characteristic of high
decomposition rate by extracting phosphate ores by
hydrochloric acid, with the combination of the technical characteristics of different phosphates and
phosphate fertilizer products and different
product standard requirements, the process technical requirements among the products are effectively jointed with one another, and the products including the feed-grade calcium
hydrogen phosphate, the fertilizer-grade potassium dihydrogen phosphate, the
water soluble fertilizer and
gypsum whiskers are in combined production, so that the production process technology of each product is simple and feasible,
phosphorus, calcium,
magnesium and
fluorine in the phosphate ores are fully utilized and the production cost of each product is also lowered.